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PHY2100 Physics Practical II UNIVERSITY OF MALTA MSIDA, MALTA 2 September 2013 2 CONTENTS Contents Experiment 1 - The Specific Charge of an electron by the Magnetron Method 3 Experiment 2 - The Hall Effect 7 Experiment 3 - The Skin Effect 11 Experiment 4 - Physics with a car headlamp 14 Experiment 5 - Determination of the ratio of the specific heat capacities of air by the Clément and Desormes’ method 20 Experiment 6 - Forbe’s Bar 23 Experiment 7 - Measuring the linear expansion of solids as a function of temperature 26 Experiment 8 - The Continuous-Flow Calorimeter 29 Experiment 9 - Verification of Cauchy’s Formula 32 Experiment 10 - The Balmer Series 34 Experiment 11 - The compound pendulum A 37 3 EXPERIMENT 1 - THE SPECIFIC CHARGE OF AN ELECTRON BY THE MAGNETRON METHOD Experiment 1 - The Specific Charge of an electron by the Magnetron Method Aim To determine the specific charge of an electron. Apparatus Magnetron on base, heater power supply 0-2A with ammeter, anode power supply 0-30V with voltmeter and milliammeter, solenoid, solenoid power supply 0-3A with ammeter. Description A magnetron is a thermionic valve with cylindical coaxial anode and cathode. Electrons emitted by the cathode travel radially to the anode (see Figure 1a), however in the presence of an axial magnetic field the electron paths become curved (Figure 1b). At a critical value of the magnetic field, the electron paths just touch the anode (Figure 1c), any further increase in magnetic field strength will result in the electrons not reaching the anode (Figure 1d) so the anode current falls to zero. Measurement of this critical field can be used to determine the specific charge. Figure 1: Electron paths inside the magnetron for different currents. The conditions for the critical case (Figure 1c) are that the radius of the electron orbit is half the anode radius of the magnetron, i.e. re = ra . 2 (1) 4 EXPERIMENT 1 - THE SPECIFIC CHARGE OF AN ELECTRON BY THE MAGNETRON METHOD But for the the circular motion of an electron with speed v me v 2 = evBc , re (2) where e and me have their usual meanings and Bc is the critical magnetic field. From conservation of energy 1 eVa = me v 2 . 2 (3) Combining these equations gives e 8Va 2Va = 2 2 = 2 2. me Bc re Bc ra (4) Hence, e/me can be found from a graph of Bc2 against Va . To determine the critical magnetic field Bc from the corresponding solenoid current Ic , the standard formula is used B = µ0 In √ l , l2 + d2 (5) where n is the number of turns per metre of the solenoid, d its diameter and l its length. Note that µ0 = 4 × 10−7 Hm−1 and the anode diameter of the magnetron (2ra ) is 6.8mm. The turns-per-unit length of the solenoid are given on the solenoid and the other dimensions required can be measured using suitable instruments. Procedure The magnetron should be connected as shown below so that • a current of up to 2A is passed through its cathode filament • a variable voltage of up to 30V can be maintained between its anode and cathode, and the current in this circuit measured. 5 EXPERIMENT 1 - THE SPECIFIC CHARGE OF AN ELECTRON BY THE MAGNETRON METHOD Figure 2: Circuit set-up for the experiment. • the solenoid, with its own power supply, can be placed over the magnetron to provide a variable axial magnetic field. To emit electrons, the filament should be white-hot. Apply current until the filament glows brightly (∼ 1.6 A) but do not exceed 2A. To maximise the life of the tube, do not leave it with the filament heated unnecessarily, i.e. turn down the filament current when not taking readings. As the anode voltage Va is turned up, an anode current Ia will be read on the milliammeter which increases as the anode voltage is increased. In this experiment, the anode voltage is kept fixed while the magnetic field is varied. With the solenoid placed over the magnetron, turn up the solenoid current Is . It will be noted that above a certain value the anode current falls to zero. The aim of this experiment is to determine this critical magnetic field for different values of the anode voltage. Note The solenoid quickly heats up with the current passing through it. This changes its resistance and hence the current flow if the power supply is used in its usual (voltage-control) mode. Better results can be obtained by using the power supply in current-control mode. This is done by turning the current control to zero and the voltage control to 6 EXPERIMENT 1 - THE SPECIFIC CHARGE OF AN ELECTRON BY THE MAGNETRON METHOD maximum, then the current control can be turned up to set the desired current. Caution: Do not pass high currents through the solenoid for longer than necessary. To perform the experiment, the anode voltage Va is set to a number of values between 3V and 20V (chosen with good judgement by the student) and for each setting, a graph of anode current Ia against solenoid current Is plotted. In practice, the anode current does not drop suddenly to zero at the critical current Ic , but falls gradually. Hence the critical current must be determined graphically. This is done by extrapolating the two straight-line segments of the curve and determining their point of intersection, as in Fig.(3). Figure 3: Graph of anode current to solenoid current. The critical current occurs at the turning point Further Reading Grant and Phillips, Electromagnetism, pp 126-128. 7 EXPERIMENT 2 - THE HALL EFFECT Experiment 2 - The Hall Effect Aim To determine the charge carrier density for a number of Hall effect setups. Apparatus Electromagnet and power supply, search coil and galvo, mounted n- and p-type semiconductor chips, electronic millivoltmeter, milliammeter, 6V batteries, rheostat. Note: Do NOT substitute a power supply for the batteries and rheostat since electronic power supplies may generate several millivolts of noise. For similar reasons , an analogue millivoltmeter will be give better results than a digital one in this experiment. Description An electric current consists of moving charge carriers (typically negatively charged electrons). In the presence of a perpendicular magnetic field, these charge carriers will be deflected, creating a potential difference perpendicular to both the magnetic field and the current flow. This is known as the Hall effect. Figure 1: Set-up for the Hall effect. The magnitude of the effect is inversely proportional to the number of charge carriers and so a semiconductor, which has a carrier density some 104 times less than a metal, is used so that the Hall voltage is can be measured using relatively unsophisticated equipment. EXPERIMENT 2 - THE HALL EFFECT 8 To convert the galvanometer readings to the magnetic field, it is necessary to know the sensitivity of the galvo and the size and number of turns of the search coil. The sensitivity of the galvo is 0.007Wb (7×10−3Wb) full-scale, the search coil has an area of 1cm2 and 100 turns (given as 100cm2 - turns). The sensitivity of the combination is thus 7 × 10 − 5 Wb cm−2 or 0.7 Wb m−2 full-scale. The SI unit of magnetic field, the Tesla, is equivalent to 1 Wb m−2 , so this corresponds to a sensitivity of 0.7T full-scale. The current flow I in a conductor with n carriers of charge e per unit volume is given by I = nAve, (1) where A is the cross-sectional area of the conductor and v the drift velocity of the carriers. The force exerted by a magnetic field on the charge carriers is FB = evB = IB . nA (2) As the charge carriers move under this force, they build up an electric field which opposes this motion. The magnitude of this force is FE = Ee = EVH , d (3) where d is the thickness of the chip. At equilibrium, these forces are equal so IB EVH = , nA d (4) or VH = d IB. neA (5) Since all other quantities are known (or can be measured), the sign of e and the carrier density n can be determined. 9 EXPERIMENT 2 - THE HALL EFFECT Procedure The first part of the experiment consists of calibrating the electromagnet. The magnet power supply reads magnet current in Ampéres, while the Hall voltage is a function of the magnetic field. A calibration graph therefore has to be drawn up to convert meter reading in amperes to magnetic field in Tesla. To do this, a search coil is used. It can be shown that the maximum deflection of a heavily-damped (ballistic) galvanometer is proportional to the change of flux through the search coil. Thus, to measure the magnetic field, all that is required is to set the galvo to zero with the search coil far from the magnet, then place the search coil in the field and read the maximum deflection. It is probably easier to zero the galvo with the coil in the field and take the reading after removing the coil: the deflection will be of course equal (and opposite). After applying a suitable conversion factor the magnet calibration curve can be plotted for use in the second part of the experiment. Note The magnet heats up when current passes through it, for this reason ensure that the cooling water is running before applying power. Do not forget to turn off the water when you are finished. Caution The galvo is a sensitive instrument. Ensure that it is unclamped before use, and clamp it again after use. Do not move the galvo while it is unclamped. To measure the Hall effect, the semiconductor chip is placed in the magnetic field and connected as shown in Fig.(2). Note Do not exceed a current of 50mA through the chip. The chip has an adjustment to compensate for manufacturing errors. Since the two side contacts may not be exactly opposite each other, a potential difference may exist between them even without a magnetic field. The knob should be adjusted so that the millivoltmeter reads zero EXPERIMENT 2 - THE HALL EFFECT 10 Figure 2: Circuit set-up for the second part of the experiment. with no applied field, with the maximum current flowing through the chip. Take readings to show that: (a) the Hall voltage is proportional to the applied magnetic field (b) the Hall voltage is proportional to the current through the chip (c) the Hall voltage changes sign between the p-type and n-type semiconductor. Draw diagrams to show that the sign of the Hall voltage indicates that the charge carriers are negatively charged in the n-type semiconductor and positively charged in the p-type semiconductor. Further Reading Grant and Phillips, Electromagnetism, pp 126-128. Blakemore, Solid State Physics, pp 166-167. EXPERIMENT 3 - THE SKIN EFFECT 11 Experiment 3 - The Skin Effect Aim To measure the electrical conductivity of copper. Apparatus Skin-effect apparatus, signal generator, current probe, oscilloscope. Description The solutions of Maxwells Equations in a current-carrying conductor have an exponential decay with depth inside a conductor. This leads to the skin effect, whereby a high-frequency alternating current in a wire is carried essentially only in a thin skin near the outer surface of the wire, while no current flows through the centre of the wire. Theory indicates that for sufficiently thick wires (ie. the wire surface can be considered as an infinite flat plane) the distribution of current varies exponentially with depth z I = I0 e−z/δ , (1) where δ is the skin depth, the depth at which the current falls to 1/e of its value at the surface. Thus, graphs of log I against z should be a straight line of slope −1/δ. The dependence of δ on frequency is given by the relation r 2 , δ= µµ0 σω (2) where µ is the permittivity of the material (about 1), σ its conductivity and ω the angular frequency (= 2πf ). A further graph should be drawn to verify this relation and obtain a value for σ which can be compared to the standard value for copper obtained from tables. As a guide, the skin depth for copper is about 1cm at 50Hz, decreasing with the square-root of the frequency to less than 10-3cm at 50MHz. 12 EXPERIMENT 3 - THE SKIN EFFECT Figure 1: The compound conductor interior. Procedure The apparatus consists of a composite wire made up of several smaller wires packed together (see diagram). Over a short distance in the centre, the individual wires are separated so that the current in each can be measured using the current probe. The current probe is a ferrite toroid that can be clipped round a wire. The magnetic field caused by the current in the wire induces a proportional voltage in a coil wound on the toroid, which can be measured using the oscilloscope. The other channel of the oscilloscope should be connected directly to the signal generator and used for triggering the timebase, thus ensuring stable display even with a small noisy signal. 13 EXPERIMENT 3 - THE SKIN EFFECT The procedure is thus to set the signal generator to a given frequency and pass as large a current as possible through the apparatus. The apparatus appears essentially as a short-circuit across the signal generator, which is thus not operating in an ideal situation. The current should not be turned up beyond the point at which distortion becomes evident. At a fixed frequency, the current in wires at different distances from the surface of the bundle can then be measured. Although the current probe is calibrated (in Volts output per Ampére), this is not needed in this experiment since it is just a constant of proportionality. Several wires at the same “depth” should be sampled to obtain an average. The procedure can then be repeated at different frequencies. Further Reading This experiment is based on an article in American Journal of Physics Vol 44 no. 10 (October 1976), pp 978-980, and was constructed by Dr. Pauline Galea while a B.Sc. student as her final-year project. A derivation for the formula for the skin depth can be found in Grant and Phillips, Electromagnetism, pp 379-383. EXPERIMENT 4 - PHYSICS WITH A CAR HEADLAMP 14 Experiment 4 - Physics with a car headlamp Aim To determine the efficiency of a tungsten filament light bulb. Apparatus 12V Digital power supply unit (p.s.u.), 60/50 W car headlamp, thermometer. Background In this experiment, you will try to answer some real-life questions on the tungsten filament of a car headlamp, such as • How efficient is the halogen gas-filled lamp with a tungsten filament? • What temperature does the filament reach? • In what part of the electromagnetic spectrum is most of the radiation emitted from the hot lamp? In order to answer the above questions, one needs to do a lot of data analysis, and hence in this experiment, you will realise how spreadsheet programs, are indispensable for large amounts of data manipulation. Description When a lamp has reached a steady state, the electrical power dissipated in the filament must be equal to the total rate of heat lost from the filament, due to conduction, convention and radiation. However, when the lamp is glowing, we can safely assume that most of the energy is lost by radiation and so the electrical power dissipated in the filament, Pel = V I, is effectively equal to the power lost by radiation, Prad . In the first part of the experiment you will check whether the empirical formula m R T = Ts , (1) Rs EXPERIMENT 4 - PHYSICS WITH A CAR HEADLAMP 15 is valid, where R is the resistance at the temperature T and Rs is the resistance at the room temperature Ts . Thus, using Eq.(1), one can estimate the temperature T of a halogen lamp at a given resistance R. Incidentally, m is a constant whose value can be found from the experimental results as explained below. To find m If we assume that the hot tungsten filament behaves as a greybody the net power radiated, to a good approximation, is described by the StefanBoltzmann law Prad = Aσ T 4 − Ts4 , (2) where the filament is at a temperature T and the surrounding room temperature is Ts is the emissivity of the filaments surface, A is the area of the surface from which the radiation is emitted and σ is the StefanBoltzmann constant. For a blackbody surface, = 1; for other surfaces, the emissivity is a complicated function of temperature, environment and fabrication (Incropera and De Witt,1990). However, to simplify the analysis the following assumptions are made about the filament • Its emissivity is constant and independent of the temperature, • It has a uniform surface temperature, • All the radiation is emitted from its surface. For the filament, the constants A and are unknown. However, these two unknown quantities can be eliminated by taking a ratio. If P1 is the power when the filament just starts to glow brightly at a temperature T1 (T14 < Ts4 ) and Pi is the power at a higher temperature Ti then, 4 Pi Ti = . (3) P1 T1 Combining Eqs(1, 3), it is possible to relate the power radiated to the resistance of the filament Pi Ri log = m 4 log . (4) P1 R1 If the predictions given by Eqs.(1,2) are valid, a plot of log(Pi /P1 ) against 4 log(Ri /R1 ) will yield a straight line with slope m through the origin. EXPERIMENT 4 - PHYSICS WITH A CAR HEADLAMP 16 In this way the temperature the filament reaches can be calculated. But what about the efficiency of the car headlamp? We will try to answer these questions in the second part of the experiment. Tungsten Efficiency Assuming that the tungsten filament radiates as a greybody, then the spectrum of the emitted radiation will be given by the Planck distribution function (Eisberg and Resnick 1985) p (λ) dλ = N dλ, λ5 ehc/λkT − 1 (5) where p (λ) dλ is the radiant power emitted in the wavelength interval λ and λ + dλ with p(λ) being the power emitted per unit wavelength in this interval, N is a normalising factor, λ is the wavelength of the emitted radiation, h is the Planck constant, c is the speed of light and k is the Boltzmann constant. The integral over all wavelengths of the function p(λ) given by Eq.(5) equals the total power radiated by the hot filament at a temperature T , i.e. Z Prad = p (λ) dλ. (6) With a spreadsheet this integral can be evaluated numerically and the value of N adjusted so that the integral is equal to the input power, Pel . The luminous efficiency of the lamp is defined as the ratio of the power radiated in the visible part of the spectrum to the input power. Thus, the efficiency of the lamp can be found by comparing the ratio of areas under the Planck distribution curve. Procedure First note the room temperature Ts and then set up the following simple circuit. Using a digital power supply unit one can vary the voltage across the lamp and then read the corresponding current. • Start increasing slowly the voltage across the lamp until the filament lamp just starts to glow brightly. Note the voltage V1 (approximately about 1V) and the corresponding current I1 . 17 EXPERIMENT 4 - PHYSICS WITH A CAR HEADLAMP Figure 1: Circuit set-up for the experiment. • Afterwards, take about 60 current readings for voltages between 0.2V-12V, i.e. in 0.2V steps. As the voltage is increased it is necessary to wait before the readings are recorded so that an equilibrium is established. • Finally, take 3 more readings in the range 13V-15V, (i.e. in 1V steps). The steps for the data analysis of the experiment are as follows 1. Input the data in some Worksheet program and hence plot the I-V characteristic of the lamp. 2. For each pair of values, calculate the resistance R (= V /I) of the filament and the dissipated power P (= V I). Plot an R-I graph. 3. The room temperature resistance Rs can now be found by extrapolating the R-I graph to find the resistance at zero current. Note you might notice some deviation from linearity for small values of the resistance. In order to handle this situation the points that deviate from linearity will have to be ignored. These points should be clearly marked on the graph (Hint: make two data series and use a legend). State the reason(s) that caused the deviation from linearity that has been observed in the discussion. 4. Thenext calculate the constant m. Verify the relationship step is to log PP1 = 4m log RR1 and hence calculate the value of m using linear regression analysis tools. EXPERIMENT 4 - PHYSICS WITH A CAR HEADLAMP 18 5. Now, the temperature T (in Kelvin) of the filament is related to its resistance R by m R T = Ts . (7) Rs Since Ts , Rs and m are now known, plot a graph of R vs. T and comment. 6. In the final part of this experiment you will try to calculate the luminous efficiency of the lamp. Recall, that if we assume that the Tungsten filament lamp radiates as a grey body, the spectrum of the emitted radiation is given by Eq.(5), i.e. p (λ) dλ = N λ5 ehc/λkT − 1 dλ. (8) (a) Set up a column of about 500 wavelength values ranging from 200nm to 9200nm, i.e. ( dλ ' ∆λ = 18nm). (b) Let T be the maximum temperature of the filament (i.e. at 15V). For each value of λ, calculate the right hand side of Eq.(5). The value of the normalising constant N should be adjusted to make the area under the graph equal to the power dissipated at that temperature. (Hint: Find the area of the rectangle subtended by each dλ and sum). (c) Plot a graph of Power / wavelength interval (W/nm) vs. wavelength (nm). (d) Sum the values of p(λ)dλ for λ values in the range 400nm 700nm (visible range). Sum all the values of p(λ)dλ (i.e. from 200 - 9200nm) Express these two sums as a percentage ratio. This percentage ratio is the luminous efficiency of the car headlamp. Comment on your result. Useful Constants Plancks constant (h) = 6.62608 × 10−34 Js, Boltzmanns constant (k) = 1.38066 × 10−23 JK1 , Speed of light (c) = 2.99792 × 108 ms−1 . 19 EXPERIMENT 4 - PHYSICS WITH A CAR HEADLAMP Further Reading F. S. Levin, An Introduction to Quantum Theory. Cambridge University Press, 2002. 20 EXPERIMENT 5 - DETERMINATION OF THE RATIO OF THE SPECIFIC HEAT CAPACITIES OF AIR BY THE CLÉMENT AND DESORMES’ METHOD Experiment 5 - Determination of the ratio of the specific heat capacities of air by the Clément and Desormes’ method Aim To find the adiabatic constant of air. Apparatus The apparatus is assembled. Description Let the v1 be the specific volume of air at the ambient temperature T0 and at a high pressure P1 . If the gas is expanded adiabatically to the atmospheric pressure P0 its new specific volume, v0 , would be given by P1 v1γ = P0 v0γ , (1) where γ is the ratio of the specific heat capacity of the gas. Such an expansion would have decreased the temperature of the gas. However on letting the gas to get back to the ambient temperature T0 at constant volume a new pressure P2 would result. Considering the isothermal process that occurs on going from the initial stage to the final stage (i.e. ignoring the adiabatic expansion), the following equation is obtained P1 v1 = P2 v0 . Therefore using Eq.(1) P0 = P1 V1 V0 (2) γ , (3) and using Eq.(2) V1 P2 = . V0 P1 Eliminating v0 and v1 from Eqs(3,4) gives γ P0 P2 = . P1 P1 (4) (5) 21 EXPERIMENT 5 - DETERMINATION OF THE RATIO OF THE SPECIFIC HEAT CAPACITIES OF AIR BY THE CLÉMENT AND DESORMES’ METHOD Taking logarithms on both sides P0 P2 = γ log . log P1 P1 (6) Making γ subject of the formula γ= log (P0 /P1 ) . log (P2 /P1 ) (7) In the case were the pressure difference is very small then an alternative approach can be taken. If h1 is the initial difference in the levels of the manometer and h2 the final difference in the levels, we have P1 = P0 + ρgh1 , P2 = P0 + ρgh2 . Thus and P1 − ρgh1 ρgh1 P0 = =1− , P1 P1 P1 (8) P2 P1 − ρg (h1 − h2 ) ρg (h1 − h2 ) = =1− , P1 P1 P1 (9) which implies that Eq.(5) ρgh1 1− = P1 γ ρg (h1 − h2 ) 1− . P1 (10) If it is assumed that ρg (h1 − h2 ) << P1 then the expansion 1− ρg (h1 − h2 ) ρgh1 ≈1−γ , P1 P1 (11) can be taken. Hence 1 h2 = 1 − h1 . γ (12) Repeat the experiment for six different values of h1 and each time finding the corresponding value of h2 . (Note no repeated readings will be requested in this case) Hence γ can be found. 22 EXPERIMENT 5 - DETERMINATION OF THE RATIO OF THE SPECIFIC HEAT CAPACITIES OF AIR BY THE CLÉMENT AND DESORMES’ METHOD Procedure Close the stopcock which is directly open to the atmosphere. Pump some air inside the carboy until the pressure on the manometer is 15 cm of water above atmospheric. Allow fifteen minutes to elapse so that the temperature of the air inside the bulb reaches the outside temperature. Open the same stopcock suddenly (about 1/2 s once the pressure begins to change, i.e. the manometer level begins to move) until the pressure inside becomes atmospheric and close the stopcock again. Obviously the levels of the water in the manometer will be the same at first, but a rise in temperature due to the passage of heat from the outside into the vessel (the air inside having been cooled due to the sudden expansion) will result in an increase in the pressure inside the carboy. This will increase the manometer levels until they become steady. Record the final difference in the levels together with the original pressure inside the carboy. Further Reading Francis Weston Sears and Gerhard L. Salinger, Thermodynamics, Kinetic Theory, and Statistical Thermodynamics, Third Edition. 23 EXPERIMENT 6 - FORBE’S BAR Experiment 6 - Forbe’s Bar Aim To determine the thermal conductivity of copper. Apparatus Copper bars (Forbes bar, and a calibration bar), boiler, two hotplates, thermocouple and millivoltmeter, vacuum flask with ice, beaker, mercury thermometer. Description A copper rod has one end held at 100◦ C by means of a steam jacket. At steady state, a temperature gradient is established along the rod that can be measured using thermocouple. Analysis of the results enables the thermal conductivity k of the rod to be determined. The temperature gradient along the bar in steady state satisfies the continuity equation d2 θ (1) kA 2 = P H, dx where k is the thermal conductivity of the material, A the cross-sectional area of the bar, P the perimeter of the bar, H is the rate of heat loss per unit length of the bar. Integrating the above equation x 2 Z x2 Z dθ mc x2 dθ kA =P H dx = P dx, dx x1 S x1 dt x1 (2) where x1 and x2 are tow distances along the bar and m, c and S are respectively the mass, specific heat and surface area of the calibration bar which can be assumed to have the same heat loss characteristics as the large bar (note that A and P refer to the large bar). 24 EXPERIMENT 6 - FORBE’S BAR The Left-Hand-Side of the equation can be evaluated by drawing tangents to the curve of θ against x at two positions x1 and x2 , and finding the difference in their slopes. The Right-Hand-Side (RHS) of the equation can be evaluated by drawing tangents to the curve of θ against t and plotting a graph of (dθ/dt) against x (the corresponding values of x for each t can be obtained from the first graph). The integral in the RHS of the equation is then given by the area under the curve of this third graph, between the positions x1 and x2 . In the above equation the only unknown is the thermal conductivity k of the bar which can thus be found. Procedure Since it takes a long time (at least 2 hours) for the bar to reach thermal equilibrium, the first step is to ensure that the steam generator is full of water and to turn it on. Aim to keep a steady flow of steam through the apparatus throughout the experiment, but do not let the boiler run dry. Top up (carefully) when required. While the bar is warming up, the thermocouple should be calibrated. First check the thermocouple wires and their connection to the millivoltmeter. Check also that the cold junction is held securely in place in an ice-water mixture, the use of a vacuum flask means that the ice will last the duration of the experiment. Check the polarity by warming the hot junction with your fingertips - if the meter reading decreases, change the junctions over or connect the meter in the opposite polarity. To calibrate the thermocouple, place the hot junction in a beaker of water on the second hotplate, together with the mercury-in-glass thermometer. Note the thermocouple output at various temperatures between room temperature and 100◦ C. Before commencing the experiment, it is important to ensure that the bar has reached a steady state. This means that the temperature at EXPERIMENT 6 - FORBE’S BAR 25 any point on the bar does not change over an appreciable period of time (several minutes). Once steady state is reached, the temperature θ can be measured as a function of position x along the bar, and a graph plotted. The final step is to obtain a measure of the rate of heat loss from the bar. This is done by heating the calibration bar to above the highest temperature recorded, and letting it cool in a similar environment while measuring its temperature φ as a function of time t, and a graph plotted. The length, diameter and mass of the calibration bar should be measured as well as the diameter of the Forbes bar, and the specific heat of copper obtained from a data book. The steps for the data analysis of the experiment are as follows 1. Sketch the calibration graph of change in temperature against voltage. Should be linear? 2. Sketch a graph of change in temperature against x. How should this fall off as? 3. Sketch a graph of change in temperature against time for the calibration bar. 4. Finally use the x positions in the second graph to correlate dθ/dt with the x positions. For each position find the respective change in temperature through the second graph then using the gradient of the third graph find dθ/dt. Lastly sketch the graph dθ/dt. 5. Determine the thermal conductivity k of copper using Eq.(2) Further Reading Francis Weston Sears and Gerhard L. Salinger, Thermodynamics, Kinetic Theory, and Statistical Thermodynamics, Third Edition. 26 EXPERIMENT 7 - MEASURING THE LINEAR EXPANSION OF SOLIDS AS A FUNCTION OF TEMPERATURE Experiment 7 - Measuring the linear expansion of solids as a function of temperature Aim Determining the linear expansion coefficients of brass, steel and glass. Apparatus Longitudinal expansion apparatus, Dial gauge, Circulation thermostat with pump and thermometer, water tubing, glass, steel and brass tubes, small beaker, Mercury thermometer, Measuring tape. Theory In response to a change in temperature a body will change its dimensions. For a protruding dimension of length l consider the linear dependence of the rate of change of length with respect to temperature per unit (reference) length 1 ds = α, (1) l0 dθ where l0 is the original length (at some reference temperature). Solving this gives the length at any temperature θ1 as l1 = l0 (1 + α∆θ) , (2) where ∆θ = θ1 − θ0 . Now the constant α does depend on the material under investigation, not the original length of the material under investigation. It should also be noted that this is an approximation, if the readability interval of the measuring device were rendered smaller then higher order terms would become significant as well. In this experiment a circulation thermostat is used to heat the water which flows through the various tube samples. A dial gauge with 0.01 mm scale graduations is used to measure the change of length ∆l a function of temperature θ. 27 EXPERIMENT 7 - MEASURING THE LINEAR EXPANSION OF SOLIDS AS A FUNCTION OF TEMPERATURE Figure 1: Schematic representation of the experimental setup to measure the linear thermal expansion of tubes with the expansion apparatus as a function of temperature. Using the Circulation Thermostat Unit The unit contains a pump, thermometer and a heating component. The pump should NOT be switched on unless the water level is above the pump inlet (that is more than half way full). If any warming signals appear switch of the device and seek out one of the laboratory attendants. Once the in- and out-lets have been connected to the tube under investigation and the forward tank filled with water the unit can be switched on. This is achieved by turning on the power switch located on the back of the unit as well as the power button on the front side of the unit. The temperature can be changed by unit the arrows and selecting with temperature on the control screen with the center (control) button. Using the arrows the value can be changed and then confirmed by pressing the center button again. In order to take readings wait for the temperature to settle as much as it can as well as eliminating as many environmental sources as possible. Procedure 1. Carefully secure the brass tube onto the longitudinal expansion apparatus. This means screwing in the tube such that the dial reading moves slightly. 2. Measure the length of the brass tube with the measuring tape and 28 EXPERIMENT 7 - MEASURING THE LINEAR EXPANSION OF SOLIDS AS A FUNCTION OF TEMPERATURE the room temperature with the thermometer. 3. Take note of the dial reading, this will be the reference value used in the change of length calculation. 4. Use the Circulation thermostat to pump heated water through the tube under investigation. Length and temperature should be noted every 5◦ C in the range 35◦ C − 95◦ C. The real temperature should be noted as opposed to the target temperature. 5. Take repeated 3 readings (first raising the temperature, then decreasing it, and finally increasing it again). In order to decrease the temperature it may be needed that water is exchanged with supply water. 6. Plot a graph of change in length against change in temperature and determine the α coefficient. Compare this to community values. 7. The process should be repeated for the steel and glass tubes. Further Reading Francis Weston Sears and Gerhard L. Salinger, Thermodynamics, Kinetic Theory, and Statistical Thermodynamics, Third Edition. 29 EXPERIMENT 8 - THE CONTINUOUS-FLOW CALORIMETER Experiment 8 - The Continuous-Flow Calorimeter Aim To determine the specific heat capacity of water. Apparatus Callender and Barnes calorimeter, constant-head device, two 0.1C mercury thermometers, 4A power supply with ammeter and voltmeter, stopwatch, measuring cylinder. Description Calorimetry as a means of measuring the specific heat of a substance is complicated by the effects of heat losses. In a continuous-flow calorimeter, two measurements can be taken at identical temperatures, thus enabling the effects of heat losses to be cancelled out. In its simplest form, the calorimeter consists of a tube through which water flows at a known rate. Heat is added to the water by an electric heater, also at a known rate, and the temperature rise measured. The rate of flow is then altered and the electrical power input varied to obtain the same inlet and outlet temperatures as before. From the two sets of results, the specific heat of water can be determined to an accuracy set essentially by the precision of the thermometers used. If m is the mass of water of specific heat capacity c that flows through the calorimeter in unit time, then the temperature change expected is given by IV = mc∆θ, (1) where IV is the electrical power input, ∆θ the temperature change across the apparatus and H the rate of heat loss. If the experiment is repeated with the same mean temperature and hence 30 EXPERIMENT 8 - THE CONTINUOUS-FLOW CALORIMETER the same rate of heat loss, then for the two experiments I1 V1 = m1 c∆θ1 , I2 V2 = m2 c∆θ2 , (2) (3) from which H can be eliminated and c determined. Procedure This experiment has two variables that can be adjusted, the flow rate and the electrical power. Before starting the experiment, make an estimate of the required flow rate to give an acceptable rise in temperature, given that the current in the heater should not exceed 4A. If the flow rate is too high, the temperature difference will be low compared to the precision of the thermometers. Remember that you also need to perform the experiment at a second flow rate, which can only be lower than the first since the electrical power input cannot be increased further. Set up the apparatus and measure the flow rate by measuring the amount of water flowing through the apparatus in a known time. The flow rate can be varied by altering the height of the constant-head apparatus, or by applying a clip to one of the hoses. After switching on the heater, ensure that the apparatus has reached steady state before recording the current, voltage and temperature readings. This can be checked by seeing that the temperature readings do not vary over a period of several minutes. Reduce the flow rate and repeat the experiment, adjusting the electrical power input to get the inlet and outlet temperatures as close as possible to those in the first experiment. If the inlet temperature changes, aim to get the average of the two temperatures as close as possible to the average in the first experiment. Using a linear combination of Eqs.(2, 3) the specific heat capacity can be determined. (This experiment has no associated graph). 31 EXPERIMENT 8 - THE CONTINUOUS-FLOW CALORIMETER Further Reading Francis Weston Sears and Gerhard L. Salinger, Thermodynamics, Kinetic Theory, and Statistical Thermodynamics, Third Edition. 32 EXPERIMENT 9 - VERIFICATION OF CAUCHY’S FORMULA Experiment 9 - Verification of Cauchy’s Formula Aim To determine the material under investigation through a comparison table and the determination of the Cauchy constants. Apparatus Spectrometer, prism, variety of spectral lamps (sodium, mercury and cadmium suggested). Description In general the variation of the refractive index µ of a material as a function of the wavelength λ can be expressed as a polynomial expansion µ=A+ C B + + ... = λ2 λ4 X n∈{0,1...} Ci , λ2n (1) provided that the wavelength is well away from an absorption band (i.e. the material is transparent at that wavelength). Often the first two terms are sufficient to obtain good agreement with experimental results, leading to Cauchys Formula µ=A+ B . λ2 (2) The aim of this experiment is to verify this relationship and determine the value of the constants A and B. If δm is the angle of minimum deviation (change in angle between ingoing and outgoing rays) and α the apex angle of the prism (angle subtended opposite shaded side), then the refractive index µ is given by m sin α+δ 2 µ= . sin α2 (3) 33 EXPERIMENT 9 - VERIFICATION OF CAUCHY’S FORMULA Spectral lines Sodium (yellow) 589.6 nm (close double) Mercury (yellow) 578.0 nm (close double) (green) 546.1 nm (blue) 491.6 nm (weak) (violet) 435.8 nm Cadmium (red) 643.8 nm (blue-green) 508.6 nm (blue) 480.0nm Procedure Mount the glass prism on the spectrometer table and set up the spectrometer (refer to your first year lab notes if necessary). Then, using the sodium source, determine the apex angle of the prism. Still using the sodium source, determine the angle of minimum deviation at that wavelength. Repeat the measurement of the angle of minimum deviation with various spectral lines from other spectral lamps. A selected list of wavelengths is given below, however other lamps may be used although their wavelengths will have to be looked up in a data book. From the angles of minimum deviation, calculate the refractive index at each wavelength. Then draw a suitable graph to verify Cauchy’s formula and determine the values of the coefficients A and B. Hence deduce the material under investigation. Further Reading Jenkins and White, Fundamentals of Optics, Fourth Edition. pp 3032 (angle of minimum deviation) pp 438-456 (sources of light and their spectra) pp 474-482 (dispersion) 34 EXPERIMENT 10 - THE BALMER SERIES Experiment 10 - The Balmer Series Aim To compare the experimentally obtained Rydberg constant to the one derived from quantum theory. Apparatus Spectrometer, diffraction grating, hydrogen and deuterium spectral lamps. Description In 1855, Balmer obtained an empirical relation for the wavelengths of the spectral lines of hydrogen in the visible region 1 1 1 = RH − n = 3, 4, 5, (1) λ 22 n2 where RH is known as the Rydberg constant for hydrogen and has the standard value of 1.1 × 107 m−1 . The major success of the Bohr theory of the hydrogen atom (1913) was in explaining this seemingly arbitrary formula. In this experiment, the wavelengths of the visible spectral lines of the hydrogen spectrum are determined using a grating spectrometer, so as to verify the above formula and obtain an experimental value for RH . Diffraction grating formula nλ = d sin θ. (2) The Bohr theory gives the radius of the nth atomic orbital of an atom of proton number Z as 4π0 n2 ~2 , (3) rn = 2 e Zme where me is the mass of the electron and the other symbols have their usual meaning (~ = h/2π). EXPERIMENT 10 - THE BALMER SERIES 35 The energy associated with this orbit is Ze2 E=− , 8π0 r whence En = − e2 Z 2 me (4π0 )2 2n2 ~2 (4) , (5) so that the energy difference between two levels n and m (n > m), and thus the energy of a photon emitted by a transition between these two levels, is given by e4 Z 2 me 1 1 1 hc 1 = − 2 = Z 2 RE − , (6) En − Em = 2 2 2 λ n m2 n2 2~ (4π0 ) m so that e4 me RE = . 2~2 (4π0 )2 (7) What does this give for the Rydberg constant? How is this an explanation of the phenomenon? Transitions to the innermost orbit (m = 1) have energies in the ultraviolet region and are named the Lyman series after their discoverer. The Balmer series correspond to transitions to the second orbital, with m = 2. Note also that the Rydberg constant RH is expressed in terms of only fundamental constants in the quantum theory. Procedure Mount the diffraction grating on the spectrometer table and set up the spectrometer (refer to your first year lab notes if necessary). The lines emitted by the hydrogen lamp are very dim, so in performing the experiment ensure that: (a) the room is as dark as possible (b) the spectral lamp is well shielded to avoid stray light (c) the spectral lamp has reached its operating temperature and hence maximum brightness - this can take up to 15 minutes 36 EXPERIMENT 10 - THE BALMER SERIES (d) your eyes are well accustomed to the darkness. This can also take several minutes. You should be able to see at least three spectral lines in the first order (red, blue-green, deep blue and possible violet), and perhaps one or two in the second order. Take as many measurements as you can since the accuracy of your calculations can be improved by taking the average of several readings. Having calculated the wavelengths of each line (the red corresponds to n = 3), plot a suitable graph to verify Balmers formula and obtain a value for RH using both the gradient and intercept as the two experimentally obtained Rydberg constants. If time permits, repeat the experiment with the Deuterium (2 D) source. What difference (if any) would you expect to see in your results? Further Reading Semat and Albright, Introduction to Nuclear Physics, Fourth Edition. pp 219-232 Jenkins and White, Fundamentals of Optics, Fourth Edition. pp 611-631 37 EXPERIMENT 11 - THE COMPOUND PENDULUM A Experiment 11 - The compound pendulum A Aim To find a number of values of the radius of gyration for a compound pendulum. Apparatus Compound pendulum, stop watch, pivot. Theory Consider the uniform rigid rod shown in Fig.(1), where the centre of mass is at G and the point of suspension is at O such that the rod can swing freely in the vertical plane about a horizontal axis through O. When the rod is displaced by an angle (φ) from the vertical, the restoring torque (τ ) is given by τ = −mgh sin φ. (1) Figure 1: Experimental set-up. If the rod is now released it will oscillate. The angular acceleration EXPERIMENT 11 - THE COMPOUND PENDULUM A 38 (d2 φ/dt2 ) is given by d2 φ τ = −I 2 , (2) dt where I is the moment of inertia of the rod about O. Now if I is the moment of inertia of the rod about an axis through G, such that I0 = mk 2 , where k is the radius of gyration of the rod about G, then by the parallel axes theorem I = I0 + mh2 . (3) Thus I = m k 2 + h2 . (4) Now, from Eqs.(2, 3), the governing equation of motion is d2 φ + gh sin φ = 0, dt2 d2 φ gh sin φ + = 0. dt2 I I (5) (6) For small angles of φ, Eq.(6) may be approximated to d2 φ ghφ + = 0. dt2 I This describes S.H.M. with period T given by s I T = 2π , mgh and on substituting for I from Eq.(6) s k 2 + h2 T = 2π . gh (7) (8) (9) Now, for a simple pendulum, the period for small oscillations is given by s l T0 = 2π . (10) g Then, a simple pendulum with period T0 = T for a compound pendulum would have a length l0 which may be obtained by comparing Eq.(9, 10) l0 = k 2 + h2 , h (11) EXPERIMENT 11 - THE COMPOUND PENDULUM A 39 where l0 is the simple pendulum equivalent length (i.e. a simple pendulum length that gives a period equal to that of a compound pendulum at a given h). We can write Eq.(11) as h2 − l0 h + k 2 = 0. (12) Thus, there will be two values of h that give the same period with an associated equivalent length lo. Let these be h1 and h2 such that these are the roots of Eq.(12). Then q 1 1 2 h1 = l0 + l0 − 4k 2 , (13) 2 2 and similarly 1 1 h2 = l0 − 2 2 q l02 − 4k 2 , (14) which implies that h1 h2 = k 2 and h1 + h2 = l0 . As shown in Fig.(2), if T is plotted against h two branches are obtained, one corresponding to O placed between A and G and the other corresponding to O placed between B and G. Figure 2: Expected graph of period against distance from pivot. From Eq.(9), with h = 0 (i.e. O on G), T is infinite. From Eq.(13,14) the least value of l0 for real roots is 2k and this corresponds to minimum T (Fig.(2)) It is seen from Fig.(2) that any horizontal line drawn above the minima intersects the curves at four points corresponding to h1 , h2 , h2 and h1 respectively for a given value of T . EXPERIMENT 11 - THE COMPOUND PENDULUM A 40 Procedure 1. Find G by balancing the rule on a knife edge 2. Determine T as a function of h by moving the pivot to as many different points along the rod as possible. 3. Plot a graph of T against h as shown in Fig.(2). Draw a set of lines parallel to the h-axis across your graph and determine a set of values of l0 . 4. From your graph determine two values for the radius of gyration and hence obtain a mean value. 5. Compute another value for the radius of gyration using the following theoretical relation L k=√ , (15) 12 where L is the length of the rod. 6. Plot another graph of T 2 h against h2 and obtain two other values for k and then find an average. Is the rod uniform? 7. Plot a final graph of T 2 h against h2 and determine a further value for k. Compare all the values that you have found for the radius of gyration. Further Reading Francis Weston Sears and Gerhard L. Salinger, Thermodynamics, Kinetic Theory, and Statistical Thermodynamics, Third Edition.