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PHYSICAL CHEMISTRY I (01:160:327) SYLLABUS AND GENERAL INFORMATION FALL 2014 Lectures: M W 6:40 - 8:00 PM Recitations: Sec 01 Sec 02 Lecturer & Recitation Instructor: WL-AUD W 5:25 – 6:20 PM SEC-216 M 8:15 – 9:10 PM SEC-209 Dr. Martha Cotter Office: Wright Lab 158 (Busch) Phone: 848-445-2259 e-mail: [email protected] Office hours: M 4:00 - 5:45 PM, F 4:30 - 6:00 PM, or by appointment Textbook: Engel and Reid, Thermodynamics, Statistical Thermodynamics, & Kinetics, 3rd Edition Major topics to be covered: classical thermodynamics, statistical thermodynamics, phase and reaction equilibria, solutions, and kinetics Hourly Exams (in lecture): Monday, October 13th Monday, November 17th Final Exam: Wednesday, December 17, 12-3 PM locations to be announced Quizzes: There will be four 20-point quizzes given in recitation on dates to be announced. The lowest quiz grade will be dropped. Homework and recitation participation: Assigned homework problems relevant to each lecture topic are given on the lecture schedule. Your solutions to the assigned problems will be collected in recitation on the dates indicated and credit will be given for a conscientious effort to complete them. Credit will also be given for active participation in recitation activities. Grading: There will be a total of 500 points possible in the course, distributed as follows: hourly exams 2 x 100 pts final exam quizzes 3 x 20 pts homework & recitation participation total = = = 200 pts 200 pts 60 pts = = 40 pts 500 pts 2 Long-Range Learning Goals: At the end of this course, you should have a solid understanding of the basic principles and techniques of classical thermodynamics, statistical thermodynamics, and kinetics, which you should be able to apply in future studies and in your career in science or a related field. be able to apply your knowledge of thermodynamics/kinetics to physical transformations, chemical reactions, phase and chemical equilibria, and solutions. have an enhanced ability to use mathematics, particularly calculus, as a tool to solve complex chemical and physical problems, starting from first principles. have enhanced analytical reasoning and problem-solving skills. Study Tips: Your performance in Chem 327 will greatly be enhanced by doing the following: 1. Attend lecture regularly. In lecture, I will emphasize important topics, clarify difficult points, and do sample problems similar to those on quizzes and exams. 2. Make a serious effort to solve all the assigned problems before they are due in recitation. Many quiz and exam problems will be similar to homework problems. 3. Attend and actively participate in recitation each week. Recitation will provide many opportunities to master important concepts and improve your problem-solving skills. 4. Keep up with the course assignments. Experience has shown that students who get seriously behind are rarely able to catch up and do well in the course. Course Website: You are encouraged to make maximum use of the Chemistry 327 website, which is accessed through the sakai portal at https://sakai.rutgers.edu/portal. (Login using your netID and password, then choose 01:160:327:F14.) The website features copies of lecture notes, course handouts, and practice exams, plus an announcements board for posting of course announcements. The lecture notes, practice exams, and most of the handouts are pdf files. To read them you must have Adobe Acrobat Reader, which can be downloaded (free) from the Adobe website http://www.adobe.com. You are responsible for checking the announcements board regularly for important course announcements. Academic Integrity: All University policies on academic integrity will strictly be enforced. Any cheating on quizzes, exams, or other assignments or any facilitating of academic dishonesty by others will be dealt with promptly in strict accordance with the Rutgers University Academic Integrity Policy. A copy of the current Academic Integrity Policy, which went into effect on September 1, 2013, can be found at http://studentconduct.rutgers.edu/files/documents/AI_Policy_2013.pdf Please read the policy carefully if you are not familiar with it. CHEMISTRY 327 - FALL 2014 LECTURE SCHEDULE & ASSIGNED PROBLEMS LECTURES 1-13 LEC # DATE TOPIC(S) SECTIONS IN E&R ASSIGNED PROBLEMS* 1 W, 9/03 2 M, 9/08 3 4 W, 9/10 M, 9/15 course intro math background math background cont’d intro to thermodynamics 1st law of thermo internal energy & enthalpy (math handout) Appendices B2,4,6 (math handout) 1.1-1.5 2.1-2.3,2.5-2.8 2.9-2.11, 3.1-3.7 5 W, 9/17 thermochemistry 4.1-4.5 6 entropy & the 2nd law of thermo entropy & the 2nd law cont’d 5.1,5.4-5.7,5.12-5.13 8 M, 9/22 (Q1) W, 9/24 (Q1) M, 9/29 problems from math handout math handout probs P1.4,11,25 P2.6,19,24; EP1 P2.27,35; P3.3,11 EP2,EP3 P4.8,14,17a-c,22 EP4 Q5.1,2,3,8 P5.12,26 P5.6,20, 29;EP5 9 W, 10/01 10 12 M, 10/06 (Q2) W, 10/08 (Q2) M, 10/13 W, 10/15 13 M, 10/20 7 11 * 5.4,5.12-5.13 cont’d 5.2-5.3,5.14 5.8-5.10 6.1,6.3,6.7 6.2 third law of thermo P5.28,45; EP6 Gibbs and Helmholtz energies P6.1,5,32;EP7 putting it all together P3.10,25-27 review for exam 1 EP8,EP9 chemical potential; mixing & 6.4-6.6,6.8,6.12 Q6.3-5, P6.8,22 chem. equilib.in ideal gases EP10 equilibrium calculations 6.9-6.11 P6.6,30,38a,b Le Chatelier’s principle 6.13 EP11,EP12 Exam I (lectures 1-9) statistical thermodynamics: (lecture notes 8, Pt 1) P12.6,8,12,28,30a-c background & fundamentals 12.1-12.5; 14.1 application to classical (lecture notes 8, Pt 2) Q14.1,2; P14.1,42 ideal gases 14.2-14.4 EP13 EP = extra (assigned) problem DUE DATE FOR PROBLEMS Sec 02 Sec 01 9/15 9/17 9/15 9/17 9/15 9/22 9/17 9/24 9/22 9/24 9/29 10/01 9/29 10/01 10/06 10/08 10/06 10/08 10/20 10/22 10/20 10/22 - 10/27 10/29 10/27 10/29 CHEMISTRY 327 - FALL 2014 LECTURE SCHEDULE & ASSIGNED PROBLEMS LECTURES 14-26 LEC # DATE TOPIC(S) 14 W, 10/22 15 17 M, 10/27 (Q3) W, 10/29 (Q3) M, 11/03 18 W, 11/05 19 21 M, 11/10 (Q4) W, 11/12 (Q4) M, 11/17 W, 11/19 application to ideal gases – cont’d relation to classical thermodynamics relation to classical thermo – cont’d phase transitions, phase stability, and phase diagrams thermodynamics of phase equilibria ideal solutions colligative properties colligative properties cont’d real solutions Exam II (lectures 10-18) kinetic theory of gases 22 23 M, 11/24 M, 12/01 24 W, 12/03 25 M, 12/08 26 W, 12/10 16 20 reaction rates and rate laws integrated rate laws T-dependence of reaction rates elementary reactions & reaction mechanisms catalysis activated complex theory kinetics review SECTIONS IN E&R ASSIGNED PROBLEMS* (lec notes 8, Pt 2) P14.11,19,23a,26 14.5,14.7-10 (lecture notes 8, Pt 3) P15.10,13 15.1-15.3 EP14,EP15 (lecture notes 8, Pt 3) P15.31,45,48 15.4-15.7 EP16,EP17 8.1-8.3 Q8.1,2; P8.12,15,32 8.5-8.7 9.1-9.4 9.6-9.7 9.8 9.5,9.9-9.11 16.1-16.5 18.1-18.3 18.5,18.8,18.10 18.9 18.4,18.7 19.1-19.3,19.5 19.4 18.14 - P8.11,24,33,35 EP18 P9.4,8,12 EP19 P9.7,33 P9.1,15; EP20 P16.2a,6,10,15,17 EP21,EP22 P18.1,5,6,7 P18.3,12,13,26,28 P18.35,38;EP23 P19.1,3,6,13,15 EP24 P19.16,17 P18.52 - DUE DATE FOR PROBLEMS Sec 02 Sec 01 10/27 10/29 11/03 11/05 11/03 11/05 11/10 11/12 11/10 11/12 11/24 11/24 11/24 11/24 - 12/01 12/03 12/01 12/08 12/03 12/10 12/08 12/10 12/10 12/10 -