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Ionic vs Molecular Compounds Period Name Unit 4 – HW 1 Worksheet (Goal 1 – 2) 1. What are Valence Electrons? How are the number of valence electrons found for the Representative Elements? 2. Define Ion – a. What charge are Cations? _____ What types of elements tend to form Cations? _______________ b. What charge are Anions? _____ What types of elements tend to form Anions? _________________ 3. Describe what an Ionic compound is made of. 4. Are Ionic compounds +, ‐, or neutral. Explain. 5. Create a list of physical properties that Ionic Compounds share. 6. The formula of an Ionic compound is called _________________________________ 7. Define molecule – 8. Molecules are electrically ____________________. 9. What type of elements are typically bonded together to form a molecular compound? 10. Produce a list of physical properties that molecules and molecular compounds share. 11. ____________________ Formulas show the type and number of atoms in a molecule. 12. A _________________________ written after the element symbol indicates the number of atoms of each element in the molecular compound. 13. How many atoms of each element are in CH4? 14. How many atoms of each element are in 4H2O? 15. What information can be gathered from the molecular formula CO2? 16. Chemical formulas can also be written for ionic compounds. In this case, however, the formula does not represent a molecule. There are no separate compounds, only a continuous array of __________. 17. Formula units are always made of _______________ and ______________________. 18. For Fe3P2: a. What is the cation in the ionic compound? b. What is the anion in the ionic compound? c. What is the ratio of cations to anions in the ionic compound? 19. How many of each ion are present in AlCl3? 20. There are also seven common elements that exist in nature as two atoms bonded together. They are commonly called “diatomic elements”. a. They are: b. Which words best describe these substances? (element, compound, ionic compound, molecular compound, molecule) Writing the Chemical Name and Formula of an Ionic Compound Name Unit 4 – HW 2 Worksheet (Goals 3 – 4) Period 21. Representative Elements: There is a pattern in predicting how many electrons are lost and gained for the representative elements, can you guess it? WRITE ON YOUR PERIODIC TABLES THE CHARGES OF THE REPRESENTATIVE ELEMENTS NOW. 22. The Transition metals have much more complicated patterns of valence electrons. There are two methods of naming such cations. The preferred method is called the stock system. As part of this system, a roman numeral in parentheses indicates the charge value of the cation. Examples: Name the following transition metal ions: a. tin (lost 2 electrons): Tin (II) b. tin (lost 4 electrons) c. iron (lost 3 electrons) d. iron (lost 2 electrons) There are 3 exceptions to this rule: 1. DO NOT USE A ROMAN NUMERAL WHEN NAMING SILVER, ZINC AND CADMIUM IONS. 2. ALWAYS USE A ROMAN NUMERAL WHEN NAMING ANY OTHER TRANSITION METAL ION. 3. DO NOT USE A ROMAN NUMBERAL WHEN NAMING A REPRESENTATIVE ELEMENTS ION. Write the symbol and charge of the following elements. a. sulfur S2‐ Name the ion Cation or Anion? Sulfide anion b. lead (4 electrons lost) c. strontium d. bromine e. copper (1 electron lost) f.
selenium g. silver Ag+ h. cesium i.
phosphorus 23. Polyatomic Ions: Ions made of _________________________________. 24. What endings do most polyatomic ions receive when naming them? 25. There are 3 important exceptions, they are: 26. What are the “rules” for writing Binary Ionic Compounds? a. Write the __________ ion first b. Write the ______________ ion last c. The net charge for the compound must add to _____ (positives + negatives = 0) d. Use _____________ to indicate how many of each ion you need to “balance” the charge. 27. Write the formula for the ionic compound formed between potassium and chlorine. 28. Write the formula for the ionic compound formed between calcium and bromine. Another approach to writing a balanced formula for a compound is to use the crisscross method. In this method, the numerical charge of each ion is crossed over and used as the subscript for the other ion. The signs of the numbers are dropped. 29. Use the crisscross method to write the formula for the ionic compound formed between iron (III) and oxygen. 30. Use the crisscross method to write the formula for the ionic compound formed between calcium and sulfur. 31. Write the formulas for the compounds formed between these pairs of ions. a. Ba+2, S‐2 b. Li+1, O‐2 c. Ca+2, N‐3 d. Cu+2, I‐1 32. Write formulas for these compounds. a. sodium iodide b. potassium sulfide c. tin (II) chloride (also called stannous chloride) d. calcium iodide 33. Define ternary ionic compounds – Remember, they are still just two ions, and all rules from before still apply! 34. Write the formula for lithium nitrate, a ternary compound: 35. Sometimes, we need to take more than one polyatomic ion to balance the charge to 0. If this happens, place the polyatomic ion in parenthesis and the subscript outside of the parentheses. a. Write the formula for lithium carbonate: b. Write the formula for potassium sulfate: c. Write the formula for ammonium phosphate: 36. Write the name & formulas for ionic compounds formed from these pairs of ions: a. NH4+1, SO32‐ b. Calcium ion, phosphate ion c. Al 3+, NO3 ‐1 d. Potassium ion, chromate ion 37. Write formulas for these compounds a. lithium hydrogen sulfate b. chromium (III) nitrite c. copper (II) bromide d. ammonium dichromate 38. Name these compounds: a. LiCN b. (NH4)2CO3 c. Fe(ClO3)3 d.
e.
f.
g.
CaSO4 KClO KMnO4 Li2SO3 Writing the Chemical Name and Formula of a Molecular Compound Period Name Unit 4 – HW 3 Worksheet (Goal 5) 39. What is a binary molecular compound? 40. We use prefixes when naming binary molecular compounds. Fill in the following: Prefix Number Prefix Number 1 6 2 7 3 8 4 9 5 10 41. Say the name of the first element, say the name of the second element, ending in –IDE, and put the appropriate prefix in to indicate how many of each element there are in the formula: If the prefix for the first element in a binary molecular compound is ________, it may be dropped. However, it must be said if it is for the second element. Don’t reduce the subscripts (like you did for binary ionic compounds) 42. Name these binary molecular compounds: a. N2O b. PCl3 c. SF6 d. OF2 e. Cl2O8 f. SO3 43. Write formulas for the following binary molecular compounds: a. nitrogen trifluoride b. disulfur dichloride c. dinitrogen tetroxide d. octoxygen dichloride e. trinitrogen pentoxide For the list on the left, name the molecular compound. For the list on the right, give the chemical formula that corresponds to the name. Name Formula 1) CCl4 11) dihydrogen monoxide 2) CO 12) sulfur trifluoride 3) P2O5 13) iodine monochloride 4) SF6 14) nitrogen tribromide 5) N2O3 15) phosphorus pentachloride 6) SO3 16) xenon difluoride 7) OCl2 17) dichlorine octoxide 8) CO2 18) dinitrogen monoxide 9) CS2 19) trisilicon tetranitride 10) SeCl2 20) boron trichloride Mole Conversions Period Name Unit 4 – HW 4 Worksheet (Goals 6 – 8) 1. Identify the representative particle in each of the following: (atom, molecule, formula unit) a. CuSO4 b. H2O c. NaCl d. Zn e. Cu f. CO2 2. How many atoms are present in the following compounds? a. BaS b. O3 c. Cl2 d. Ag3PO4 e. Fe(NO3)3 f. PCl5 3. Consider the following samples: 1.00 mol H2O2, 1.00 mol C2H6, or 1.00 mol CO a. Which sample contains more molecules? b. Which sample contains more atoms? 4. Write the relationship between the mole and Avogadro’s number. 5. Calculate the number of representative particles (molecules, formula units, atoms) or moles for each of the following using Avogadro’s number: a. 8.2 mol CuSO4 b. 8.67 x 1018 atoms Zn c. 343.67 mol H2O d. 328 formula units H3PO4 6. Calculate the molar mass of each of the following using the periodic table: a. CO2 b. C6H12O6 c. CCl4 d. HNO3 e. Fe f. CuOH 7. Write the relationship between the mole and molar mass. 8. Calculate the number of grams or moles for each of the following using molar mass: a. 142.7 g NaHCO3 b. 13.87 mol CuCl2 c. 3.14 x 103 mol HCl d. 8.63 x 10‐3 g CaCO3 9. Write the relationship between the mole and molar volume at STP. 10.Calculate the volume in liters or moles for each of the following at STP using molar volume: a. 27 L NO2 b. 3.5 mol H2 c. 2.30 x 101 L HCN d. 0.250 mol O2 11.Calculate the required information for each problem: a. Molecules in 87.6 grams of CO2 b. Volume in liters of 100.0 grams of gaseous O2 at STP c. Mass in grams of 9.2 x 1021 NaCl formula units d. Volume in liters of 1.33 x 1024 N2 molecules e. Mass in grams of 300 molecules of H2O f. Number of H atoms in 6.047 x 1023 molecules of H2 g. Number of O atoms in 13.7 grams of SO2. Percent Composition and Empirical Formula
Name
Period
Unit 4 – HW 5 Worksheet (Goal 9 – 10)
1. Define percent composition.
2. Briefly describe how to determine percent composition given a chemical formula.
Percent Composition Calculations
Determine the percent composition by mass of each element in the following compounds.
3. Magnesium
carbonate MgCO3
4. Sulfuric Acid H2SO4
5. Sodium Nitrate
NaNO3
6. A hydrated salt (a salt with water loosely bound to it) has a mass of 12.33 g. The salt is
heated in a crucible to remove the water. After heating, the anhydrous salt (a salt without
water attached to it) has a mass of 9.25 g. What is the percent composition of water in
the hydrated salt?
7. Define empirical formula.
8. Is the empirical formula of a compound the same as the molecular formula? Explain.
9. Circle the empirical formulas in the following list of compounds.
NaCl
Pb2(SO4)4
H2O2
H2O
MgCl2
MgO
Empirical Formula Calculations
Show your work. Remember to first convert values to moles and then determine the lowest
whole number mole ratio.
10. Find the empirical formula for a compound which contains 32.8% chromium and 67.2%
chlorine.
11. What is the empirical formula for a compound which contains 80.1 % zinc and 19.3%
oxygen?
12. The characteristic odor of pineapple is due to ethyl butyrate, an organic compound which
contains only carbon, hydrogen and oxygen. If a sample of ethyl butyrate is known to
contain 0.62069 g of carbon, 0.103448 g of hydrogen and 0.275862 g of oxygen, what is
the empirical formula for ethyl butyrate? What is the molecular formula of ethyl butyrate
if the molar mass is 116.16 g/mol?