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Chapter 12 Thermal Energy 12.1- Temperature and Thermal Energy • Thermodynamics- the study of heat transformations into other forms of energy – began with 18th century steam engines Thermal Energy • Thermal Energy- total energy of a molecule – From this the average energy per molecule can be calculated Hot Objects • What will happen to this balloon if it is placed in a refrigerator? What about over a pot of boiling water? Solids • Particles cannot move freely- Vibrate Thermal Energy and Temperature • Group 1 • Temperature- depends on the average kinetic energy of particles; does not depend on mass • How much energy would a 2 kg block have to have compared to 1 kg block at the same temperature? • Energy DOES depend on mass • Average Kinetic Energy per particle= Total Kinetic Energy/ Number of Particle Equilibrium and Thermometry • Conduction- transfer of kinetic energy when particles collide Thermal Equilibrium • Thermal Equilibrium- the state in which the rate of energy flow between the two objects is equal and the objects are at the same temperature • Thermometers: GROUP 2 Temperature Scales • Celsius- developed with water in mind • Kelvin- no negative temperatures • TC+273=TK • Temperature limits – No upper limit – Lower limit is absolute zero (-273.15 oC) Heat and Flow of Thermal Energy • Heat- energy that is transferred between objects – Always flows from hot to cold • Conduction and Convection- GROUP 3 • RADIATION- GROUP 4 Specific Heat • The amount the temperature increases depends on the mass and type of object. • The amount of energy that must be added to the material to raise the temperature of a unit mass by one temperature unit. • J/kg K • Table 12-1 page 318 • Heat Transfer Q=mC∆T – Heat transfer is equal to the mass of an object times the specific heat of the object times the difference between the final and initial temperatures. Math Examples Calorimetry: Measuring Specific Heat • Calorimeter-device used to measure changes in thermal energy • Tf=mACATA + mBCBTB mACA + mBCB Math Practice 12.2 Changes of State and the Laws of Thermodynamics • Changes of State – As the thermal energy of an object increases, the motion of the particles __________, and the temperature __________. Melting Point • Change from a solid to a liquid – All energy goes to break forces between particles. – No energy increase KE – Temperature ____________________. Boiling Point • Change from a liquid to a gas – Temperature ____________________. Heat of Fusion • Amount of energy needed to melt 1 kg of a substance • Q=mHf Heat of Vaporization • Thermal energy needed to vaporize 1 kg of a liquid • Q=mHv • What would the equation be for the freezing of a substance? Math Examples • You will have all day on Thursday to work on Book Work, the Laboratory Analysis, or the Chapter 12 Study Guide. • • • • Friday we will finish Chapter 12 Notes Monday we be doing another lab. Tuesday we will grade the Study Guides Test Wednesday • • • • 1st Law of Thermodynamics Heat Engines Efficiency Refrigerators Heat Pumps 2nd Law of Thermodynamics • Entropy • Violations of the 2nd Law