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Aim: How Can We Make Measurements in the Laboratory Accuracy Vs. Precision Accuracy How close a measurement is to the true, accepted value. Precision How close measurements are to one another. Quantitative vs. Qualitative Measurements • Qualitative Measurements gives data in a descriptive, non-numeric form. – Example: “This person feels feverish.” • Quantitative Measurements gives data in a definite form, usually as numbers. – Example: “This person’s temperature is 100.3 degrees Fahrenheit.” Percent Error % Error = Observed Value – True Value x 100 True Value Percent error helps us to determine the accuracy and precision of our chemical data. Where can you find this formula in your Reference Tables? Percent Error Example % Error = Observed Value – True Value x 100 True Value A student determined the boiling point of a substance to be 62.5 oC. If the accepted value is 58.1 oC, what is the percent error? Accuracy vs. Precision “Lab” Do Now: 1.Hand in safety contract, safety letter, and questionnaire. 2. Put your name on testing folder, insert calculator, reference table, pens, and pencils. 3. Accuracy & precision activity due on Wednesday, 9/11. 4. Quiz on Thursday, 9/12. 5. Homework packet #1 due next Tuesday, 9/17. 6. Fill in your name on the seating chart. Aim: How do scientists use the metric system and scientific notation to make calculations? The Powers of Ten Picture a microscopic cell… Picture the galaxy... Scientists need a way to express extremely large and extremely small numbers in their quantitative measurements. Scientific Notation • Scientific notation allows scientists to express extremely large and extremely small numbers in their measurements • Scientific notation shows the product of two numbers: (a coefficient) x (10 to some exponent)(units) a number between 1 and 10 that you multiply an expression by 10 multiplied by itself that many times; example: 103 = 10 x 10 x 10 Expressing Very Large Numbers… • Do you recognize this number? 300,000,000 m/sec • Express the speed of light using scientific notation (the product of two numbers): (a coefficient) x (10 to some exponent)(units) 8 3 x 10 m/sec Expressing Very Small Numbers… • Do you recognize this number? .000000000753 kg • Express the mass of a single dust particle using scientific notation: (a coefficient) x (10 to some exponent)(units) -10 7.53 x 10 kg Try some on your own… 1. 0.000008 meters = ______________ 2. 457,000 Joules = ________________ 3. 65 grams = _____________________ SI Units (“Le Systeme International d’Unites”) • Scientists express quantitative measurements using SI units. D in your Reference Tables to find a list of the – Use Table _____ SI Units we will be using. • Selected base SI units: gram (g) – mass: _____________ liter (L) – volume: ___________ meter (m) – distance: _______________ Kelvin (K) – temperature: _____________ Joule (J) – heat energy: ______________ • Prefixes combine with base units to indicate fractions or multiples of a unit. – Examples: kilo, hecto, milli, centi So… Why SI Units? So… Why SI Units? Comparing English units of length to SI units of length.. English Conversions 12 inches = 1 foot 3 feet = 1 yard 1760 yards = 1 mile SI Conversions 10 centimeters = 1 decimeter 10 decimeters = 1 meter 10 meters = 1 dekameter Think about it… •Which would you rather memorize? •Which would you rather use in calculations? So… Why SI Units? Comparing U.S. units of volume to SI units of volume .. U.S. Conversions 8 ounces = 1 cup 2 cups = 1 pint 2 pints = 1 quart 4 quarts = 1 gallon SI Conversions 1000 cubic millimeters = 1 cubic centimeter 1000 cubic centimeters = 1 cubic decimeter 1000 cubic decimeters = 1 cubic meter 1000 cubic meters = 1 cubic dekameter Converting Between SI Units Using the Ladder Method Kilo (k) Hecto (H) Deca (D) When you go up the steps..move decimal point to the left Base Unit When you go down the steps, move decimal point to the right deci (d) centi (c) milli (m) Metric Conversion Practice • How many kg (kilograms) are there in 5276.4 g (grams)? ______________________________________ Kilo (k) Hecto (H) Deca (D) Base Unit deci (d) centi (c) milli (m) Metric Conversion Practice • How many mm (millimeters) are in 160 cm (centimeters)? ______________________________________ Kilo (k) Hecto (H) Deca (D) Base Unit deci (d) centi (c) milli (m) Metric Conversion Practice • How many L (liters) are in 2534 mL (milliliters)? ______________________________________ Kilo (k) Hecto (H) Deca (D) Base Unit deci (d) centi (c) milli (m) Metric Conversion Practice • How many meters are in 1 cm? ______________________________________ Kilo (k) Hecto (H) Deca (D) Base Unit deci (d) centi (c) milli (m) Aim: How can we use dimensional analysis (factor-label method) to convert between units? Dimensional Analysis (a.k.a. The Factor-Label Method) • We use dimensional analysis to convert from one unit to another. Equivalence Statement Equivalence Statement: the relationship between two different units Examples: 1 foot = 12 inches 1 hour = 60 minutes 1 dozen = 12 eggs 1 kilometer = 1000 meters Selected Equivalence Statements 1000 1L = ____________mL 1 1000 g = ____________Kg 1 cm3 1 = ______mL 101.3 1 atm = _____________kPa Conversion Factors Conversion Factor: A relationship between two different units in a fraction form. Example: 1 dozen or 12 eggs 12 eggs 1 dozen Steps of Factor-Label Method 1. 2. 3. 4. 5. Write down the units you are given. Write “X” and draw a line. Write given unit on the bottom of the line. Write the desired unit on the top of the line. Find and plug in your conversion factor. (Hint: the larger unit will always get a 1 next to it!) 6. Cancel units and do the math. 7. Voila! Let’s do one together… • Convert 90 minutes to hours. 90 minutes = _______ hours hour = Desired Starting Units x Desired1 units 90 min X = 1.5 hours 1 Starting Units 60units min 1 hour = 60 minutes Let’s do one together… • Convert 0.600 liters to milliliters. 0.600L = _______mL Starting Units x Desired 1000units mL = Desired = 600 mL 1 0.600L X Starting1 units Units L 1 L = 1000mL Let’s do one together… How many kilograms are there in 5276.4 grams? 5276.4g = _______kg Starting Units x Desired units 1 kg= Desired X = Units 5.276 g 1 5276.4gStarting units 1000 g 1 kg = 1000g TRY THE REST ON YOUR OWN !!!! How about a challenge?! How old are you? Convert your age in years to your age in hours. Hint: you will need to do this in TWO steps. Years Days and then Days Hours 26 years = _______ days _____ days = ________ hours How about a challenge?! If an animal were to consume exactly 25g of food each day, how many kg of food would it consume in one year? 25 g/day = _______kg/year 25 Units g 1 kg units 365 days Starting x Desired = Desired X X = 9.125 1 Starting 1000 g units1 year Units day kg/year 1 kg = 1000g 1year = 365 days TRY THE REST ON YOUR OWN !!!! Aim: How can we count significant figures accurately? Significant Figures • Significant figures describe all digits in a measurement that are certain, plus one digit that is an estimate. How long is this line? • When we measure something, we always estimate between the smallest marks, one place further than we know for sure. 4.5 cm estimate Uncertainty in Measurement • The better the measuring device the better we can estimate. 4.55 cm estimate Uncertainty in Measurement • What is the total mass on this balance? ______ g + _____ g + _____ g + _____ g = ___________________ g Rules for Counting Significant Figures • Rule #1: All non-zero digits are significant. 4 • Ex: 125.7 g = ___________ sig figs 3 • Ex: 5.45 mL = __________ sig figs Rules for Counting Significant Figures • Rule #2: “Sandwich Rule” – Zeros between non-zero digits are significant. 3 • Ex: 405 mm = ___________ sig figs 4 • Ex: 20.06 mL = __________ sig figs 6 • Ex: 1002.05 g = __________ sig figs Rules for Counting Significant Figures • Rule #3: “Leading Zeros Rule” – Zeros that are placeholders in a measurement are not significant. 2 • Ex: .0054 g = ___________ sig figs 3 • Ex: .0702 cm = __________ sig figs Rules for Counting Significant Figures • Rule #4: “The Right-Right Rule” - In measurements with a decimal, zeros to the right of the decimal and to the right of nonzero digits are significant. 6 • Ex: 124.50 g = ___________ sig figs 5 • Ex: .38000 cm = __________ sig figs Rules for Counting Significant Figures • Rule #5: “Trailing Zeros” – Zeros in a number with no decimal point are not significant. 2 • Ex: 5600 kg = ___________ sig figs 4 • BUT… 5600. kg = __________ sig figs Here’s a Shortcut… Decimal Present: Start at Pacific (left) and begin counting with first non-zero digit. Ex: 0.00234 Decimal Absent: Start at Atlantic (right) and begin counting with first non-zero digit. Ex: 1,000 Practice Problems: Either on Nearpod or on Looseleaf 1. 2. 3. 4. 5. 6. 7. 8. 0.0278 m = 1.3 cm = 1.00 M = 8021 L = 0.2003 g = 56.000 kg = 120 cm3 = 0.000008075 = 3 ___________ 2 ___________ 3 ___________ 4 ___________ ___________ 4 5 ___________ 2 ___________ 4 ___________ Re‐write the quantity 827,000,000,000,000 picoseconds to show: a) 1 sig. fig. 14 8 x 10 ps ________________________________ b) 2 sig. figs. 8.3 x 1014 ps _________________________________ c) 3 sig. figs. 8.27 x 14 10 ps _________________________________ Rewrite the quantity 0.0031904 kg to show: a) 1 sig. fig. -3 3 x 10 kg _______________________________ b) 2 sig. figs. -3 3.2 x 10 kg _______________________________ c) 3 sig. figs. -3 3.19 x 10 kg _______________________________ How Do We.... Determine the number of significant figures in measured values when doing various mathematical computations ? Multiplication & Division 5.282 x 3.42 18.1 The answer should be rounded off to contain the same number of digits as found in the factor with least number of significant figures. Addition & Subtraction 11.31 33.264 + 4.1 48.7 The answer should be the rounded off so as to contain the same number of decimal places as the number with the least number of decimal places. Record your answer to the correct number of significant digits • 1.23 x 400.0 = 492 • 1.2 + 0.345 = 1.5 • 640 ÷ 5.0 = 128 • 450.5 – 325.10 = 125.4 QUIZ REVIEW! • Name that tool… beaker tongs test tube holder QUIZ REVIEW! • Name that tool… wire gauze clay triangle QUIZ REVIEW! • Name that tool… wash bottle Bunsen burner QUIZ REVIEW! • Name that tool… graduated cylinder beaker test tube Erlenmeyer flask QUIZ REVIEW! • Convert these units… 500 mL to L .300 m to cm 0.5 L 30.0 cm QUIZ REVIEW! • Calculate the percent error…! –Erica measures an eraser and finds its mass to be 34.2 grams. Ms. Roman says its mass is 36.6 grams. What is Erica’s percent error? QUIZ REVIEW! •LAB SAFETY!!!