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Multiphase Fluid Samples: A Critical Piece of the Puzzle A new multiphase sampling tool allows operators to capture representative fluids without separation equipment. The ability to accurately analyze fluid composition in real time creates opportunities for them to replace conventional testing equipment with more-efficient and often more-accurate multiphase flowmeters. Poor well test data can be as bad as no well test data, especially for those charged with field development planning or production management. Applying unreliable results to long-term planning—particularly when modeling large or complex reservoirs—inevitably leads to less- than-optimal drainage strategies. Measurements are often distorted by such common events as wells flowing at rates beyond the test separator capacity or well fluids arriving at surface in the form of foams, oil-water emulsions, heavy oils or condensate-laden wet gas. Vitaliy Afanasyev Noyabrsk, Russia Paul Guieze Alejandro Scheffler Clamart, France Bruno Pinguet Maturin, Venezuela Bertrand Theuveny Moscow, Russia Oilfield Review Summer 2009: 21, no. 2. Copyright © 2009 Schlumberger. For help in preparation of this article, thanks to Mahdi Baklouti, Olivier Loicq, Federico Ortiz Lopez and Gerald Smith, Clamart; and David Harrison, Houston. PhaseSampler, PhaseTester, PhaseWatcher, PVT Express and Quicksilver Probe are marks of Schlumberger. 1. Mullins OC, Elshahawi H, Flannery M, O’Keefe M and Vanuffellen S: “The Impact of Reservoir Fluid Compositional Variation and Valid Sample Acquisition on Flow Assurance Evaluation,” paper OTC 20204, presented at the Offshore Technology Conference, Houston, May 4–7, 2009. 30 Oilfield Review > Smaller and lighter. The traditional test separator (left) has a footprint of 5.68 by 2.24 m, is 2.45 m high [18.7 by 7.4 by 8.0 ft] and weighs 15,000 kg [33,000 lbm]. By comparison, the PhaseTester MPFM (right) measures 1.50 by 1.65 m, is 1.77 m high [4.92 by 5.41 by 5.81 ft] and weighs 1,700 kg [3,750 lbm]. Efficient production of formation fluids requires accurate predictions about how temperature and pressure changes that always accompany reservoir depletion affect the constituent fluid and formation properties. In remote areas and on deepwater platforms, lack of infrastructure, space and weight restrictions and transport logistics can make traditional testing and metering equipment impractical. Fluids produced in deep water—cooled by their trip to the surface through thousands of feet of pipe in nearfreezing water—sometimes cannot be heated to a temperature sufficient to accomplish separation. At the same time that the industry is struggling with those challenges, an increasing portion of operators’ portfolios is made up of the type of reserves historically avoided because they are difficult to produce economically. These include heavy oils, wet gas and other unconventional fluids that defy phase separation. In installations where weight and space must be taken into consideration or where complex fluids make phase separation difficult, multiphase flowmeters (MPFMs) are quickly gaining acceptance as an alternative to traditional separators and test units. They are more convenient and have a smaller footprint than traditional separator-based meters and test units, and they can be used to measure flow rates without prior separation of fluids into phases (above). Additionally, the fact that MPFMs are flowthrough devices means they are safer to operate and do not generate disposable fluids. In contrast, separators must contain fluids under pressure and elevated temperatures for some period of time to effect separation. Summer 2009 Until recently, however, the effectiveness of MPFMs was hobbled by a significant drawback: Confidence in the accuracy of flow rates calculated without separation was limited by the absence of representative fluid samples for validation. Such samples are critical for determining in situ volumetric ratios and dry gas properties used to minimize uncertainties in flow measurements. Another method of downhole sampling uses wireline tools to capture the fluid and keep it in a chamber at in situ conditions while it is brought to the surface and then transported to a laboratory for analysis. Because this process includes the risk and expense of a well intervention, many operators prefer to take samples at a separator on the surface. The accuracy of downhole sample analysis is also hampered by the need to acquire samples in a manner that ensures they are indeed representative of the entire reservoir. But reservoir fluid properties are variable, and laboratory evaluation must be understood in the context of the spatial distribution of complex fluids within the reservoir. Unrecognized formation compartmentalization increases the uncertainty of downhole sampling. Reservoirs with multiple compartments can yield very different fluids within one production zone and affect overall recovery.1 To address these issues, Schlumberger has developed the PhaseSampler fluid sampling and analysis system to be used in conjunction with a PhaseTester portable MPFM or the permanently installed PhaseWatcher MPFM. The sampling tool is small enough to be fitted to the MPFM and is easy to use (below). Laboratory tests using this combination of services to calculate flow rates and properties of conventional fluids yielded > Simple attachment. The PhaseSampler multiphase sampling device (inset) fits on the sampling port of the PhaseTester or PhaseWatcher MPFM. Compact and easily attached, it requires no additional external power. 31 Flow computer Nuclear detector Nuclear source Venturi Pressure transmitter Differentialpressure transmitter Flow > Multiphase metering technique. PhaseTester MPFM technology is based on measuring mass flow rate in the venturi spool using differential-pressure sensors—a well-established method for flow rate metering in a single-phase flow regime. A barium source emits gamma rays whose attenuation is measured at two different energy levels. Measuring this attenuation in multiphase media allows calculation of the density of the fluid and the mass/ volume fractions of the oil, water and gas. The combination of these techniques with mathematical models provides information about the oil, water and gas production. Engineers use the well test data to continually diagnose production anomalies, quickly resolve problems and efficiently produce wells. This technology can also capture flow rate measurement data during cleanup. This article examines the multiphase sampling answers that are as accurate as those achieved by tool recently developed by Schlumberger and how traditional methods. Laboratory results have also proved that the it complements multiphase meters by enabling use of MPFMs to test wells flowing heavy oil and capture of fluid samples without traditional sepawet gas delivers a more accurate picture of the rators. A case history from Siberia illustrates how transient evolution of flow, volumes and rates flow rates can be improved using multiphase samthan is possible with traditional separators.2 pling and meters to test remote gas-condensate Phase separation can rarely be achieved with wells. Another from Algeria demonstrates the the efficiency required to deliver truly accurate accuracy of results achieved using the new Rick_Fig03_2 sampling system to determine fluid properties. flow calculations. Determination of fluid properties, calculation of flow rates and prediction of fluid behavior are Shrinking the Margin of Error inseparable elements in developing reservoir MPFM technology is based on differentialdrainage strategies. Accurate determination of pressure measurement in a venturi spool—a each becomes more critical with increasing fluid well-known method for single-phase flow meaand reservoir complexity. That is because the test surement that can be adapted for multiphase results that once were considered not much more flow by adding a nuclear component to measure than a common tool for decisions on whether to total mass flow rate and the holdups, or fractions, complete a well have today become an indispens- of gas, oil and water (above).3 The resulting well able data source for modeling and development test data are used to diagnose production anomaplanning. Production data from inline MPFMs lies continuously rather than periodically as must are used to forecast the onset of problems as be done using separators. Also, data can be gathwells age and the composition of fluids changes ered during well cleanup—which increases with temperature and pressure variations. understanding of possible flow assurance problems, offers better well-performance assessment and reduces test times. This is an impossibility 32 using traditional separators that must remain off line until the well has returned drilling fluids or other contaminants introduced into the formation during drilling and completion. Immediate economic benefits of using MPFMs for well testing include a reduced footprint. Also, because little or no stabilization time is required, it is possible to test more wells per unit of time. These are especially attractive characteristics in remote and deepwater locations where conserving time and space is essential to project economics. As a production-monitoring tool, MPFMs exhibit excellent response to fluctuating flow; require little or no stabilization time; and are not affected by complex flow regimes such as slugs, foams or emulsions. Because their operation is insensitive to changes in flow rate, phase holdup or pressure regime, they require no process control. These capabilities give operators a means to recognize such time-dependent events as a change in flow regime or the onset of hydrate formation. In turn, wellsite engineers are able to adjust well treatment programs, flow rates or other parameters before they impact production efficiency. MPFM devices measure flow rates at line conditions. As a consequence, engineers must turn to PVT calculations to convert these results to the standard conditions used to compute oil, water and gas flow rates. Three sets of PVT data are required to calculate flow rates at standard conditions: densities, volumetric conversion factors (from line to standard conditions) and solution ratios. The liquid viscosity at line conditions must also be considered when heavy oil is one of the phases. These data are obtained through analyses of samples collected at the surface or—when feasible—acquired downhole with a wireline tool, such as the Quicksilver Probe sampler.4 In a multiphase environment, samples may be collected at the surface in two ways. The first is to capture a known volume of a representative mix of each phase from a traditional three-phase separator. The second approach is to collect a set of representative phase samples (oil, water and gas) at line conditions and use independent measurements of each of the phase fractions in the commingled flow to reconstruct the whole fluid.5 Separator Sampling The validity of flow rates calculated from samples taken at a separator is questionable because a correct analysis depends on thermodynamic equilibrium, in which both liquid and gas are at the same pressure and temperature and in equilibrium with each other. Oilfield Review While discussions continue as to when and at what point in the separation process true equilibrium is reached, experts widely acknowledge that such a condition is reached a few feet after the fluid passes a choke, a change in pipe size or other pressure loss–generating flowline assembly. As a consequence, the temperature and pressure of the phases within a sample taken from a flowline are often not at equilibrium.6 Additionally, it is impossible to take high-pressure samples and, when one phase is dominant, significant carry-over or carry-under can occur and distort flow measurements.7 Once samples of each phase are collected, there are several options for generating fluid properties. These include the use of black oil models (BOMs) to estimate fluid properties from stocktank measurements; wellsite measurements; equation-of-state (EOS) calculations using PVT data generated during field exploration and appraisal stages; or a full PVT laboratory analysis. Black oil models are based on statistical functions that assume reservoir fluid consists of three phases—oil, water and gas. Pressure, temperature and density are inputs and fluid composition is included in the statistical measurement from which the correlations are derived. EOS models incorporate more fluid properties than BOMs and are more scientifically defined, but they are only as accurate as the PVT data analysis. These models are ineffective when PVT data are no longer representative of the fluids because they have changed in response to pressure and temperature variations. The response when such conditions are recognized is to approximate some of the necessary data, raising the level of uncertainty to that of the BOM. To ensure accuracy in wellsite measurements they must be acquired by experts. PVT laboratory analysis can be time-consuming, though this may not be an issue if accuracy is more important than lost production time. Calculations are derived from correlations that may limit accuracy in certain fluids and that are particularly impractical for use in heavy oils and gas condensates. Line Sampling Collecting representative phase samples at line conditions reduces the uncertainties introduced by pressure, temperature and effluent variations. In some cases, however, the complexity of the multiphase flow regime makes it impossible to sample a single phase at a time. To overcome this challenge, researchers developed the PhaseSampler system, designed for sampling from areas within the flow stream where one phase is dominant and the oil, gas and water are Summer 2009 at equilibrium at line conditions. The system hardware includes •a three-probe sampler that fits into the flow meter port •an optical phase detector to sense the type of fluid entering or leaving the sample chamber •a kit that allows direct measurement at the wellsite of key fluid property inputs at line and standard conditions for any type MPFM •dedicated data-acquisition software that receives the measured fluid properties as an alternative to the correlation available with standard multiphase meters. Through the sampling trap, the probes are placed in the flowline’s multiphase stream so that the venturi is in front of the probes. This positioning ensures the sample is well mixed and not affected by fluid slugs or similar flow anomalies and is therefore representative of the flow being measured by the venturi. Two of the probes face upstream to capture mostly liquids; one is placed at the bottom of the pipe, one at the top. The third probe is positioned in the middle of the flow path, facing downstream, and captures a sample that is predominantly gas (below). The captured fluid remains in a phase-segregating Sampling mostly liquid Sampling mostly gas Sampling mostly liquid > Multiphase sampling. The location and orientation of the PhaseSampler probes within the flow stream enable them to collect discrete, phaseconcentrated samples at line conditions. Two probes—one at the top and one at the bottom of the flow path—face upstream and collect samples that are predominantly liquid. The third probe is in the center of the pipe and faces downstream. Numerous experiments have shown this alignment minimizes the amount of liquid entering the tube and results in the capture of a sample that is predominantly gas. 2. Afanasyev V, Theuveny B, Jayawardane S, Zhandin A, Bastos V, Guieze P, Kulyatin O and Romashkin S: “Sampling with Multiphase Flowmeter in Northern Siberia—Condensate Field Experience and Sensitivities,” paper SPE 115622, presented at the SPE Russian Oil & Gas Technical Conference and Exhibition, Moscow, October 28–30, 2008. 3. For more on multiphase flow measurement: Atkinson I, Theuveny B, Berard M, Conort G, Groves J, Lowe T, McDiarmid A, Mehdizadeh P, Perciot P, Pinguet B, Smith G and Williamson KJ: “A New Horizon in Multiphase Flow Measurement,” Oilfield Review 16, no. 4 (Winter 2004/2005): 52–63. 4. For more on Quicksilver Probe technology: Akkurt R, Bowcock M, Davies J, Del Campo C, Hill B, Joshi S, Kundu D, Kumar S, O’Keefe M, Samir M, Tarvin J, Weinheber P, Williams S and Zeybek M: “Focusing on Downhole Fluid Sampling and Analysis,” Oilfield Review 18, no. 4 (Winter 2006/2007): 4–19. 5. Afanasyev et al, reference 2. 6. Hollaender F, Zhang JJ, Pinguet B, Bastos V and Delvaux E: “An Innovative Multiphase Sampling Solution at the Well Site to Improve Multiphase Flow Measurements and Phase Behavior Characterization,” paper IPTC 11573, presented at the International Petroleum Technology Conference, Dubai, UAE, December 4–6, 2007. 7. Carry-over (liquids in the gas line) and carry-under (gas in the liquids line) may result when a separator design is ill-suited to the flow regime. Either can affect the accuracy of multiphase flow rate measurements. Rick_Fig04_1 33 sample chamber until a sufficient volume of the targeted phase is collected (below). The single-phase sample is then placed in a flash apparatus for measurement of fluid properties or it is transferred into a sample bottle for transport to a PVT laboratory for a recombination PVT study.8 The higher accuracy of the GOR resulting from the improved characterization of MPFM measurements enables a more-reliable recombination and subsequent PVT analysis. Optical phase detector Optical phase detector Oil Oil Water Gas Water Gas Optical phase detector Optical phase detector Oil Oil Water Gas Water Gas > Isolating one phase. Fluids captured by a probe (top, black arrow) enter a sample chamber (middle left) where an optical phase detector distinguishes between oil, water and gas. This dynamic fluid profiling continues throughout the sampling process. The nontarget phases are displaced from the chamber back into the flowline by a hydraulically activated piston (middle right, bottom left—water flowline from bottom not shown) until only the phase of interest remains (bottom right). 34 It is important to the recombination that captured samples be validated. To that end, Schlumberger developed a quality assurance/ quality check (QA/QC) concept that includes sampling QA, rapid sampling QC, saturation-pressure determination and a cross-check with separator or downhole sample when available. Of these, the most powerful QC tool is PVT Express onsite bubblepoint determination at sampling temperature (next page). Successful replication of the initial formation fluid from recombination depends on a number of variables including reservoir conditions, well parameters and sampling procedures. For example, if the bottomhole flowing pressure is below the initial dewpoint pressure, the formation fluid will be diphasic; liquids deposited in the formation or in the near-wellbore region will not be lifted. Consequently, recombination will reflect only flowline fluids. Recombination is accomplished by either physical or mathematical means. Physical recombination requires single-phase samples of the gas, oil or water and a gas/liquid ratio obtained through MPFM measurements. Though no physical experiments are required for mathematical recombination, additional information is needed. These inputs include liquid density at recombination conditions, molecular weight of the liquid, gas expansion factor and liquid/gas ratios. Although the physical approach requires more time and personnel investment and is more subject to human error, it also offers significant advantages over mathematical recombination. These include •tangible results in the form of monophasic samples •less uncertainty than from calculations •opportunity for further analyses •experimental saturation point •in situ and stock-tank densities. Recombination allows the development of a compositional model for a monophasic fluid at either formation or producing conditions. Physical recombination enables this model to be fine-tuned at experimental reference points. An EOS is then used to simulate complex tests. The resulting formation-fluid model can be used to understand the drainage behavior of a field and can be applied to its exploration, development, production and forecasting.9 A Different Approach Certain situations make it difficult to use traditional separators to gain insight into a field’s drainage behavior. For instance, in fields with Oilfield Review Summer 2009 260 240 220 Pressure, bar 200 180 160 140 120 Bubblepoint 100 80 60 61 62 63 64 65 66 67 Volume, cm3 Diphasic Monophasic Optical signal (relative units) 200 150 Pressure, bar high gas volume factors (GVFs), samples must be truly representative or the PVT properties will not have the accuracy necessary for correct rate calculations.10 These samples may be hard to capture by traditional means that rely on good phase separation—a difficult task where such fluids are concerned. In 2007, after years of calculating flow rates through periodic conventional testing, operator Rospan International began investigating a multiphase well testing program to refine the geological and dynamic models of its Urengoyskoe gascondensate field in northern Siberia. The decision was based on the need for a more thorough understanding of drainage behavior because most reservoirs had been produced at conditions below the dewpoint. Despite depletion from earlier production, analysts determined the reservoirs would support substantial future production.11 The field, discovered in 1966, is 80 km [50 mi] south of the Arctic Circle. Capturing representative fluid samples from this location and then transporting them for analyses at a laboratory thousands of miles away would be impractical and expensive. Also, conducting traditional well tests and interpreting the data are made difficult by complicated reservoir structures, relatively high formation pressures and the physical and chemical properties of the produced fluids. Most production comes from the deep Achimov Formation that lies more than 3,000 m [9,800 ft] below the surface. It is characterized by sandstones and siltstones with claystone bands, irregularly distributed reservoirs and significant lithological facies variations. Net-pay thickness ranges from 0 to 5 m [0 to 16 ft] for oil zones and from 0 to 60 m [0 to 197 ft] for gas intervals. Average porosity ranges from 15% to 18%. Oil saturation is 60% and gas saturation varies from 56% to 77%.12 Formation pressure ranges from 530 to 660 bar [7,700 to 9,570 psi] and formation temperature from 17°C to 91°C [62°F to 196°F]. GVF is between 97% and 99.5%. Rospan addressed the issues of great distances and complex reservoirs through the use of a PhaseTester multiphase flowmeter and the PhaseSampler device. The Schlumberger PVT Express portable laboratory service was used to deliver onsite compositional analysis of gas and gas condensate without phase changes. These samples were used for sample validation and fluid-properties characterization.13 In one well, a PhaseSampler tool captured fluid at the MPFM and a downhole single-phase sampler captured a bottomhole fluid sample. 100 35.6, 98 50 0 –150 –50 50 150 250 350 450 Temperature, °C PhaseSampler gas PhaseSampler liquid PhaseTester line sampling conditions > Quality assurance and check. Saturation pressure obtained at sampling temperature can be used to validate samples from multiphase sampling devices. The bubblepoint for the liquid sample (top) and the dewpoint for the gas sample (not shown) should equal the sampling pressure. When a valid sample is taken—at line conditions and in thermodynamic equilibrium— phase envelopes for liquid and gas cross at the sampling point (bottom). For quality purposes, the acceptable deviation of measured bubblepoint from sampling is ±5%. Because the dewpoint is more difficult to detect, the allowed deviation is ±20%. (adapted from Afanasyev et al, reference 2.) 8.A flash apparatus facilitates observation of fluid 12.Gas saturation is the relative amount of gas in the pore phase behavior at the moment sample pressure is space of a formation, usually expressed as a percentage. instantaneously released to atmospheric pressure. 13.Bastos V and Harrison D: “Innovative Test Equipment 9.Afanasyev et al, reference 2. Expedites Data Availability,” E&P 82, no. 2 (February Rick_Fig05_1 2009): 64–65. 10. GVF is the gas volume at reservoir conditions divided by the gas volume at standard conditions. This factor is used to For more on PVT Express technology: Akkurt et al, convert surface-measured volumes to reservoir conditions. reference 4, and Betancourt S, Fujisawa G, Mullins OC, An oil formation volume factor is used to convert Carnegie A, Dong C, Kurkjian A, Eriksen KO, Haggag M, surface-measured oil volumes to reservoir volumes. Jaramillo AR and Terabayashi H: “Analyzing Hydrocarbons in the Borehole,” Oilfield Review 15, no. 3 11.Romashkin S, Afanasyev V and Bastos V: “Multiphase (Autumn 2003): 54–61. Flowmeter and Sampling System Yield Real-Time Wellsite Results,” World Oil 230, no. 5 (May 2009): 66–70. 35 450 105.5, 420 105.5, 394 400 350 Pressure, bar 300 250 PhaseSampler gas: 11.01 PhaseSampler liquid: 11.02 PhaseSampler sampling conditions (6 mm) BHS: 1.02 Bottomhole sampling SRS Measured dewpoint Mathematically recombined PhaseSampler samples 200 150 100 10.5, 83 50 0 –150 –50 50 150 250 350 450 Temperature, °C > Validation of surface samples using a bottomhole sample (BHS). This graph superimposes BHS phase envelopes and mathematically recombined samples acquired by a multiphase sampling device. Bottomhole and line conditions are shown for reference. Envelopes of the multiphase samples cross at the sampling point (green dot). The single-phase reservoir sample (SRS) was used in an EOS to obtain its phase envelope. A best-fit characterization (blue) moved the phase diagram closer to the measured dewpoint (orange triangle) and to the mathematically recombined monophasic sample (red curve) that is consistent with the BHS. Since sampling pressure was higher than the dewpoint, it was assumed the reservoir fluid was originally monophasic. However, it split into two phases when pressure decreased as it flowed to the surface. The samples were studied and recombined mathematically using a gas/liquid ratio averaged over the sampling period. When plotted, the phase envelopes of the captured multiphase sample and the bottomhole sample crossed at the sampling point, indicating the condensate and gas phases were in equilibrium as they passed through the meter (above). The experiment, as demonstrated by the resulting plots, confirmed several important 100 Black oil model 900 Rick_Fig06_1 80 850 70 800 60 750 50 700 40 650 30 600 20 Oil density at line conditions, kg/m3 Volume, sm3/sm3 90 950 PhaseSampler analysis 550 Solution gas Oil volume factor Oil density > Differences and potential error. The differences in the BOM and the PhaseSampler analysis for solution gas, oil volume factor and oil density were significant. Using the BOM would result in underestimated oil shrinkage and overestimated oil density, which could lead to significant errors in the large Berkine basin. (adapted from Bastos and Harrison, reference 13.) 36 points for the operator: •Samples from a multiphase sampling device are good initial material for recombination. •A gas/liquid ratio from recombination can be used to reconstruct monophasic flow. •An EOS works better than experimental reference points. •Multiphase sampling and testing are viable tools in formation fluid simulation. In a second study conducted in the field, a sample from a new well was physically recombined using wellsite analytical equipment and the PhaseSampler service. After a day of reconditioning the sample at reservoir conditions, 25 cm3 was transferred to a PVT cell for QC and saturation-pressure determination. This experiment resulted in a dewpoint pressure of 376.8 bar [5,463.6 psi], essentially matching an earlier EOS prediction of 382 bar [5,539 psi] based on mathematical recombination. This outcome confirmed the feasibility of using physical recombination on samples captured by a multiphase sampling device. It also showed that recombination is easier to accomplish with these samples than with those obtained using conventional means placed downstream of a separator. And finally, it demonstrated that physical recombination used in conjunction with bottomhole data provides essential information about flow regimes. As a consequence of these examples and other work done over a period of six months, the Schlumberger and Rospan International team has developed a multiphase sampling and analysis program specifically for the Urengoyskoe condensate field. The procedure involves using a multiphase sampling device and an MPFM on each well. When possible, the process includes sending one sample collected at the largest choke setting and one collected at the smallest setting to a laboratory for testing. Each sample pair is recombined mathematically and physical recombination is provided for samples from new wells. A botttomhole sample is captured in every fifth well. 14.Basic sediment and water, or BS&W, refers to impurities contained in produced oil and is reported as a percentage of the fluid in samples captured at the surface. Its measurement is described in ASTM Standard Test D96-82. 15.Bastos and Harrison, reference 13. 16.Oyewole AA: “Testing Conventionally Untestable High-Flow-Rate Wells with a Dual Energy Venturi Flowmeter,” paper SPE 77406, presented at the SPE Annual Technical Conference and Exhibition, San Antonio, Texas, USA, September 29–October 2, 2002. 17.Theuveny B, Zinchenko IA and Shumakov Y: “Testing Gas Condensate Wells in Northern Siberia with Multiphase Flowmeters,” paper SPE 110873, presented at the SPE Annual Technical Conference and Exhibition, Anaheim, California, USA, November 11–14, 2007. Oilfield Review 80 180 PhaseSampler analysis Laboratory results 60 120 90 60 50 40 30 20 30 10 0 1 2 3 N2 4 Well number 40 CO2 H 2S C1 80 PhaseSampler analysis Laboratory results 35 25 20 15 10 5 C3 iC4 nC4 Free gases iC5 N2 CO2 C1 C2 C3 iC4 nC4 iC5 nC5 C6 C7 C6 C7 80 70 60 60 50 50 40 40 30 30 20 20 10 0 nC5 PhaseSampler analysis Laboratory results 70 Volume, sm3/sm3 30 C2 Gas density at line conditions, kg/m3 0 Weight, mol % PhaseSampler analysis Laboratory results 70 Weight, mol % Solution gas, sm3/sm3 150 10 Gas volume factor Gas density Dissolved gases > Confirmation. Though the laboratory ambient temperature was 77°F [25°C], and wellsite temperatures ranged from 104°F [40°C] to 122°F [50°C], measurements of solution gas by both PhaseSampler analysis and the laboratory were in good agreement (top). The PhaseSampler and PVT compositional analyses for the free gas (top right) and dissolved gas (bottom left) were also in close agreement, as were those for the GVF and the gas density (bottom right). Free gas and dissolved gas are represented by two bars in each graph to indicate samples measured using two different types of gas chromatographs. Measuring Differences Whereas the flow and fluid property measure ment challenge in the Urengoyskoe field was a product of complex geology and remoteness, in the Berkine basin of eastern Algeria, multiphase sampling was put to the test in four wells with fluid parameters that varied significantly. GOR across the wells ranged from 1,000 to 18,000 ft3/bbl [176 to 3,200 m3/m3], API gravity from 40 to 53, basic sediment and water from 0% to 33% and water salinity from fresh to over saturated brine.14 Operators Sonatrach and Anadarko, who had formed a partnership to manage oil fields in the basin, sought to determine whether the PhaseSampler technology could accurately measure reservoir fluid properties at each wellsite. The operators required a three-step validation process: •PhaseSampler results would be compared to BOM predictions. •PhaseSampler and PVT measurements of GOR and gas composition would be compared. •Repeatability would be tested by comparing mul tiple flashes under identical flowing conditions. The match between PhaseSampler and labora tory results across the varying zones was good for Summer 2009 measurements of solution gas, compositional anal ysis of free and dissolved gas and determination of gas volume and density (above). Multiphase sampling measurement repeatability was con firmed by the performance of eight flashes each for gas and oil. However, differences between solution gas volume, oil volume factor and oil density as calcu lated with the BOM were significant (previous page, bottom). This confirmed experts’ early con cerns that the BOM would underestimate oil shrinkage and overestimate oil density. Had these erroneous figures been applied to the deci sion-making process on a reservoir the size of the one tested in the Berkine basin, the impact could have been considerable.15 The Critical Piece Traditionally, the industry has tested well flow rates and reservoir potential through the use of separators that break multiphase well effluent into its constituent phases before the measure ment of each phase. But there have always been concerns about the quality of a separation pro cess that uses test vessels that rely on gravity and pressure reduction. Even when results appear to be accurate, the method has inherent flaws. Among these are carry-over, carry-under and dis crete measurements that in complex regimes, such as slugging water, may lead to mistaken con clusions about water cut if the readings were taken at the wrong time.16 Additionally, the type of reserves the industry is exploiting is changing. There is now increased demand for advances such as high-resolution measurements of gas/liquid ratios to determine changes in fluid properties at choke crossings. Operators are also seeking greater test repeat ability to confirm slowly evolving trends, lower risks associated with conventional separators that capture hydrocarbons under elevated pres sure and temperature, and high-quality data from permanent monitoring installations.17 The success of the multiphase sampling device promises to eliminate any further objec tion to the use of MPFMs in both testing and production monitoring. Laboratory tests and comparisons with traditional sampling methods and analyses have proved its ability to collect representative fluid samples for real-time compo sitional analysis, thus providing a critical piece to the multiphase flowmeter puzzle. —RvF 37