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Synthetic and Natural Organic Polymers Chapter 22 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display. A ___________ is a high molar mass molecular compound made up of many repeating chemical units. Naturally occurring polymers •___________ •___________ •___________ •___________ Synthetic polymers •___________ •___________ •___________ 22.1 The simple repeating unit of a polymer is the ___________. _________________ is a polymer made up of only one type of monomer ( CF2 CF2 )n ___________ ( CH2 CH2 )n ___________ ( CH2 CH )n Cl _________ 22.2 ____________ is a polymer made up of two or more monomers ( CH CH2 CH2 CH CH CH2 )n Styrene-butadiene rubber 22.2 Stereoisomers of Polymers R groups on same side of chain Isotactic R groups alternate from side to side Syndiotactic R groups disposed at random Atactic Proteins _________ ________ are the basic structural units of proteins. An amino acid is a compound that contains at least one amino group (-NH2) and at least one carboxyl group (-COOH) H O H O +H N 3 C C O- + +H3N C C OR2 R1 ___________ bond H O H O +H N 3 C C N C C O- + H2O R1 H R2 22.3 22.3 Protein Structure Carbon Nitrogen Oxygen R group The structure is held in position by intramolecular hydrogen bonds (………) Hydrogen 22.3 Protein Structure 22.3 Protein Structure Intermolecular Forces in a Protein Molecule ionic forces hydrogen bonds dispersion forces ionic forces dispersion forces dispersion forces dipole-dipole forces 22.3 Hydrogen Bonds in Parallel and Antiparallel b-pleated Sheets 22.3 Protein Structure The structural changes that occur when oxygen binds to the heme group in hemoglobin. 22.3 Nucleic Acids Nucleic acids are high molar mass polymers that play an essential role in protein synthesis. 1. Deoxyribonucleic acid (DNA) 2. Ribonucleic acid (RNA) DNA molecule has 2 helical strands. Each strand is made up of ________________. 22.4 The Components of the Nucleic Acids DNA and RNA 22.4 Base-Pair Formation by Adenine and Thymine and by Cytosine and Guanine 22.4 Chemistry In Action: DNA Fingerprinting 22.4