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Chemistry 11 – Unit 5 Forero Name: ______________________________ Date: ___________ Blk: _____ NOTES: ATOMIC STRUCTURE I. History of the Atom Dalton 1803 Thomson 1897 Rutherford 1909 Bohr 1913 1. DALTON 2. THOMSON - everything is made of _______________ - discovery of _______________ particle (_____________) - different______________ combine to form ______________ in simple whole ______________ Cathode ray experiment - rays are ____________, not __________ - each element has its own unique type of ___________ with a characteristic ___________ - new particles are ______________, lighter than smallest atom (_____________) - ____________________________ model - ____________________________model 3. RUTHERFORD Thin gold foil experiment - ______________ particles mostly pass through ______________ - but sometimes ______________ back when they hit something ______________ - thus, atom made mostly of ______________ - core of ______________ charged material, where most of the ______________ of the atom is (______________) - why don’t negative electrons give in to the pull of the positive nucleus and ______________ inwards? Chemistry 11 – Unit 5 Forero 4. BOHR - negatively charged electrons found in ________________________________________ around the positive charged nucleus - electrons found at fixed ____________________ orbiting at fixed _________________ from the nucleus - path closest to nucleus = ___________________________________ - energy ______________ the farther the orbits are from the nucleus - the farther the electron is from the nucleus, the ______________ attraction it feels - electrons can jump from one energy level to another, but are not found ______________ levels - they lose or gain a discrete package of energy (____________________________) every time it jumps levels ____________________________ - explains why each element has a certain number of electrons available for ______________ - the electrons found on the ____________________________ ___________________ - planetary model II. Atomic Number and Atomic Mass (review!) Particles which make up the atom are called ______________. 1. Protons: ______________________________________________________________ 2. Electrons: _____________________________________________________________ 3. Neutrons: _____________________________________________________________ PARTICLE The Properties of the Atomic Particles SYMBOL CHARGE MOLAR MASS LOCATION Chemistry 11 – Unit 5 Forero The chemical elements are different from one another by the number of ______________ in the nucleus. ATOMIC NUMBER = ___________________________________________________ - found on top of ____________________________ A ______________ atom has ____________________________: ____________________________= ____________________________ EXAMPLE: 1. Any atom containing 3 protons must be…? 2. A neutral sodium atom has ___________ electrons If ______________ are added to or subtracted from a neutral atom, the resulting particle is called: ION # of protons ______ # of electrons Electrons have a ______________ charge so: - ______________ a______________ charge produces a ______________ion - ______________ = # of e-______# of p’s - ______________ a ______________ charge produces a ______________ ion - ______________ = # of e- ______ # of p’s Example: 1. If an electron is added to a neutral F atom, then the ion is written as: 2. If two electrons are removed from a neutral Ba atom, then the ion is written as: Chemistry 11 – Unit 5 Forero Since both neutrons and protons have a molar mass of approximately ______, then: - Total mass of an atom = __________________________________________________ *the ______________ are too ______________ to make an appreciable contribution to the mass of an atom ATOMIC MASS = __________________________________, thus: NUMBER OF NEUTRONS = _______________________ – ______________________ Example: Find the number of protons, neutron and electrons in the following atoms: a) Al b) C But, then why is it that the atomic mass of some elements is not a whole number? *See Titanium above… III. Natural Mixtures: Isotopes and Mass Number Example: ISOTOPES OF HYDROGEN What’s the difference between Hydrogen-1, Hydrogen-2 and Hydrogen-3? ISOTOPES: different ______________ of the same ______________, with the _____________ # of protons but with _____________ #’s of neutrons, or… - atomic species having the same ____________________________, but different ____________________________ Chemistry 11 – Unit 5 Forero MASS NUMBER = _______________________________________________________ ____________________________________________________ Hydrogen-3 To find the p’s and n’s from nuclear notation: Calcium-41 Find the # of protons and # of neutrons in each of the following isotopes: Chemistry 11 – Unit 5 Forero Now try the other way! Now try it with ions! Find the same items on the table: 1) 56Fe3+ 2) 76As3- 3) 201Au+ 4) 82Br - Chemistry 11 – Unit 5 Forero EXTRA PRACTICE: Write the nuclear notation: 1) An isotope has 46 protons, 58 neutrons and 42 electrons. 2) An isotope has 52 protons, 79 neutrons and 54 electrons. NATURAL MIXTURES - The molar mass of chlorine is 35.5 g. Since there can’t be 0.5 of a proton or neutron, then this atomic mass __________ represent an ______________value of a ______________ of isotopes. Example: Find the average atomic mass of: 1) Cl, given that it is composed of 75.77% Cl-35 and 24.23% Cl-37. 2) B, given that it is composed of 18.8% B-10 and 81.2% B-11. BONUS: 3) Naturally occurring silicon consists of 92.23% Si-28 (mass = 27.976927 g), 4.76% Si-29 (mass = 28.976495 g) and 3.10% Si-30 (mass = 29.973770 g). What is the expected average molar mass (atomic mass) of a sample of natural silicon, expressed to 4 decimal places? (Ans: 28.0855 g)