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Chemical Reactions • Reactions involve chemical changes in matter that result in new substances. • Reactions involve rearrangement and exchange of atoms to produce new molecules. • Reactants Products CH4 + 2O2 → CO2 + 2H2O Copyright © Houghton Mifflin Company. All rights reserved. CH4 O2 CO2 H2O 6|1 Evidence of Chemical Reactions • A chemical change occurs when new substances are made. • Visual clues (permanent): – Color change, precipitate formation, gas bubbles, flames, heat release, cooling, light • Other clues: – New odor, permanent new state Copyright © Houghton Mifflin Company. All rights reserved. 6|2 Evidence of Chemical Reactions (cont.) Copyright © Houghton Mifflin Company. All rights reserved. 6|3 Chemical Equations • Shorthand way of describing a reaction • Provides information about the reaction: – Formulas of reactants and products – States of reactants and products – Relative numbers of reactant and product molecules that are required – CH4(g)+ 2O2(g) → CO2(g) + 2H2O(l) – Can be used to determine weights of reactants used and of products that can be made Copyright © Houghton Mifflin Company. All rights reserved. 6|4 Symbols Used in Equations • Symbols used after chemical formula to indicate state: – (g) = gas; (l) = liquid; (s) = solid – (aq) = aqueous, dissolved in water – e. g. NH3(aq) indicates ammonia dissolved in water Copyright © Houghton Mifflin Company. All rights reserved. 6|5 Conservation of Mass • Matter cannot be created or destroyed. • In a chemical reaction, all the atoms present at the beginning are still present at the end. • Therefore, the total mass cannot change. Copyright © Houghton Mifflin Company. All rights reserved. 6|6 Combustion of Methane • Methane gas burns to produce carbon dioxide gas and liquid water CH4(g) + O2(g) CO2(g) + H2O(l) O H C H H H + O O C + O H H O 1C+4H + 2O Copyright © Houghton Mifflin Company. All rights reserved. 1C+2O +2H+O 1C+2H+3O 6|7 Combustion of Methane Balanced • To show a reaction obeys the Law of Conservation of Mass, it must be balanced. CH4(g) + 2 O2(g) CO2(g) + 2 H2O(l) H H C H H O + O C + O O O 1C + 4H + 4O Copyright © Houghton Mifflin Company. All rights reserved. O O + H H + O H H 1C + 4H + 4O 6|8 Writing Equations • Use proper formulas for each reactant and product. • Proper equation should be balanced. – Obey Law of Conservation of Mass. – All elements on reactants side also on product side. – Equal numbers of atoms of each element on reactant side as on product side. • Balanced equations show the relationship between the relative numbers of molecules of reactants and products. – Can be used to determine mass relationships Copyright © Houghton Mifflin Company. All rights reserved. 6|9 Balancing Chemical Equations • If the equation is in words, write the formulas for the reactants and products (include physical states). • Balance the equation by counting the atoms on both sides of the equation and changing the coefficients as needed. Never change the subscripts! • This is done by trial and error. Start with the most complicated compound first. • The best balanced equation is the one with the smallest integer coefficients (not fractions). Copyright © Houghton Mifflin Company. All rights reserved. 6 | 10 Balance the following equations: • Solid potassium reacts with gaseous nitrogen to form solid potassium nitride. • C3H8(g) + O2(g) → CO2(g) + H2O(l) • CuSO4(aq) + KI(s) → CuI(s) + I2(s) + K2SO4(aq) Copyright © Houghton Mifflin Company. All rights reserved. 6 | 11