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Chem I Ch 10 Notes/ Chem I H chapter 11 notes 10A The atomic mass is found by checking the periodic table. The atomic mass is the number of grams of an element that is numerically equal to the mass of an atomic mass unit. atomic mass C = 12.0 g The atomic mass is the mass of one mole of atoms. Mole – quantity such that there are as many atoms as in 12 g of carbon The mass of a mole of NaCl is the molar mass. 1 atom 1 mole 1 molecule C 12.0 u 12.0 g Cl2 Fe 55.8 u 55.8 g H 2O Cu 63.5 u 63.5 g 2Cl 2H 1 mole 2 X 35.5u = 71.0u 71.0 g 2 X 1.0u = 2.0u 1O 1 X 16.0u = 16.0u 18.0 g 18.0u C3H6 3C 3 X 12.0u=36.0u 6H 6 X 1.0u= 6.0u 42.0u 1 formula unit Al2(SO4)3 2Al, 2 X 27.0u = 54.0u 3S, 3 X 32.1u = 96.3u 12 O, 12 X 16.0u = 192.0u 342.3u 1 mole 342.3 g 42.0 g Notes Converting grams to moles 10B To convert first write what you are given. Then “times sign draw a line”. Place what you want above the line and the given below the line. “mol” always has a coefficient of 1. Where you see “g”, go to the periodic table to find the value. Ex 1 How many grams are in 6.50 moles of H2SO4? 6.50 moles × 98.1 g = 638 g 1 mol 2H 2 X 1.0 = 2.0g 1S 1 X 32.1 = 32.1g 4O 4 X 16.0 = 64.0g 98.1g Ex 2 What is the mass in grams of 5.90 mol C8H18? 8C 8 X 12.0 = 96.0g 5.90 mol 114.0 g 673g 1mol 18H 18 X 1.0 = 18.0g 114.0g Ex 3 What is the number of moles in 432 g Ba(NO3)2? 1 Ba 1 X 137.3 = 137.3g 2 N 2 X 14.0 = 28.0g 6O 6 X 16.0 = 96.0g 261.3g 432 g 1 mol 1.65 mol 261.3 g Moles, Atoms, Molecules 10C Representative particle - atom, molecule, or formula unit. A mole of a substance contains 6.02 X 1023 representative particles Avogadro’s number = 6.02 X 1023 Mole – SI unit used to measure number of representative particles in a substance A dozen is to eggs as mole is to atoms. Conversion questions to answer – What’s the unknown What is given How many times signs Molecules will always have 1 or 6.02 X 1023 EX 1 How many moles of magnesium is 1.25 X 1023 atoms of magnesium? 1.25 × 10 23 atoms × 1 mol 6.02 × 10 23 atoms = 0.208 mol EX 2 How many atoms are in 2.12 mol of C3H8 (propane)? 6.02 1023 molecules 11 atoms 2.12 mol 1.40 1025 atoms 1 mol molecule Percent Composition % mass mass of element 100% mass of compound Ex 1 Find the % composition of C3H8. 3C 3 X 12.0 = 36.0g 8H 8 X 1.0 = 8.0g 44.0g %C 36.0g 100% 81.8% 44.0g %H 8.0g 100% 18.2% 44.0g Ex 2 What is the percentage of nitrogen in NH3? 1N 1 X 14.0 = 14.0g 3H 3 X 1.0 = 3.0g 17.0g %N 14.0g 100% 82.4% 17.0g 10D Empirical Formulas 10E Empirical formula – lowest whole-number ratio of the elements in a compound (divide by – Greatest Common Factor) CNH4 not C2N2H8 Empirical Formula Calculations 1. Change the given information to moles for each element. 2. Divide each mole answer by the smallest number of moles. 3. If the answers from step 2 are not whole numbers then divide by the smallest decimal part. 4. Write the formula with the mole ratio as subscripts. EX 1 Find the empirical formula. A compound contains 9.31g of Ag and 0.69g of O. 9.31g Ag 1 mol 0.0866 2 107.9g 0.0431 0.69g O 1 mol 0.0431 1 16.0g 0.0431 Ag2O EX 2 A compound contains 25.9% N and 74.1% O. Find the empirical formula. 25.9g N 1 mol 1.85 1 14.0g 1.85 74.1g O 1 mol 4.63 2.50 16.0g 1.85 N2O5 1.5 = 2 2.50 .5 = 5 Molecular Formulas 10F Molecular formula – empirical formula or its multiple Several compounds can have the same empirical formula but different molecular formulas. Convert molecular empirical Divide subscripts by greatest common factor empirical molecular multiply subscripts by molar mass empirical formula mass EX 1 The empirical formula is CH4N and the molar mass is 60.0 g. Find the molecular formula. C 1 X 12.0 = 12.0g 4H 4 X 1.0 = 4.0g 60.0g 2 30.0g C2H8N2 N 1 X 14.0 = 14.0g 30.0g EX 2 Find the molecular formula of C4H6O if the molar mass is 280.0g. 4C 1 X 12.0 = 48.0g 6H 4 X 1.0 = 6.0g O 1 X 14.0 = 16.0g 70.0g 280.0g 4 70.0g C16H24O4 Name______________________Pd._____ Date_________ Chem I H Chapter 11 Notes/ Chem I Chapter 10 Notes 10A The atomic mass is found by checking the __________ ______. The _____________ ________ is the number of grams of an element that is numerically equal to the mass of an atomic mass unit. (atomic mass C = 12.0 g) The atomic mass is the mass of one ____________ of atoms. Mole – quantity such that there are as many atoms as in 12 g of carbon The mass of a mole of NaCl is the ______________ ________. 1 atom 1 mole 1 molecule C 12.0 u 12.0 _ Cl2 2Cl 2 X 35.5u = Fe 55.8 u 55.8 _ H 2O 2H 2 X 1.0u = Cu 63.5 u 63.5 _ 1O 1 X 16.0u = C3H6 3C 3X 6H 6x 1 formula unit Al________________________ Al2(SO4)3 S________________________ O ________________________ 1 mole 1 mole 71.0 _ Ch 10 Notes Converting grams to moles 10B To convert first write what you are ______________________. Then “times sign__________________________________”. Place what you want above the line and the given below the line. “mol” always has a coefficient of __________. Where you see “g”, _______ to the periodic table to find the value. Ex 1 How many grams are in 6.50 moles of H2SO4? Show all work 2H ________________________ ____________________ 1S ____________________ 4O ____________________ ____________________ Ex 2 What is the mass in grams of 5.90 mol C8H18? 8C__________ ____________ ______________________________ Ex 3 What is the number of moles in 432 g Ba(NO3)2? Ba N O _____________________________________ g Moles, Atoms, Molecules 10C Representative particle - atom, molecule, or _________ _____ A mole of a substance contains ____________________ representative particles Avogadro’s number = ______________________ _________– SI unit used to measure number of representative particles in a substance A dozen is to eggs as mole is to atoms. Conversion questions to answer – What’s the ______________ What is given How many times _________ Molecules will always have 1 or ___________________ EX 1 How many moles of magnesium is 1.25 X 1023 atoms of magnesium? ___________________________________________ EX 2 How many atoms are in 2.12 mol of C3H8 (propane)? ___________________________________________ Percent Composition % mass mass of element 100% mass of compound Ex 1 Find the % composition of C3H8. 3C ______________ 8H ______________ _____ _____________________________ _____________________________ Ex 2 What is the percentage of nitrogen in NH3? 1N ______________ 3H ______________ _____ _____________________________ 10D Empirical Formulas 10E Empirical formula – lowest __________________ ratio of the elements in a compound (divide by – Greatest Common Factor) i.e. CNH4 not C2N2H8 Empirical Formula Calculations 5. Change the given information to __________ for each element. 6. Divide each mole answer by the _________________ number of moles. 7. If the answers from step 2 are not whole numbers then divide by the smallest decimal part. 8. Write the formula with the mole ratio as ___________. EX 1 Find the empirical formula. A compound contains 9.31g of Ag and 0.69g of O. 9.31 g Ag X 0.69 g O X Which answer is the smallest number?____________________ 9.31g Ag 1 mol 0.0866 2 107.9 g 0.0431 0.69 g O 1 mol 0.0431 1 16.0 g 0.0431 ______________________ EX 2 A compound contains 25.9% N and 74.1% O. Find the empirical formula. (Hint: change % to grams) Molecular Formulas 10F Molecular formula – empirical formula or its ______________ Several compounds can have the same _____________ _____ but different molecular formulas. Convert molecular empirical Divide subscripts by ______________ __________ _________ empirical molecular multiply subscripts by ___________________ EX 1 The empirical formula is CH4N and the molar mass is 60.0 g. Find the molecular formula. C 1 X 12.0 = 12.0g 4H 4 X 1.0 = 4.0g N 1 X 14.0 = 14.0g 30.0g __________________ EX 2 Find the molecular formula of C4H6O if the molar mass is 280.0g. 4C 1 X 12.0 = 48.0g 6H 4 X 1.0 = 6.0g O 1 X 14.0 = 16.0g 70.0g ____________________ Ch 10 Test Reference Percent Composition % mass mass of element 100% mass of compound Empirical Formula Calculations 1. Change the given information to moles for each element. 2. Divide each mole answer by the smallest number of moles. 3. If the answers from step 2 are not whole numbers then divide by the smallest decimal part. 4. Write the formula with the mole ratio as subscripts. Convert molecular empirical Divide subscripts by greatest common factor Convert multiply subscripts by empirical molecular molar mass empirical formula mass