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_. Element Symbols: An element’s symbol can stand for one atom of the element or one mole of atoms of the element. (One mole = 6.02 x 1023 atoms of an element.) Write the symbol for the following elements. 1. oxygen 11. plutonium 2. hydrogen 12. americium 3. chlorine 13. radium 4. mercury 14. germanium 5. fluorine 15. zinc 6. barium 16. arsenic 7. helium 17. lead 8. uranium 18. iron 9. radon 19. calcium 10. sulfur 20. cobalt Write the name of the element that corresponds to each of the following symbols. 21. Kr 31. Cu 22. K 32. Ag 23. C. 33. P 24. Ne 34. Mn 25. Si 35. I 26. Zr. 36. Au 27. Sn 37. Mg 28. Pt 38. Ni 29. Na 39. Br 30. Al 40. Hg 1 Atomic Structure: Quiz #3 An atom is made up of protons and neutrons (both found in the nucleus) and electrons (in the surrounding electron cloud). The atomic number is equal to the number of protons. The mass number is equal to the number of protons plus neutrons. In a neutral atom, the number of protons equals the number of electrons. The charge on an ion indicates an imbalance between protons and electrons. Too many electrons produces a negative charge, too few, a positive charge. This structure can be written as part of a chemical symbol. Example: 7 protons 8 neutrons (15 - 7) 15 +3 mass number N charge 4 electrons remaining (7-3) atomic number7 Complete the following chart. Element/ Ion 1. H 2. Atomic Number Atomic Mass Mass Number Protons Neutrons Electrons H+ 3 12 6C 4. 73Li+ 5. 35 17CI6. 39K 19 7. 2412Mg2+ 8. As39. Ag 10. Ag+1 11. S-2 12. U 2 Isotopes and Average Atomic Mass: Elements come in a variety of isotopes, meaning they are made up of atoms with the same atomic number but different atomic masses. These atoms differ in the number of neutrons. The average atomic mass is the weighted average of all the isotopes of an element. Example: A sample of cesium is 75% average atomic mass? 133 Cs, 20% 132 Cs and 5% 134 Cs. What is its Answer: .75 x 133 = 99.75 .20 x 132 = 26.4 .05 = 134 = 6.7 Total = 132.85 amu = average atomic mass Determine the average atomic mass of the following mixtures of isotopes. 1. 80% 1271, 17% 1261, 3% 1281 2. 50% 197 Au, 50% 198Au 3. 15% 55Fe, 85% 56Fe 4. 99% lH, 0.8% 2H, 0.2% 3H 5. 95% 14N, 3% 15N, 2% 16N 6. 98% 12C, 2% 14C 3 Electron Configuration: Electrons are distributed in the electron cloud into principal energy levels (l, 2, 3), sublevels (s, p, d, f), orbitals (s has 1, P has 3, d has 5, f has 7) and spin (two electrons allowed per orbital). Example: Draw the electron configuration of sodium (atomic # 11). Answer: 1s2 2s22p6 3s1 Draw the electron configurations of the following atoms. 1. Cl 2. N 3. Al 4. 0 5. P 6. K 7. Ti 8. Ar 9. Zn 10. Si 11. C 12. F 13. I 14. Sr 15. Mn 16. Mg 4 Valence Electrons: The valence electrons are the electrons in the outermost principal energy level. They are always "s" or "s and p" electrons. Since the total number of electrons possible in s and p sublevels is eight, there can be no more than eight valence electrons. Determine the number of valence electrons in the atoms below. Example: Carbon Electron configuration is 1s 2 2s2 2p2. Carbon has 4 valence electrons. 1. fluorine 11. lithium 2. phosphorus 12. zinc 3. calcium 13. carbon 4. nitrogen 14. iodine 5. iron 15. oxygen 6. argon 16. barium 7. potassium 17. aluminum 8. helium 18. hydrogen 9. magnesium 19. xenon 10. sulfur 20. copper 5 Periodic Table Worksheet: 1. Where are the most active metals located? 2. Where are the most active nonmetals located? 3. As you go from left to right across a period, the atomic size (decreases increases). Why? / 4. As you travel down a group, the atomic size (decreases / increases). Why? 5. A negative ion is (larger / smaller) than its parent atom. 6. A positive ion is (larger / smaller) than its parent atom. 7. As you go from left to right across a period, the first ionization energy generally (decreases / increases). Why? 8. As you go down a group, the first ionization energy generally (decreases / increases). Why? 9. Where is the highest electronegativity found? 10. Where is the lowest electronegativity found? 11. Elements of Group 1 are called 12. Elements of Group 2 are called 13. Elements of Group 3-12 are called 14. As you go from left to right across the periodic table, the elements go from (metals / nonmetals) to ( metals / nonmetals). 15. Group 17 elements are called 6 16. The most active element in Group 17 is 17. Group 18 elements are called 18. What sublevels are filling across the Transition Elements? 19. Elements within a group have a similar number of 20. Elements across a series have the same number of 21. A colored ion generally indicates a 22. As you go down a group, the elements generally become ( more / less) metallic. 23. The majority of elements in the periodic table are (metals / nonmetals). 24. Elements in the periodic table are arranged according to their 25. An element with both metallic and nonmetallic properties is called a 7 Ionic Bonding: Ionic bonding occurs when a metal transfers one or more electrons to a nonmetal in an effort to attain a stable octet of electrons. For example, the transfer of an electron from sodium to chlorine can be depicted by a Lewis dot diagram. Na' + .CI: -- Na+CI Calcium would need two chlorine atoms to get rid of its two valence electrons. CI' + a + .CI: Ca+2CI2 Show the transfer of electrons in the following combinations. 1. K + F 2. Mg + I 3. Be + S 4. Na + 0 5. AI + Br Covalent Bonding: Covalent bonding occurs when two or more nonmetals share electrons, attempting to attain a stable octet of electrons at least part of the time. 8 For example: H. + xCI_ _CI _ J'- xx Note that hydrogen is content with 2, not 8, electrons. Show how covalent bonding occurs in each of the following pairs of atoms. Atoms may share one, two or three pairs of electrons. 1 . H + H (H2) 2. F + F (F) 3. o + o (°2) 4. N + N (N2) 5. C + o (CO) 6. H + o (H2O) Balancing Chemical Equations: Rewrite and balance the equations below. 1. N2 + H2 --,-. NH3 2. KCI03 --,-. KCI + 2 9 3. NaCI + F2 --,-. NaF + CI2 4. H2 + 2 --,-. H2O 5. AgN03 + MgCI2 --,-. AgCI + Mg(N03)2 6. AIBr 3 + K2SO 4 --,-. KBr + AI2(SO 4)3 7. CH4 + 2 --,-. CO2 + H2O I8. C3Ha + 2 --,-. CO2 + H2O 9. CaH,a + 2 --,-. 1 2 + H2O 10. FeCI3 + NaOH --,-. Fe(OH)3 + NaCI 11. P + 2 --,-. P2OS 12. Na + H2O --,-. NaOH + H2 13. Ag2O --,-. Ag + 2 14. Sa + 2 --,-. S03 15. CO2 + HP --,-. C6H1206 + 2 16. K+MgBr2 --,-. KBr+Mg 17. HCI + CaC03 --,-. CaCI2 + H2O + CO2 10 Word Equations: Write the word equations below as chemical equations and balance. 1. zinc + lead (II) nitrate yield zinc nitrate + lead 2. aluminum bromide + chlorine yield aluminum chloride + bromine 3. sodium phosphate + calcium chloride yield chloride calcium 4. potassium chlorate when heated yields potassium 5. aluminum + hydrochloric acid yield phosphate + sodium chloride + oxygen gas aluminum chloride + hydrogen gas 6. calcium hydroxide + phosphoric acid yield calcium phosphate + water 7. copper + sulfuric acid yield copper (II) sulfate + water + sulfur dioxide 8. hydrogen + nitrogen monoxide yield water + nitrogen 11 Classification of Chemical Reactions: Classify the reactions below as synthesis, decomposition, single replacement (cationic or anionic) or double replacement. 1. 2H2 + °2 _ 2H20 2. 2H20 _ 2H2 + °2 3. Zn + H2SO4 _ ZnS04 + H2 4. 2CO + °2 _ 2CO2 5. 2HgO _ 2Hg + °2 6. 2KBr + CI2 _ 2KCI + Br2 7. CaO + H2O _ Ca(OH)2 8. AgN03 + NaCI _ AgCI + NaN03 9. 2H202 _ 2H20 + °2 10. Ca(OH)2 + H2SO4 _. CaSO4 + 2H20 12 Predicting Products of Chemical Reactions: Predict the products of the reactions below. Then, write the balanced equation and classify the reaction. 1. magnesium bromide + chlorine 2. aluminum + iron (III) oxide _ II II 3. silver nitrate + zinc chloride 4. hydrogen peroxide (catalyzed by manganese dioxide) 5. zinc + hydrochloric acid 6. sulfuric acid + sodium hydroxide 1_7. sodium + hydrogen 8. acetic acid + copper 13