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World of Chemistry 102 First Exam Name ______________________ SPRING 2006 1. (3 pts) When sodium metal is added to water, the following reaction occurs. 2Na + 2H2O 2Na+(aq) + 2OH-(aq) + H2 Identify the substance that is oxidized ______________ Identify the substance that is reduced ______________ Identify the reducing agent ______________ 2. (4 pts) Based on their relative positions in the periodic table, which might you expect to be a better oxidizing agent, Cl2 or I2? Give a reason for your choice. 3. (4 pts) Based on their relative positions in the periodic table, which might you expect to be a better reducing agent, Na or Cs? Give a reason for your choice. 4. (6pts) Sketch a voltaic cell that uses the oxidation-reduction reaction Cu(s) + 2Ag+(aq Cu2+(aq) + 2Ag(s) Which atom or ion is reduced? ________Which atom or ion is oxidized?________ 5. (8 pts) Organic compounds are named according to the functional group each contains. Illustrate at least four of the eight groups below with the structure of an organic compound and name the compound: a. an alcohol b. an acid c. an amine d. an aldehyde e. a ketone f. an ester g. an ether h. an amide 6. (4 pts) Name four elements that are most often found in organic molecules, especially biomolecules. _____________ _______________ _______________ ______________ 7. (6 pts) Write the Lewis structure and give the name of a saturated hydrocarbon. Write the Lewis structure and give the name of an unsaturated hydrocarbon. Write the Lewis structure and give the name of an aromatic hydrocarbon. 8. (6 pts) Draw the Lewis structure and identify the lone pairs (if any) in the molecule methane, CH4. Draw the Lewis structure and identify the lone pairs (if any) in the molecule methyl amine, CH3NH2. Draw the Lewis structure and identify the lone pairs (if any) in the molecule methanol, CH3OH. 9. (5 pts)What three elements are found in a carbohydrate? What is the general composition of a carbohydrate. 10. (4 pts) How does the formula for a monosaccharide, C6H12O6, differ from that of a disaccharide. Why is there a difference? 11. (2 pts) Write the formula for a pentasaccharide. 12. (5 pts) Name the monomer(s) in each of the following: Starch_____________________________________________ Protein_____________________________________________ Polyethylene________________________________________ Cellulose___________________________________________ Polypeptide__________________________________________ 13. (2 pts) What products are formed when a protein undergoes hydrolysis. 14. (2 pts) What is the difference between a saturated and an unsaturated fat? 15. (4 pts) Describe the four levels of protein structure. 16. (2 pts) Alcohols, Esters, carboxylic acids, amides, ketones, aldehydes, ethers, and amines represent the functional groups in organic chemistry. Among this list of functional groups select the one which is an example of: A protein _______________________ A fat ___________________________ 17. (4 pts)What is the difference in the structure of starch and the structure of cellulose? How does this difference impact on the difference in their properties? 18. (4 pts) What are the two ways in which DNA nucleotides differ from RNA nucleotides? 19. (3 pts) What are the two classes of vitamins. What property distinguishes them from each other? 20. (4 pts) Why is it often more healthful to eat vegetables that have been steamed rather than boiled? 21. (4 pts) Which class of vitamins when taken in large enough quantities to be toxic will our bodies be more tolerant of and why? 22. (6 pts) What are lipoproteins? Which classification of lipoproteins are more desireable to have in the blood stream and why? 23. (9 pts) Identify and name all of the functional groups in the following compound.