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Physics 130 - University of North Dakota
Physics 130 - University of North Dakota

... Simple Harmonic Motion (SHM) Real objects are “elastic” (to some extent) Elastic: Object returns to original shape after deformation Original shape called “Equilibrium” Object resists deformation with force Force called “Restoring Force” Force proportional to deformation Force is in opposit ...
General Equilibrium
General Equilibrium

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printable version

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Equilibrium Constant

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Chapter 19, part II Notes

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The Equilibrium Constant

... use stoichiometry to find the change in the other parts. 2) If not given, let x be the change in concentration of the reactant with the smallest coefficient (to avoid fractions) 3) You will usually need to do one of these steps in order to solve: ...
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... had come to equilibrium, the concentration of PCl3 was found to be 0.12 mole/L. Determine the Kc value. (b) Given K and one or more initial concentrations, determine the equilibrium concentrations General Method: Set up a "concentration table" based on an unknown "x" -- usually one of the equilibriu ...
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Equilibrium Constant- Keq

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Consider the following chemical equilibrium A B
Consider the following chemical equilibrium A B

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... 2. For systems involving gases, the equilibrium constant is often determined by using partial pressure instead of concentration. Given the following reaction at equilibrium at the partial pressures of the ...
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Unit 8: Equilibrium Content Outline: Shifting Equilibrium and Le

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Lecture3_Module_19

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Chemical equilibrium

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Chemistry 341

... familiarity with differential and integral calculus. The first part of the course focuses on the basic concepts, principles, and laws of classical thermodynamics, with emphasis on formulations and operational definitions most relevant to chemical systems and chemical processes. These concepts, princ ...
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Word - IPFW.edu

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Chemical Equilibrium

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... 8. Use Table I data to determine the stability of the compounds listed. (The more exothermic the reaction is, the lower in energy the products are. Low energy corresponds to high stability.) 9. State the two fundamental thermodynamic drives in nature. (Memorize: “Nature is lazy and disorganized.) 10 ...
Kc and Kp Conversions Hess`s Law in Equilibrium Constants
Kc and Kp Conversions Hess`s Law in Equilibrium Constants

... The equilibrium constant of a reaction that has been multiplied by a number is the equilibrium constant raised to a power that is equal to that number. ...
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Topics 7 and 17 Outlines

... • The reaction quotient (Q) measures the relative amount of products and reactants present during a reaction at a particular point in time. Q is the equilibrium expression with non-equilibrium concentrations. The position of the equilibrium changes with changes in concentration, pressure, and temper ...
Wanganui High School
Wanganui High School

... asked to write K expressions use K, if KC then write KC! o Do I need the state symbols? Not for this Unit Standard but if you are putting them in, put them ALL in, and put them in the right place, inside the ] bracket eg [H2(g)]3 9 [H2)](g)3 8, [FeSCN]2+(aq) PC 1.2 Changes in equilibrium position ar ...
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Chapter 2 PowerPoint

ChE 215, Physical Chemistry
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... The objective of this course is to introduce the basic topics in Kinetics, Thermodynamics and Statistical Mechanics. In fact this course present collection of distinct topics particularly useful to chemical engineering students. The basic principles in the course are demonstrated by six experiments ...
Equilibrium Review worksheet
Equilibrium Review worksheet

... substances involved in this equilibrium. The vessel is heated to 650 °C. Determine the equilibrium amount concentrations of each substance, organizing your values in an ICE table. (Hint: use the value of Kc to determine which side of the reaction is favored, and therefore which substances will incre ...
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Thermodynamic equilibrium

Thermodynamic equilibrium is an axiomatic concept of classical thermodynamics. It is an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by permeable walls. In thermodynamic equilibrium there are no net macroscopic flows of matter or of energy, either within a system or between systems. In a system in its own state of internal thermodynamic equilibrium, no macroscopic change occurs. Systems in mutual thermodynamic equilibrium are simultaneously in mutual thermal, mechanical, chemical, and radiative equilibria. Systems can be in one kind of mutual equilibrium, though not in others. In thermodynamic equilibrium, all kinds of equilibrium hold at once and indefinitely, until disturbed by a thermodynamic operation. In a macroscopic equilibrium, almost or perfectly, exactly balanced microscopic exchanges occur; this is part of the notion of macroscopic equilibrium.An isolated thermodynamic system in its own state of internal thermodynamic equilibrium has a uniform temperature. If its surroundings impose some unchanging long range force field on it, it may consist of one phase or may exhibit several spatially unchanging internal phases. If its surroundings impose no long range force field on it, then either (1) it is spatially homogeneous, with all intensive properties being uniform; or (2) it has several internal phases, which may exhibit indefinitely persistent continuous spontaneous microscopic or mesoscopic fluctuations.In non-equilibrium systems, by contrast, there are net flows of matter or energy. If such changes can be triggered to occur in a system in which they are not already occurring, it is said to be in a metastable equilibrium.It is an axiom of thermodynamics that when a body of material starts from a non-equilibrium state of non-homogeneity or chemical non-equilibrium, and, by a thermodynamic operation, is then isolated, it spontaneously evolves towards its own internal state of thermodynamic equilibrium. This axiom is presupposed by the second law of thermodynamics, which restricts what can happen when a system, having reached thermodynamic equilibrium, with a well defined entropy, is subject to a thermodynamic operation.
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