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the PDF - JILA - University of Colorado Boulder
the PDF - JILA - University of Colorado Boulder

Measurement and assignment of the size-dependent
Measurement and assignment of the size-dependent

Two-Dimensional Quantum Dynamics of O2 Dissociative Adsorption
Two-Dimensional Quantum Dynamics of O2 Dissociative Adsorption

Chapter 11 Clickers
Chapter 11 Clickers

Spectroscopic study of chromium, iron, OH, fluid and mineral
Spectroscopic study of chromium, iron, OH, fluid and mineral

Chapter 1 Rotation of an Object About a Fixed Axis
Chapter 1 Rotation of an Object About a Fixed Axis

... viewed as the product of the distance r and the tangential component of the force, Ft . (c) Torque τ can also be viewed as the product of the force F and the distance r⊥ (often called the moment arm, or lever arm). where Ft = F sin φ is the component of the force perpendicular to r, or as τ = (r sin ...
KLH2002 - the Research Group of Angelika Kühnle
KLH2002 - the Research Group of Angelika Kühnle

Demonstrating the style for the Journal of Physics: Conference series
Demonstrating the style for the Journal of Physics: Conference series

... optical dipole transitions of the trion state in a singly charged QD taking into account the spin relaxation dynamics. Our theoretical and numerical approach yields the time evolution of the spin population of the trion state which is in good agreement with the time-resolved polarised photoluminesce ...
time-dependent density functional theoretical - Prof. Shih
time-dependent density functional theoretical - Prof. Shih

... and molecules predicted by these GGA density functionals [9–12] are reasonably accurate, the excited-state energies and the ionization potentials obtained from the highest occupied orbital energies of atoms and molecules are far from satisfactory, typically 40 to 50% too low [13]. The problem of the ...
The structure of the energy bands and optical absorption in osmium
The structure of the energy bands and optical absorption in osmium

Stereochemistry at Tetrahedral Centers
Stereochemistry at Tetrahedral Centers

... • Chirality most often results when a carbon atom is bonded to 4 unique groups of atoms. ...
The Calculation of Molecular Similarity: Principles and Practice
The Calculation of Molecular Similarity: Principles and Practice

Diatomic molecules in ultracold Fermi gases—novel
Diatomic molecules in ultracold Fermi gases—novel

... interaction in the s-wave channel (negative s-wave scattering length a). However, for ordinary values of a, the superfluid transition temperature is extremely low. For this reason, the efforts of experimental groups have been focused on modifying the intercomponent interaction by using Feshbach reso ...
Voltage-dependent conductance states of a single
Voltage-dependent conductance states of a single

... The relevance of mechanism (ii) was tested by fixing the SnPc molecule more rigidly to the metal surface. This was achieved by removing the eight outermost H atoms of the molecule [15, 17]. The resulting strong chemical bonds between C atoms of SnPc and the Ag substrate are expected to inhibit later ...
Imaging of single-chromophore molecules in aqueous
Imaging of single-chromophore molecules in aqueous

... wavelength of 685–720 nm. We use a custom-made interference filter made by Chroma Technology Corporation, Brattleboro, VT, with >80% transmission in the 585–680 nm band, and with optical density >3 in the 690–730 nm band. However, the O-H bend mode, at 1645 cm−1, falls within the fluorescence band, ...
M. Sc. in Industrial Chemistry Centre for Applied Chemistry Syllabus
M. Sc. in Industrial Chemistry Centre for Applied Chemistry Syllabus

18.1 Raman Scattering
18.1 Raman Scattering

Chapter 23
Chapter 23

A  comparative analysis  of two methods for the... of electric-field-induced  perturbations to molecular vibration
A comparative analysis of two methods for the... of electric-field-induced perturbations to molecular vibration

Measurement and data processing and analysis
Measurement and data processing and analysis

Ch11 - Rolling, Torque, and Angular Momentum
Ch11 - Rolling, Torque, and Angular Momentum

Detection Sensitivity of Single-Molecule Optical Absorption at Room
Detection Sensitivity of Single-Molecule Optical Absorption at Room

... where krelax is the krelax,2 in Figure 1a, which is the rate constant of the rate-limiting step in the sequential relaxation process from the vibronic states prepared by the optical excitation to the lowest vibrational level in the ground electronic state. hv is the photon energy, σ is the absorptio ...
Molecules in Motion - Martin Quack
Molecules in Motion - Martin Quack

Vacuum-ultraviolet to infrared supercontinuum in hydrogen
Vacuum-ultraviolet to infrared supercontinuum in hydrogen

2848-R - Bulgarian Chemical Communications
2848-R - Bulgarian Chemical Communications

< 1 ... 8 9 10 11 12 13 14 15 16 ... 53 >

Rotational spectroscopy



Rotational spectroscopy is concerned with the measurement of the energies of transitions between quantized rotational states of molecules in the gas phase. The spectra of polar molecules can be measured in absorption or emission by microwave spectroscopy or by far infrared spectroscopy. The rotational spectra of non-polar molecules cannot be observed by those methods, but can be observed and measured by Raman spectroscopy. Rotational spectroscopy is sometimes referred to as pure rotational spectroscopy to distinguish it from rotational-vibrational spectroscopy where changes in rotational energy occur together with changes in vibrational energy, and also from ro-vibronic spectroscopy (or just vibronic spectroscopy) where rotational, vibrational and electronic energy changes occur simultaneously.For rotational spectroscopy, molecules are classified according to symmetry into spherical top, linear and symmetric top; analytical expressions can be derived for the rotational energy terms of these molecules. Analytical expressions can be derived for the fourth category, asymmetric top, for rotational levels up to J=3, but higher energy levels need to be determined using numerical methods. The rotational energies are derived theoretically by considering the molecules to be rigid rotors and then applying extra terms to account for centrifugal distortion, fine structure, hyperfine structure and Coriolis coupling. Fitting the spectra to the theoretical expressions gives numerical values of the angular moments of inertia from which very precise values of molecular bond lengths and angles can be derived in favorable cases. In the presence of an electrostatic field there is Stark splitting which allows molecular electric dipole moments to be determined.An important application of rotational spectroscopy is in exploration of the chemical composition of the interstellar medium using radio telescopes.
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