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66 In Thermodynamics, the total energy E of our system (as
66 In Thermodynamics, the total energy E of our system (as

... by TdS, since the latter is always large due to second law T dS ≥ dQ to get: dU ≤ T dS + dW, or: dW ≥ dU − T dS = dF Therefore, the maximal work is always greater or equal the free energy. In other words, a certain amount of internal energy dU can never be converted completely into work, a part is a ...
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... to do work and is the sum of its enthalpy (H) plus the product of the temperature and the entropy (S) of the system. This quantity can be defined as: G=H−TS or more completely as G=U+PV−TS where •U = internal energy (SI unit: joule) •P = pressure (SI unit: pascal) •V = volume (SI unit: m 3 ) •T = te ...
Physics 231 Topic 14: Laws of Thermodynamics Wade Fisher
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... expansion at constant pressure of one atmosphere to four times its original volume. a) What is the new temperature? b) What is the work done on the gas? a) PV/T=constant so if V x4 then T x4 273K*4=1092 K b) W=-PV use PV=nRT before expansion: PV=1*8.31*273=2269 J after expansion: PV=1*8.31*1092=907 ...
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... • A state is the condition of a system as determined by its properties. • A simple compressible system is a system whose only mode of performing quasi-equilibrium work is through a change of its volume against a pressure. • The state postulate: The state of a simple compressible system consisting of ...
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