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Integrated X-ray L Absorption Spectra. Counting Holes in Ni
Integrated X-ray L Absorption Spectra. Counting Holes in Ni

... to NiIV, the number of d holes increases; hence, the L edge resonance intensity should also increase. This is indeed observed, most dramatically for KNiIVIO6 (Figure 1). The qualitative trend for L edge intensities to increase with Ni oxidation states is not a surprise. However, it is gratifying to ...
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... were also varied. According to the thermodynamic data from NIST,[10] ΔHf(CO) = −110.53 kJ/mole, ΔH(W) = 851.03 kJ/mole, and ΔHf[W(CO)6] = −882.9 kJ/mole, which gives a thermodynamic mean BDE(W–CO) value of 1.85 eV3 that is consistent with the value calculated here for t1 = 0 (1.84 eV). All the other ...
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... precise controllability, SPPs can enable novel approaches for controlling electronic processes on surfaces. For example, it has been shown that they can be used to tune the work function of a metal [8], induce molecular dissociation through electron heating [9], and allow chemical identification of ...
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... several nuclei of the same element, but with different bonds, different local magnetic fields will be felt by these nuclei. For every bond type, the shielding is proportional to applied field, which can be expressed by the effective field Bef f at the nucleus: Bef f = Bmol (1 − σ) ...
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Electron paramagnetic resonance



Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a technique for studying materials with unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but it is electron spins that are excited instead of the spins of atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes or organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford.
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