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revised acid bases
revised acid bases

... in water can tell us which is the stronger acid of HCl and HBr because both react essentially completely to give H3O+ . Water is said to have levelling effect. Since the effective proton affinity of H2O in water is 1130 kJ mol-1 all acids with conjugate bases having effective proton affinity smaller ...
Enzyme
Enzyme

... • It is an inorganic ion which loosely bound to an enzyme or an substrate to increase the chance to an enzyme-substrate complex forming. Some times, the inorganic ions are free and does not bind to the enzyme or substrate, • e.g. copper, iron, calcium, Cl- etc. ...
FREE Sample Here
FREE Sample Here

... ATP is the main energy currency in cells, and it can especially be used to drive condensation reactions that produce macromolecular polymers. How does ATP normally catalyze the condensation reaction, which by itself is energetically unfavorable? A. It transfers its terminal phosphate to an enzyme an ...
- DigitalCommons@Linfield
- DigitalCommons@Linfield

... stretches determine the secondary structure of the molecule. In the spectra of BSA, the amide stretches show a alpha-helical structure. The similar spectra between the colloidal solution and the nanoparticle film shows that BSA is orienting itself in the same manor such that the same amino acid resi ...
Electron Transport Chain
Electron Transport Chain

... NAD+ and Electron Transport Chain • In cellular respiration, glucose and other organic molecules are broken down in a series of steps • Electrons from organic compounds are usually first transferred to NAD+, a coenzyme • As an electron acceptor, NAD+ functions as an oxidizing agent during cellular ...
PPT - Bruce Blumberg
PPT - Bruce Blumberg

... • Screen with transposon – Recover positives, sequence flanking region • Use flanking sequence to screen normal genomic library – What type of library will you screen (λ, BAC, etc)? Why? – If insertion is a gene trap or related • You can digest mutant DNA with an enzyme that linearizes the vector • ...
Macromolecular peroxo complexes of Vanadium(V) and
Macromolecular peroxo complexes of Vanadium(V) and

... Different polymeric materials, natural and synthetic, prepared both by addition and condensation polymerization are reported as matrices to anchor complexes.72 In the case of linear or branched organic polymers, the macromolecular metal complexes are soluble in organic solvents and their structure c ...
Enzymes | Principles of Biology from Nature Education
Enzymes | Principles of Biology from Nature Education

... vitamins that are essential for proper nutrition and bodily function are coenzymes (e.g., vitamin C). For example, coenzyme A interacts with acetyl groups in fatty acid synthesis and pyruvate oxidation pathways of cellular respiration. Coenzyme A plays such an important role in these reactions, amon ...
Why does nature use zinc–a personal view†
Why does nature use zinc–a personal view†

... No other metal has as many functions in living organisms as the metal zinc. In one of the early reviews on its biochemistry1 Vallee noted that it occurs in all six groups of the IUBMB enzyme classification. The number of enzymes known to contain zinc in the active center now exceeds 1000.2 In mid 200 ...
Bio-Organic Mechanism Game – Simplistic biochemical structures
Bio-Organic Mechanism Game – Simplistic biochemical structures

... resonance stabilization in acetal formation or breakdown). Multiple resonance structures are not drawn. Only very occasionally is an intermediate drawn, when confusion arises from too many arrows going in too many different directions. Do not confuse these examples for real mechanisms! They are desi ...
Sam P. de Visser,* Jan-Uwe Rohde,* Yong
Sam P. de Visser,* Jan-Uwe Rohde,* Yong

... including the biodegradation and metabolism of toxic compounds in the body as well as the biosynthesis of hormones [1–7]. They utilize molecular oxygen at a heme center and react via oxygen atom transfer to substrates, leading to C H hydroxylation, C C epoxidation, aromatic hydroxylation, and hetero ...
ppt - Vanderbilt University
ppt - Vanderbilt University

... Hydrophobic effect. Proteins will fold so that hydrophobic amino acids are on the inside (shielded from water) and hydrophilic amino acids are on the outside (exposed to water). ...
Chem I Review Part 2
Chem I Review Part 2

... A. A Lewis structure in which there are no formal charges is preferred. B. Lewis structures with large formal charges (e.g., +2,+3 and/or -2,-3) are preferred. C. The preferred Lewis structure is one in which positive formal charges are on the most electronegative atoms. 89. What is the formal charg ...
1. Sucrose is a disaccharide. The diagram shows the structure of a
1. Sucrose is a disaccharide. The diagram shows the structure of a

... intestinal problems if they drink milk. Milk can be treated with the enzyme lactase and this reduces the amount of lactose present. The diagram shows an industrial reactor used to produce ...
Isolation and Characterization of Plastidic Glucose-6-Phosphate Dehydrogenase
Isolation and Characterization of Plastidic Glucose-6-Phosphate Dehydrogenase

... Fig 8 GST fusion western blot and purification western ….……………………… 52 Fig 9 Native gel activity with DTT ………………………………………..………. 54 Fig 10 Effects of DTT on G6PDH activity …………………………………..……. 56 Fig 11 Effects of DTT on 6PG and overexpression ………………………………. 58 Fig 12 Kinetics of Km for G6PDH with NADPH ...
Novel Specific Halogenating Enzymes from Bacteria
Novel Specific Halogenating Enzymes from Bacteria

... Crystallization and elucidation of the three-dimensional structure revealed th at they contain a catalytical triad consisting of serine, histidine and aspartate residues and belong to the rx/P hydrolases (Hecht et al., 1994; Pelletier et al., 1995). These findings and the observation th at they requ ...
She2p Is a Novel RNA Binding Protein
She2p Is a Novel RNA Binding Protein

... Figure 1. Structure of the She2p Homodimer (A) Stereoview of the She2p homodimer with each monomer in blue or green (PyMOL, DeLano Scientific, CA). The second, less complete monomer was substituted with a superimposed first monomer to provide a fuller depiction of the She2p homodimer. Vertical line ...
Intermediate status of thermochemical energy storage - stage-ste
Intermediate status of thermochemical energy storage - stage-ste

... performed by thermogravimetry. They enlightened the necessity to pay attention to the initial particle size of these oxides since it influences the kinetics and the thermodynamics of the reaction. Especially, smaller particles would contribute in lowering the oxidation temperature, but it would also ...
Crystal structure of ATP sulfurylase from Saccharomyces cerevisiae
Crystal structure of ATP sulfurylase from Saccharomyces cerevisiae

... above speci®ed residues produce either reduced activity or inactive enzymes. This strongly indicates that nucleotide binding as well as sulfurylase activity involves residues of these motifs. Additionally, a fourth highly conserved motif can be found: the 356ISGTxxR363 module is widespread among the ...
Identifying Importance of Amino Acids for Protein
Identifying Importance of Amino Acids for Protein

... A way to test the importance of amino acids in experiments was proposed by Fersht and co-workers.78,79 The method, called protein engineering or F value analysis, is based on the engineering of a mutant protein with the amino acids under consideration replaced by other ones. The value of the free en ...
Sequence±structure±function studies of tRNA
Sequence±structure±function studies of tRNA

... their relationship to two distinct classes of enzymes that generate 5-methylpyrimidine in nucleic acids, namely RNA:m5U MTases and DNA:m5C MTases. The enzymatic mechanism of DNA:m5C methylation has been extensively studied by crystallography, mutagenesis, biophysical methods and molecular dynamics s ...
Section 5.3: Proteins
Section 5.3: Proteins

A bioinformatics study concerning the structural and functional
A bioinformatics study concerning the structural and functional

... is a cholesterol and fatty acid binding protein. There are two isoforms of cav1: the α- and the β-isoform. The β-isoform lacks the first 32 amino acid residues of the α-isoform.3,4 Two types of post-translational modifications have been shown to affect cav1, i.e., palmitoylation and phosphorylation, ...
GENERAL AND INORGANIC CHEMISTRY STUDY GUIDE
GENERAL AND INORGANIC CHEMISTRY STUDY GUIDE

... have only been produced artificially as the synthetic products of man-made nuclear reactions. Of the 98 naturally occurring elements, 84 are considered primordial and either stable or metastable (apparently stable but theoretically unstable or radioactive). The remaining 14 naturally occurring eleme ...
Protein kinase A
Protein kinase A

... ADP/ATP ratio is high enough so that ATP-sensitive potassium channels (KATP) are open, and the membrane potential is about 70 mv. Voltage-sensitive calcium channels (VSCC) and calciumsensitive potassium channels (CSKC) are closed. B. Beta cell response to increased blood glucose. Increased entry an ...
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Metalloprotein



Metalloprotein is a generic term for a protein that contains a metal ion cofactor. A large number of all proteins are part of this category.
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