pptx
... the skilled experimentalist to stop at the alkene. This is a particularly good way to generate cis double bonds. Note that the Wittig reaction also gives cis alkenes (usually), but most other olefinations give trans products. Therefore partial reduction from an alkyne can be a useful strategy! ...
... the skilled experimentalist to stop at the alkene. This is a particularly good way to generate cis double bonds. Note that the Wittig reaction also gives cis alkenes (usually), but most other olefinations give trans products. Therefore partial reduction from an alkyne can be a useful strategy! ...
Topic 16 notes - A
... Optical isomers are often found together in a mixture in equal quantities. The opposite effect they have on the rotation of plane polarised light will thus result in no overall rotation. An equimolar mixture of two optical isomers will thus have no effect on plane polarised light and is thus not opt ...
... Optical isomers are often found together in a mixture in equal quantities. The opposite effect they have on the rotation of plane polarised light will thus result in no overall rotation. An equimolar mixture of two optical isomers will thus have no effect on plane polarised light and is thus not opt ...
Honors Chemistry Name Julien Period _____ Date Chapter 17
... Chapter 17 Notes from Basic Chemistry ...
... Chapter 17 Notes from Basic Chemistry ...
CHAPTER 17: Carbonyl group (1)
... 17.8 Acetals as protecting groups Due to interference of functional groups during a reaction we often need to transform them to "unreactive species". This is accomplished using "protecting groups" which should be inert to the subsequent reactions. At the end of the synthetic strategy, these protecti ...
... 17.8 Acetals as protecting groups Due to interference of functional groups during a reaction we often need to transform them to "unreactive species". This is accomplished using "protecting groups" which should be inert to the subsequent reactions. At the end of the synthetic strategy, these protecti ...
Chapter 7: Dienes
... occurs when a diene meets an alkene or alkyne, particularly one with an electron-withdrawing group attached to the C = C results in formation of a new 6-membered ring of C atoms requires the diene to have both bonds in an s-cis configuration occurs spontaneously with the right dienophile ...
... occurs when a diene meets an alkene or alkyne, particularly one with an electron-withdrawing group attached to the C = C results in formation of a new 6-membered ring of C atoms requires the diene to have both bonds in an s-cis configuration occurs spontaneously with the right dienophile ...
Reaction Stoichiometry
... Carbon reacts with steam to produce hydrogen and carbon monoxide. If 2.40 mol of carbon are exposed to 3.10 mol of steam, identify the limiting reactant. How many moles of each product are formed? What mass of each product is formed? ...
... Carbon reacts with steam to produce hydrogen and carbon monoxide. If 2.40 mol of carbon are exposed to 3.10 mol of steam, identify the limiting reactant. How many moles of each product are formed? What mass of each product is formed? ...
IUPAC nomenclature of organic chemistry
... structure. For example, the three isomers of xylene CH3C6H4CH3, commonly the ortho-, meta-, and para- forms, are 1,2-dimethylbenzene, 1,3-dimethylbenzene, and 1,4dimethylbenzene. The cyclic structures can also be treated as functional groups themselves, in which case they take the prefix "cycloalkyl ...
... structure. For example, the three isomers of xylene CH3C6H4CH3, commonly the ortho-, meta-, and para- forms, are 1,2-dimethylbenzene, 1,3-dimethylbenzene, and 1,4dimethylbenzene. The cyclic structures can also be treated as functional groups themselves, in which case they take the prefix "cycloalkyl ...
Chapter 5
... group as the parent alkane and number it from the end that gives the -OH the lower number. 2. Change the ending of the parent alkane from -e to -ol and use a number to show the location of the -OH group; for cyclic alcohols, the carbon bearing the -OH group is carbon1. 3. Name and number substituent ...
... group as the parent alkane and number it from the end that gives the -OH the lower number. 2. Change the ending of the parent alkane from -e to -ol and use a number to show the location of the -OH group; for cyclic alcohols, the carbon bearing the -OH group is carbon1. 3. Name and number substituent ...
TOPIC 7. ELIMINATION REACTIONS (chapter 7 and parts of
... 1. Describe mechanisms for elimination of a leaving group and adjacent proton to form a pi-bond. 2. Discuss the effect of starting material (“substrate”), leaving group, and reaction conditions on the course and outcome of a reaction. 3. Describe syntheses of alkenes and alkynes. 4. Use combinations ...
... 1. Describe mechanisms for elimination of a leaving group and adjacent proton to form a pi-bond. 2. Discuss the effect of starting material (“substrate”), leaving group, and reaction conditions on the course and outcome of a reaction. 3. Describe syntheses of alkenes and alkynes. 4. Use combinations ...
Comparison of homogeneous and heterogeneous catalysis
... of FFA to methyl esters increased with the increase in catalyst amount. With 0.5% H2SO4, the acid value reduced to 11.40 mg KOH/g which further reduced to 6.50 with 1.3% of H2SO4. The acid value of mahua oil was further reduced to 2.07 mg KOH/g with 1.5% (v/v) H2SO4. Further increase in the catalyst ...
... of FFA to methyl esters increased with the increase in catalyst amount. With 0.5% H2SO4, the acid value reduced to 11.40 mg KOH/g which further reduced to 6.50 with 1.3% of H2SO4. The acid value of mahua oil was further reduced to 2.07 mg KOH/g with 1.5% (v/v) H2SO4. Further increase in the catalyst ...
Chapter 7- Alcohols
... There are special reagents which can also be employed e.g. thionyl chloride (SOCl2) or phosphorus tri-bromide (PBr3) O CH3CH2OH + Cl-S-Cl ...
... There are special reagents which can also be employed e.g. thionyl chloride (SOCl2) or phosphorus tri-bromide (PBr3) O CH3CH2OH + Cl-S-Cl ...
Chapter 21 Carboxylic Acid Derivatives
... • Acid chlorides and anhydrides are too reactive to be used with water or alcohol. • Esters, 3 amides, and nitriles are good polar aprotic solvents. • Solvents commonly used in organic reactions: Ethyl acetate Dimethylformamide (DMF) Acetonitrile Chapter 21 ...
... • Acid chlorides and anhydrides are too reactive to be used with water or alcohol. • Esters, 3 amides, and nitriles are good polar aprotic solvents. • Solvents commonly used in organic reactions: Ethyl acetate Dimethylformamide (DMF) Acetonitrile Chapter 21 ...
Fatty Acids and Alcohols Composition of Brazilian Sugarcane Waxes
... cosmetic industries. Sugarcane wax also can be applied in pharmaceutics, due to the presence of long chain aliphatic alcohol (policosanol) that appears to have hypocholesterolemic effect. Waxes extracted from sugarcane filter mud, from sugarcane harvested in 2001 in Sao Paulo, Brazil were analyzed. ...
... cosmetic industries. Sugarcane wax also can be applied in pharmaceutics, due to the presence of long chain aliphatic alcohol (policosanol) that appears to have hypocholesterolemic effect. Waxes extracted from sugarcane filter mud, from sugarcane harvested in 2001 in Sao Paulo, Brazil were analyzed. ...
AMIDES AND AMINES: ORGANIC NITROGEN COMPOUNDS
... Amines are bases while carboxylic acids and phenols are acids. Alcohols and amides are neither acids nor bases. (a) amine, base (b) amide, neither (c) amide, neither (d) carboxylic acid, acid (e) alcohol, neither (f) alcohol, neither ...
... Amines are bases while carboxylic acids and phenols are acids. Alcohols and amides are neither acids nor bases. (a) amine, base (b) amide, neither (c) amide, neither (d) carboxylic acid, acid (e) alcohol, neither (f) alcohol, neither ...
Mechanistic Studies on Alcoholysis of α-Keto esters
... form hydrates and hemiacetals of keto carbonyls in the presence of water and alcohols, respectively.3 In the course of our studies on the solvent effect in photochemistry of phenacyl carboxylates, we had a chance to prepare and work with 2-methylphenacyl phenylglyoxylate (1a), which we found it very ...
... form hydrates and hemiacetals of keto carbonyls in the presence of water and alcohols, respectively.3 In the course of our studies on the solvent effect in photochemistry of phenacyl carboxylates, we had a chance to prepare and work with 2-methylphenacyl phenylglyoxylate (1a), which we found it very ...
Making Scents of Esters
... *Some artificial flavorings can be produced to taste just like natural flavors (ex. oil of wintergreen). Other natural flavorings (such as (chocolate) are such complex mixtures of chemicals that scientists have yet to make an artificial flavor that tastes just like the natural one (ex. chocolate is ...
... *Some artificial flavorings can be produced to taste just like natural flavors (ex. oil of wintergreen). Other natural flavorings (such as (chocolate) are such complex mixtures of chemicals that scientists have yet to make an artificial flavor that tastes just like the natural one (ex. chocolate is ...
Petasis reaction
The Petasis reaction (alternatively called the Petasis borono–Mannich (PBM) reaction) is the chemical reaction of an amine, aldehyde, and vinyl- or aryl-boronic acid to form substituted amines.Reported in 1993 by Nicos Petasis as a practical method towards the synthesis of a geometrically pure antifungal agent, naftifine, the Petasis reaction can be described as a variation of the Mannich reaction. Rather than generating an enolate to form the substituted amine product, in the Petasis reaction, the vinyl group of the organoboronic acid serves as the nucleophile. In comparison to other methods of generating allyl amines, the Petasis reaction tolerates a multifunctional scaffold, with a variety of amines and organoboronic acids as potential starting materials. Additionally, the reaction does not require anhydrous or inert conditions. As a mild, selective synthesis, the Petasis reaction is useful in generating α-amino acids, and is utilized in combinatorial chemistry and drug discovery.