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Second Semester Final Review Guide
Second Semester Final Review Guide

... Energy in Chemical Reactions When a bond breaks, energy is (released / abosorbed). circle one 1. When a bond forms, energy is (released / abosorbed). circle one 2. When more energy is released than absorbed, the reaction is (exothermic / endothermic). circle one 3. When more energy is absorbed than ...
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... Concept 4.1: Organic chemistry is the study of carbon compounds • Organic chemistry is the study of compounds that contain carbon • Organic compounds range from simple molecules to colossal ones • Most organic compounds contain hydrogen atoms in addition to carbon atoms ...
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... Metal alkyls are also typically quite to extremely reactive to molecular O2, water, and a variety of other ligands and reagents. As with hydrides, they play a very important and active role in catalysis. ...
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Hydroformylation



Hydroformylation, also known as oxo synthesis or oxo process, is an important homogeneously catalyzed industrial process for the production of aldehydes from alkenes. This chemical reaction entails the addition of a formyl group (CHO) and a hydrogen atom to a carbon-carbon double bond. This process has undergone continuous growth since its invention in 1938: Production capacity reached 6.6×106 tons in 1995. It is important because the resulting aldehydes are easily converted into many secondary products. For example, the resulting aldehydes are hydrogenated to alcohols that are converted to plasticizers or detergents. Hydroformylation is also used in specialty chemicals, relevant to the organic synthesis of fragrances and natural products. The development of hydroformylation, which originated within the German coal-based industry, is considered one of the premier achievements of 20th-century industrial chemistry.The process typically entails treatment of an alkene with high pressures (between 10 to 100 atmospheres) of carbon monoxide and hydrogen at temperatures between 40 and 200 °C. Transition metal catalysts are required.
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