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Lecture 5
Lecture 5

Chapter 7: Energy and Chemical Change
Chapter 7: Energy and Chemical Change

thermodynamics - La Salle High School
thermodynamics - La Salle High School

... Third Law of Thermodynamics If the entropy of each element in its most state is taken as zero at the absolute zero of temperature, every substance has a positive entropy. But at 0K, the entropy of substance may equals to 0, and does become zero in perfect crystalline solids. Implication: all perfec ...
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1 Lecture: 2 Thermodynamic equilibrium 1
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... constant for a conservative system. If we include all the variables that describe the processes, all systems are conservative. It follows that the energy is always conserved. We consider a system “A” surrounded by the rest of the universe, and we say that the system has a certain amount of energy U ...
Section 1 – Thermal Energy
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... º In your snowball the slower moving particles of your snowball come into contact with the faster moving particles of your hand. º As the particles collide energy is transferred. º One transfers energy to its neighbor and so on. Heat Conductors º Conductors can happen in solids, liquids and gases. º ...
LAW: The first law of thermodynamics states that the total energy in
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... • Explain the utility of enthalpy, flow work, and shaft work • Calculate enthalpy changes associated with sensible heat, latent heat, and chemical ...
LAW: The first law of thermodynamics states that the total energy in
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Thermodynamics

... Enthalpies (heats) of combustion: complete reaction of compounds with oxygen. Measure using a bomb calorimeter. Most chemical reactions used for the production of heat are combustion reactions. The energy released when 1g of material is combusted is its Fuel Value. Since all heats of combustion are ...
Mechanical Engineering
Mechanical Engineering

... from other state functions or properties is also a state function. For example, since U, P and V are state functions, the enthalpy ‘H ‘ defined as below is also a state function. H = Cp T ...
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saulvillalobos.files.wordpress.com
saulvillalobos.files.wordpress.com

Unit 61: Engineering Thermodynamics
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... • Using the specific enthalpy form of the steady flow energy equation (SFEE)… Q – W = (h2 – h1) + (1/2)(V22 –V12)+ g(z2 – z1) We note that g(z2 – z1) = 0 since there is no change in height between the fluid entry and exit (horizontal). Also there is negligible fluid kinetic energy at exit thus (1/2) ...
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Unit 1, Lecture 3 - Massey University
Unit 1, Lecture 3 - Massey University

... A cyclic process is one that starts and ends in the same state This process would not be isolated On a PV diagram, a cyclic process appears as a closed curve The internal energy must be zero since it is a state function V If Eint = 0, Q = W In a cyclic process, the net work done on the system ...
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Notes in pdf format

... Example: Isobaric expansion of water One gram of water is placed in a cylinder, and the pressure is maintained at 2.0 x 105 Pa. The temperature is raised by 31 C. In one case, the water is in the liquid phase and expands by the small amount of 1.0 x 10-8 m3. In another case, the water is in the gas ...
Le Châtelier`s Principle
Le Châtelier`s Principle

... • Make more reactants because more collisions with the products will occur • A stress was applied and the system compensated for this change What will removing CO2 do? • Shift to make more products ...
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... 15-3 Constant Volume and Constant Pressure Processes Let’s consider once again two different thermodynamic processes, one in which heat is added to a system at constant volume, and the other when heat is added at constant pressure. EXPLORATION 15.3A – A constant-volume process A sample of monatomic ...
Ch. 5 --Thermochemistry (I)
Ch. 5 --Thermochemistry (I)

...  Chemical reactions can absorb or release heat.  They also have the ability to do work.  For example, when a gas is produced, the gas can be used to push a piston, doing work.  Zn(s) + 2H+(aq)  Zn2+(aq) + H2(g)  The work performed by the above reaction is called pressure-volume work.  When th ...
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... A thermodynamic system exchange energy with its surroundings by mean of heat and work. When heat is ...
SUMMARY
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... energy. The temperature of an object is related to the average kinetic energy of the molecules making up the object. A measure of temperature tells how hot or cold an object is on two arbitrary scales, the Fahrenheit scale and the Celsius scale. The absolute scale, or Kelvin scale, has the coldest t ...
Γ = Γ ∙ (1)
Γ = Γ ∙ (1)

... Equation (1) can be solved for every temperature that appears on a thermodynamic chart, resulting in a family of lines called moist adiabats. Since the moist adiabatic rate given by (1) is not constant, these lines are curves whose mean slope is much greater at higher temperatures and saturation mix ...
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Heat



In physics, heat is energy in a process of transfer between a system and its surroundings, other than as work or with the transfer of matter. When there is a suitable physical pathway, heat flows from a hotter body to a colder one. The pathway can be direct, as in conduction and radiation, or indirect, as in convective circulation.Because it refers to a process of transfer between two systems, the system of interest, and its surroundings considered as a system, heat is not a state or property of a single system. If heat transfer is slow and continuous, so that the temperature of the system of interest remains well defined, it can sometimes be described by a process function.Kinetic theory explains heat as a macroscopic manifestation of the motions and interactions of microscopic constituents such as molecules and photons.In calorimetry, sensible heat is defined with respect to a specific chosen state variable of the system, such as pressure or volume. Sensible heat transferred into or out of the system under study causes change of temperature while leaving the chosen state variable unchanged. Heat transfer that occurs with the system at constant temperature and that does change that particular state variable is called latent heat with respect to that variable. For infinitesimal changes, the total incremental heat transfer is then the sum of the latent and sensible heat increments. This is a basic paradigm for thermodynamics, and was important in the historical development of the subject.The quantity of energy transferred as heat is a scalar expressed in an energy unit such as the joule (J) (SI), with a sign that is customarily positive when a transfer adds to the energy of a system. It can be measured by calorimetry, or determined by calculations based on other quantities, relying on the first law of thermodynamics.
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