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EE4302 Fl04 Class Sy..
EE4302 Fl04 Class Sy..

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Lecture 11

... the previous chapters, we have studied that an electric charge sets up an electric field that affects other electric charges. Here, we might expect that a magnetic charge sets up a magnetic field that can then affect other magnetic charges. Such a magnetic charge is called a magnetic monopole (a new ...
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Magnetochemistry



Magnetochemistry is concerned with the magnetic properties of chemical compounds. Magnetic properties arise from the spin and orbital angular momentum of the electrons contained in a compound. Compounds are diamagnetic when they contain no unpaired electrons. Molecular compounds that contain one or more unpaired electrons are paramagnetic. The magnitude of the paramagnetism is expressed as an effective magnetic moment, μeff. For first-row transition metals the magnitude of μeff is, to a first approximation, a simple function of the number of unpaired electrons, the spin-only formula. In general, spin-orbit coupling causes μeff to deviate from the spin-only formula. For the heavier transition metals, lanthanides and actinides, spin-orbit coupling cannot be ignored. Exchange interaction can occur in clusters and infinite lattices, resulting in ferromagnetism, antiferromagnetism or ferrimagnetism depending on the relative orientations of the individual spins.
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