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CHEM 490 - Nicholls State University
CHEM 490 - Nicholls State University

ap chemistry chapter 8 bonding
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... 4.1 A student sets up the coordinates for NH3 rather unconventionally, as shown on the right. In this coordinate system, the x-axis is the three-fold axis. One of the σ -planes, σb , makes an angle of 45◦ with the y-axis. By considering the transformation of a general point in space, deduce the six ...
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Jahn–Teller effect



The Jahn–Teller effect, sometimes also known as Jahn–Teller distortion, describes the geometrical distortion of molecules and ions that is associated with certain electron configurations. This electronic effect is named after Hermann Arthur Jahn and Edward Teller, who proved, using group theory, that orbital nonlinear spatially degenerate molecules cannot be stable. The Jahn–Teller theorem essentially states that any nonlinear molecule with a spatially degenerate electronic ground state will undergo a geometrical distortion that removes that degeneracy, because the distortion lowers the overall energy of the species. For a description of another type of geometrical distortion that occurs in crystals with substitutional impurities see article off-center ions.
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