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ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ
ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ ψ

... Consider three non-interacting particles of masses M, 2M and 4M, constrained to lie in a square with sides of length L. How many quantum numbers are there for this system? Separate variables and obtain the eigenfunctions and eigenvalues. What are the degeneracies of the three lowest energy levels? T ...
08_lecture_ppt
08_lecture_ppt

... • Lowest energy state = “ground state” • Higher states = “excited states” • Photon energy equals difference in state energies • Hydrogen atom example – Energy levels – Line spectra ...
08_lecture_ppt - Chemistry at Winthrop University
08_lecture_ppt - Chemistry at Winthrop University

here
here

Bohr Model, Quantum Mechanical Model
Bohr Model, Quantum Mechanical Model

L35 - University of Iowa Physics
L35 - University of Iowa Physics

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Unit 5 Objectives

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Periodic Trends/Patterns
Periodic Trends/Patterns

Exam 3 Review - Iowa State University
Exam 3 Review - Iowa State University

... larger value of the indicated atomic property. a. Ionization energy, Na or Mg b. Ionization energy, Mg or Cl c. Electron affinity, Cl or Br d. Atomic radius, K or Cs e. Atomic radius, Se or Br ...
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... 36. A compound containing sodium is placed in a flame and yellow/orange color is produced. Explain how and why this occurs. 37. Electromagnetic radiation can be discussed in terms of both particles and waves. Explain the experimental verification for each of these views. 38. Summarize the developmen ...
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Chemistry 1311 Problem Set 6 1. CsCl has a simple cubic lattice

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X-ray diffraction techniques X

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X-ray photoelectron spectroscopy



X-ray photoelectron spectroscopy (XPS) is a surface-sensitive quantitative spectroscopic technique that measures the elemental composition at the parts per thousand range, empirical formula, chemical state and electronic state of the elements that exist within a material. XPS spectra are obtained by irradiating a material with a beam of X-rays while simultaneously measuring the kinetic energy and number of electrons that escape from the top 0 to 10 nm of the material being analyzed. XPS requires high vacuum (P ~ 10−8 millibar) or ultra-high vacuum (UHV; P < 10−9 millibar) conditions, although a current area of development is ambient-pressure XPS, in which samples are analyzed at pressures of a few tens of millibar.XPS is a surface chemical analysis technique that can be used to analyze the surface chemistry of a material in its as-received state, or after some treatment, for example: fracturing, cutting or scraping in air or UHV to expose the bulk chemistry, ion beam etching to clean off some or all of the surface contamination (with mild ion etching) or to intentionally expose deeper layers of the sample (with more extensive ion etching) in depth-profiling XPS, exposure to heat to study the changes due to heating, exposure to reactive gases or solutions, exposure to ion beam implant, exposure to ultraviolet light.XPS is also known as ESCA (Electron Spectroscopy for Chemical Analysis), an abbreviation introduced by Kai Siegbahn's research group to emphasize the chemical (rather than merely elemental) information that the technique provides.In principle XPS detects all elements. In practice, using typical laboratory-scale X-ray sources, XPS detects all elements with an atomic number (Z) of 3 (lithium) and above. It cannot easily detect hydrogen (Z = 1) or helium (Z = 2).Detection limits for most of the elements (on a modern instrument) are in the parts per thousand range. Detection limits of parts per million (ppm) are possible, but require special conditions: concentration at top surface or very long collection time (overnight).XPS is routinely used to analyze inorganic compounds, metal alloys, semiconductors, polymers, elements, catalysts, glasses, ceramics, paints, papers, inks, woods, plant parts, make-up, teeth, bones, medical implants, bio-materials, viscous oils, glues, ion-modified materials and many others.XPS is less routinely used to analyze the hydrated forms of some of the above materials by freezing the samples in their hydrated state in an ultra pure environment, and allowing or causing multilayers of ice to sublime away prior to analysis. Such hydrated XPS analysis allows hydrated sample structures, which may be different from vacuum-dehydrated sample structures, to be studied in their more relevant as-used hydrated structure. Many bio-materials such as hydrogels are examples of such samples.
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