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440400 - IDEALS @ Illinois
440400 - IDEALS @ Illinois

Growth Mechanism and Electronic Structure of Zn3P2 on the Ga
Growth Mechanism and Electronic Structure of Zn3P2 on the Ga

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2014 HSC Chemistry Marking Guidelines

Singlet-triplet spin blockade and charge sensing in a few
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Modification of the surface electronic and chemical properties of Pt
Modification of the surface electronic and chemical properties of Pt

... in which the two metals function independently. These phenomena were not considered in this work. Ruban et al. studied the changes in the electronic structure of epitaxial monolayers of one metal on another metal for the late transition metals.7 In that work, the changes in electronic structure were ...
Answers to Selected Exercises
Answers to Selected Exercises

... other. b. When wood burns, most of the solid material in wood is converted to gases, which escape. The gases produced are most likely CO2 and H2O. c. The atom is not an indivisible particle, but is instead composed of other smaller particles—electrons, neutrons, and protons. d. The two hydride sampl ...
Probing charge fluctuator correlations using quantum dot pairs Purohit, er, tt
Probing charge fluctuator correlations using quantum dot pairs Purohit, er, tt

... We study a pair of quantum dot exciton qubits interacting with a number of fluctuating charges that can induce a Stark shift of both exciton transition energies. We do this by solving the optical master equation using a numerical transfer matrix method. We find that the collective influence of the c ...
CP PHysics Ch 21 ppt - Lincoln High School
CP PHysics Ch 21 ppt - Lincoln High School

The Physics of Electron Storage Rings
The Physics of Electron Storage Rings

Temporal interferences driven by a single-cycle terahertz pulse in the... dynamics of negative ions
Temporal interferences driven by a single-cycle terahertz pulse in the... dynamics of negative ions

... the dotted lines in Figs. 1(a) and 1(b). The associated electron waves interfere with each other as a result of the different quantum phases accumulated by the electron moving along these two trajectories. Two examples of the interference pattern are shown in Figs. 1(c) and 1(d), respectively, for t ...
Applications of Supersymmetric Quantum
Applications of Supersymmetric Quantum

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Path Integral Monte Carlo Zachary Wolfson

... of antimatter and opening the door to the field of elementary particle physics.( 5) The same year that Anderson discovered the positron, he predicted that, due to the Coulomb attraction between a positron and electron, the two particles should be able to form a bound state, known as positronium. The ...
Negentropy in Many-Body Quantum Systems
Negentropy in Many-Body Quantum Systems

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4) What is the term for the procedure of collecting data and recording

... percent of copper in the sample? A) 12% B) 29% C) 50% D) 58% E) 75% Stainless steel is composed of iron, manganese, chromium, and nickel. If a 2.00 g sample was analyzed and found to contain 2.75% manganese, what is the mass of manganese in the sample? A) 0.0138 g B) 0.0550 g C) 0.182 g D) 0.727 g E ...
Chemistry 2008 Multiple Choice
Chemistry 2008 Multiple Choice

... Collision theory: reactants collide frequently, with sufficient force and correct orientation. ...
Nitrogen Activation in a Mars–van Krevelen
Nitrogen Activation in a Mars–van Krevelen

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... Average bond enthalpy is the energy required to break one mole of a covalent bond, where all reactants and products are in the gaseous state. It is the average energy used to break that bond in different molecules. The greater the average bond enthalpy, the stronger the bond. Bond enthalpies are use ...
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A family of intracules, a conjecture and the electron correlation... z* Peter M. W. Gill,* Deborah L. Crittenden,w

... that Ec ¼ 0.04667 þ O(Z1) and the correlation energy therefore tends toward a constant as the nuclear charge increases. Thus, for example, although the two electrons in the U901 ion are generally much closer together than those in the Ne81 ion, the resulting correlation energies are almost equal. ...
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Lecture - Rutgers Physics

... Typically, it’s easier to work with the integrals rather than the sums. Thus, whenever we consider an energy range which includes many levels (e.g., when kBT >> inter-level spacing), and, especially, when we are dealing with continuous spectra, we’ll replace the sum over a discrete set of energy lev ...
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... Binary compounds composed of two nonmetals are usually molecular and are named using a prefix system. Common names- water (H2O) and ammonia(NH3) Write the full name of the first element in the formula. Write the name of the second element in the formula with an ide suffix. Use a prefix in front of e ...
Year 11 C2 Mock Exam Revision Questions
Year 11 C2 Mock Exam Revision Questions

lecture slides file
lecture slides file

... color, density, taste/odor, melting/boiling point). Chemical properties describe the ability of the substance to form new substances, either by decomposition or reaction with other substances (corrosiveness, flammability, acidity, toxicity, etc.). No two substances have identical physical and chemic ...
Quantum Energy Teleportation: An Introductory
Quantum Energy Teleportation: An Introductory

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X-ray photoelectron spectroscopy



X-ray photoelectron spectroscopy (XPS) is a surface-sensitive quantitative spectroscopic technique that measures the elemental composition at the parts per thousand range, empirical formula, chemical state and electronic state of the elements that exist within a material. XPS spectra are obtained by irradiating a material with a beam of X-rays while simultaneously measuring the kinetic energy and number of electrons that escape from the top 0 to 10 nm of the material being analyzed. XPS requires high vacuum (P ~ 10−8 millibar) or ultra-high vacuum (UHV; P < 10−9 millibar) conditions, although a current area of development is ambient-pressure XPS, in which samples are analyzed at pressures of a few tens of millibar.XPS is a surface chemical analysis technique that can be used to analyze the surface chemistry of a material in its as-received state, or after some treatment, for example: fracturing, cutting or scraping in air or UHV to expose the bulk chemistry, ion beam etching to clean off some or all of the surface contamination (with mild ion etching) or to intentionally expose deeper layers of the sample (with more extensive ion etching) in depth-profiling XPS, exposure to heat to study the changes due to heating, exposure to reactive gases or solutions, exposure to ion beam implant, exposure to ultraviolet light.XPS is also known as ESCA (Electron Spectroscopy for Chemical Analysis), an abbreviation introduced by Kai Siegbahn's research group to emphasize the chemical (rather than merely elemental) information that the technique provides.In principle XPS detects all elements. In practice, using typical laboratory-scale X-ray sources, XPS detects all elements with an atomic number (Z) of 3 (lithium) and above. It cannot easily detect hydrogen (Z = 1) or helium (Z = 2).Detection limits for most of the elements (on a modern instrument) are in the parts per thousand range. Detection limits of parts per million (ppm) are possible, but require special conditions: concentration at top surface or very long collection time (overnight).XPS is routinely used to analyze inorganic compounds, metal alloys, semiconductors, polymers, elements, catalysts, glasses, ceramics, paints, papers, inks, woods, plant parts, make-up, teeth, bones, medical implants, bio-materials, viscous oils, glues, ion-modified materials and many others.XPS is less routinely used to analyze the hydrated forms of some of the above materials by freezing the samples in their hydrated state in an ultra pure environment, and allowing or causing multilayers of ice to sublime away prior to analysis. Such hydrated XPS analysis allows hydrated sample structures, which may be different from vacuum-dehydrated sample structures, to be studied in their more relevant as-used hydrated structure. Many bio-materials such as hydrogels are examples of such samples.
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