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Chemical Kinetics
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... Reactions are reversible Choose conditions where the reverse has negligible contributions. Study at a point soon after they are mixed before product builds up. Reaction rate will depend only on concentration of the reactants. ...
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... when treated with sodium bromide afforded corresponding bromide that exhibited doublet at ı 6.61 (J = 12.4 Hz) indicating the presence of double bond [33] and upfield shift in the signal of saturated methylene protons containing alcoholic group. Monohalogenation of diols [34] is often a stubborn prob ...
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... • The entropy starts of with a low value (ordered) and leads to a higher value (disordered) • This means that reactants and products will have an entropy content, S • We are interested in the change in entropy of a chemical system. • This gives us an idea as to whether a reaction is feasible / spont ...
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Chemical equilibrium



In a chemical reaction, chemical equilibrium is the state in which both reactants and products are present in concentrations which have no further tendency to change with time. Usually, this state results when the forward reaction proceeds at the same rate as the reverse reaction. The reaction rates of the forward and backward reactions are generally not zero, but equal. Thus, there are no net changes in the concentrations of the reactant(s) and product(s). Such a state is known as dynamic equilibrium.
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