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Chapters_38-39
Chapters_38-39

... them with enough energy—that is, if you use a light source that is bright enough. That is not what happens. For light below the cutoff frequency f0, the photoelectric effect does not occur, no matter how bright the light source. The existence of a cutoff frequency is, however, just what we should ex ...
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... also clear differences between the measured and simulated results. First, the measured distribution shows a clear asym­ metry about zero momentum even though the expectation value � p x � �0 at all delays. Second, in the measured distri­ bution, the times at which the wave packet has the largest pro ...
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... It occurs when an atom or a molecule and their concomitant ions have energy states whereby the energy in two or more photons is absorbed. Negative ion chemical ionization See chemical ionization. Penning ionization Ionization occurs through the interaction of two or more neutral gaseous species, at ...
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... for spherical systems, atoms [19] and metallic clusters [20]. Because the independent-particle response function χ 0 defined by Eq. (13) is a scalar integral kernel for spherical systems, Eq. (12) for δ n(r ) is separated for each multipole component. The equation in each multipole is an integral eq ...
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Imaging and Tuning Molecular Levels at the Surface of a Gated

... and annihilation operators. We will neglect the dependence on electron wavevector k , as well as phonon wavevector q . This is based on the observation that the electron and phonon bandwidths are both relatively small. We have also checked that the electron-phonon matrix elements do not change appre ...
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Atomic orbital



An atomic orbital is a mathematical function that describes the wave-like behavior of either one electron or a pair of electrons in an atom. This function can be used to calculate the probability of finding any electron of an atom in any specific region around the atom's nucleus. The term may also refer to the physical region or space where the electron can be calculated to be present, as defined by the particular mathematical form of the orbital.Each orbital in an atom is characterized by a unique set of values of the three quantum numbers n, ℓ, and m, which respectively correspond to the electron's energy, angular momentum, and an angular momentum vector component (the magnetic quantum number). Any orbital can be occupied by a maximum of two electrons, each with its own spin quantum number. The simple names s orbital, p orbital, d orbital and f orbital refer to orbitals with angular momentum quantum number ℓ = 0, 1, 2 and 3 respectively. These names, together with the value of n, are used to describe the electron configurations of atoms. They are derived from the description by early spectroscopists of certain series of alkali metal spectroscopic lines as sharp, principal, diffuse, and fundamental. Orbitals for ℓ > 3 continue alphabetically, omitting j (g, h, i, k, …).Atomic orbitals are the basic building blocks of the atomic orbital model (alternatively known as the electron cloud or wave mechanics model), a modern framework for visualizing the submicroscopic behavior of electrons in matter. In this model the electron cloud of a multi-electron atom may be seen as being built up (in approximation) in an electron configuration that is a product of simpler hydrogen-like atomic orbitals. The repeating periodicity of the blocks of 2, 6, 10, and 14 elements within sections of the periodic table arises naturally from the total number of electrons that occupy a complete set of s, p, d and f atomic orbitals, respectively.
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