Download Alcohols from Alkenes: Oxymercuration–Demercuration

Alcohols from Alkenes: Oxymercuration–Demercuration
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Alcohols from Alkenes: Oxymercuration–Demercuration
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Mechanism of Oxymercuration–Demercuration
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Mechanism of Oxymercuration–Demercuration
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Alcohols from Alkenes: Hydroboration–Oxidation
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Syn Addition
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Alcohols from Alkenes: Hydroboration–Oxidation
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Syn Addition
Herbert C. Brown discovered (1956)
hydroboration which led to his being
named a co-winner of the 1979 Nobel
Prize in Chemistry
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Alcohols from Alkenes: Hydroboration–Oxidation
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Orbital View for Hydroboration
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Oxidation and Hydrolysis of Alkylboranes
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Repeat sequence
twice
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Regio- and Stereochemistry of Hydroboration and Oxidation
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Addition of Bromine to Alkenes
Addition of Bromine to Alkenes: Mechanism
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Stereospecific Reactions
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Reaction 1
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Reaction 2
A reaction is stereospecific when a particular stereoisomeric
form of the starting material reacts in such a way that it gives a
specific stereoisomeric form of the product.