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CH 115 Fall 2014 Worksheet 14 1. Draw the Lewis structures for the following organic molecules. a). CH3NH2 b). CH3CN c). CH3COOH 2. What is the general formula for a hydrocarbon that has no double bonds? What is this type of hydrocarbon called? CnH2n+2; alkane 3. List the rules for naming a hydrocarbon. 1. Find the longest continuous chain of carbons – designate this as your parent chain. Use the alkane naming system (methane, ethane, propane, butane, etc) to name this chain depending on how many carbons it has. 2. Locate any substituents that branch off from the main parent chain and name them (same as above but replace “ane” ending with “yl” ending, e.g. methane methyl, etc.) 3. Number the substituents so that that each branch has the lowest number possible. 4. Write the name! Remember commas in between numbers and dashes in between numbers and letters. Substituents named in alphabetical order! 4. Name/draw the following hydrocarbons. a). CH 3 CH3 H3 C CH3 CH3 4-ethyl-3,6-dimethylnonane b). 5,6,7-triethyl-4-methylnonane c). 2,3,4,5-tetramethylhexane d). 3-ethyl-2-methylpentane CH 115 Fall 2014 Worksheet 14 e). CH 3 CH 3 CH 3 H3 C H3 C 3-methyl-4-dipropyloctane 5. Arrange the following in order of decreasing length (from longest to shortest): Double bond, single bond, triple bond Single, double, triple 6. What is a dipole moment? What periodic trend determines whether or not a bond will have a dipole moment or polarity? Dipole moment occurs due to unequal sharing of electrons in a covalent bond. One element (the more electronegative one) pulls more electron density towards itself and becomes partially negative, leaving the other element in the bond partially positive. Electronegativity or a difference in electronegativity between the two atoms in the bond will cause a dipole moment. When a dipole moment exists, the bond is classified as polar.