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Name:______________________________________________ Date:_________________ Class Period: _____ Chemistry Final 2013 – Semester 1 Review Guide I. CLASSIFICATION OF MATTER 1. Define the following: a. Elements: ___________________________________________________________ b. Compound: _________________________________________________________________ c. Mixture: _____________________________________________________________________ 2. What is the difference between homogeneous and heterogeneous mixtures? 3. Identify the following as an element (e), compound (c), or mixture (m): Substance E, C or M As NaCl Sand + Water S Air 4. State the Law of Conservation of Matter: 5. State the Law of Definite Proportions: 6. Which of the following indicate a chemical change: (a) Fizzing (c) Color change (b) Burning (d) All of the above 7. Which of the following are physical changes: (a) State of changes (solid, liquid, gas) (c) Cracking open an egg (b) Dissolving (d) All of the above 8. If 30g of KCl are added to 136g of water the resulting mass is _______. II. LABORATORY SAFETY 1. When should long hair be tied back? 2. When chemicals are spilled what should you do? III. NUMBERS IN CHEMISTRY 1. Answer the following calculations to the correct number of significant figures: a. 3.0 x 2.30 = ____________________________ What’s the rule? _________________ b. 2.3 + 3.44 = ____________________________ What’s the rule? _________________ c. 3.44 x 2.0 + 3.9 ____________________________ 2. 3. 4. Convert the following into scientific notation: a. 0.0035 ____________________________ b. 43,025 ____________________________ c. 1 ____________________________ d. 0.01 ____________________________ Express the following in standard (regular) notation: a. 3.6 x 104 ____________________________ b. 4.9 x 10 - 2 ____________________________ How many significant figures do the following numbers have? a. 0.00321 ____________________________ b. 320001 ____________________________ c. 1.0000 ____________________________ d. .00210 ____________________________ 5. There are 60 seconds per minute, 60 minutes per hour, 24 hours per day and 365 days per year. How many seconds are in a 3 years? 6. If 3.784 liters = 1 gallon, how many liters are in 4 gallons? 7. A field goal kicker who makes 20/21 field goals through the center of the uprights has: 8. What is the formula for density? What is the unit for density? (Draw the density triangle) (a) poor accuracy but good precision (b) good accuracy and good precision (c) poor accuracy and poor precision (d) good accuracy and poor precision 2 9. An unknown metal has the mass of 2.5g and a volume of 0.48mL. What is its density? 10. If the density of a substance is 25g/mL, what is the volume occupied by 300g of the substance? 11. Define qualitative and quantitative measurements. Give an example of each. a. Quantitative measurement:____________________________________________________ b. Qualitative measurement:________________________________________________ 12. What would be the best metric unit for measuring the diameter of a dime? ________________________________________________________________________________ IV. ATOMIC STRUCTURE 1. What was the contribution to chemistry by each of these individuals? a. Neils Bohr ___________________________________________________________________ b. Henry Moseley _______________________________________________________________ c. Rutherford ___________________________________________________________________ d. JJ Thomson __________________________________________________________________ e. Schrodinger __________________________________________________________________ f. Democritous __________________________________________________________________ g. Dalton _______________________________________________________________________ h. Chadwick _____________________________________________________________________ i. De Broglie ____________________________________________________________________ j. Millikan ______________________________________________________________________ 2. An atomic number is the same as the number of: 3. An atom is defined as the smallest part of an element that: (a) (b) (c) (d) (a) (b) (c) (d) Neutrons Electrons Alpha particles Protons Has protons, neutrons, and electrons Has protons and neutrons Retains the chemical identity of that element Can form an ion 3 4. The atomic number (# of protons) and mass of chlorine are? 5. The neutrons of an atom are found: 6. Which subatomic particle has the smallest mass? 7. The number of protons always equals the number of __________ in a neutral atom. 8. The mass number of an element tells you the # of __________ and __________ 9. Who is credited with discovering: 10. Isotopes have the same number of __________ but different numbers of __________ and different atomic __________. (a) (b) (c) (d) (a) (b) (c) (d) (a) (b) (c) (d) 17, 35 33, 75 16, 32 29, 64 In the nucleus Orbiting the nucleus In the s block In the orbitals Protons Neutrons Electrons Ions a. The nucleus? _______________________ b. The electron? _______________________ c. The Planetary Model of the Atom? _________________________ V. PERIODIC TABLE AND PERIODIC TRENDS 1. Define these terms AND draw arrows to represent how these trends increase across the period and within each group: a. Atomic Radius: b. Ionization Energy: c. Electronegativity: 2. Where can you locate the metals, non-metals, metalloids, alkali metals, alkaline earth metals, transition metals, halogens and noble gases on the periodic table? (HINT: Draw a diagram to help!) 4 VI. IONIC AND COVALENT BONDING 1. Naming Ionic Compounds a. NH4Cl __________________________________________________ b. Fe(NO3)3 __________________________________________________ c. Cu3P __________________________________________________ d. Al(CN)3 __________________________________________________ e. Pb(SO4)2 __________________________________________________ 2. Formula of Ionic Compounds a. lead (II) nitride __________________________________________________ b. silver bromide __________________________________________________ c. chromium (VI) phosphate __________________________________________________ d. vanadium (V) sulfide __________________________________________________ e. potassium bicarbonate __________________________________________________ 3. Naming Covalent Compounds a. IO2 __________________________________________________ b. C2Br6 __________________________________________________ c. BBr3 __________________________________________________ d. N2O3 __________________________________________________ 4. Formula of Covalent Compounds a. tetraphosphorus triselenide __________________________________________________ b. disilicon hexabromide __________________________________________________ c. diselenium diiodide __________________________________________________ d. tetrasulfur dinitride __________________________________________________ 5. Naming Gases a. What are the seven diatomic molecules (names and formulas)? 5 VII. CHEMICAL REACTIONS 1. Provide a description and pattern for each type of chemical reaction. a. Combustion Reaction b. Synthesis Reaction c. Decomposition Reaction d. Single Replacement Reaction e. Double Replacement Reaction 2. Identify the type of chemical reaction using the following chemical equations. BALANCE. a. ____ Mg + ____ Fe2O3 ____ Fe + ____ MgO Type of Reaction: ________________ b. ____ C2H4 + ____ O2 ____ CO2 + ____ H2O Type of Reaction: ________________ c. ____ PbSO4 ____ PbSO3 + ____ O2 Type of Reaction: ________________ d. ____ H2O + ____ SO3 ____ H2SO4 Type of Reaction: ________________ e. ____ H2SO4 + ____ NH4OH ____ H2O + ____ (NH4)2SO4 Type of Reaction: ________________ VIII. PREDICTING PRODUCTS AND CHEMICAL REACTIONS 1. Identify the type of reaction, predict the products and write a balanced chemical equation. a. __Na + __Cl2 ___ __________________ Type of Reaction: __________________ b. ___KI ___ _______________ + ___ ___________________ Type of Reaction: __________________ c. ___Zn + ___Cu2(SO4)3 ___ ________________ + ___ ____________________ Type of Reaction: __________________ 6 d. ___NaOH + ___H2SO4 ___ _______________ + ___ ___________________ Type of Reaction: __________________ e. ___C2H6 + ___O2 ___ ______________ + ___ _____________ Type of Reaction: __________________ 2. Definitions a. Chemical Reaction _____________________________________________________________________________ b. Balanced Chemical Equation _____________________________________________________________________________ 3. What is always equal on each side of the arrow in a balanced chemical equation? 4. How many atoms are represented in the formula for Cr(CO3)3? 5. Where are reactants and products found in a chemical equation? IX. PERCENT COMPOSITION (PERCENT BY MASS): 1. What is the equation for percent by mass? 2. What is the percent by mass of each element in CuSO4? 3. What is the percent by mass of each element in H3PO4? 7 X. GENERAL REVIEW 1. Convert the following metric units: (K H D B d c m) a. 1L = ___________________ mL b. 100cm = ___________________ m c. 2735cg = ___________________ g d. 0.25 KL = ___________________ mL e. 3.25 g = ___________________ Hg 2. Which SI unit is used to measure: a. Mass? ___________________ b. Volume? ___________________ c. Length? ___________________ d. Temperature? ___________________ 3. In normal processes can total energy be created or destroyed? 4. Label physical or chemical change for the following: a. A change in color ___________________ b. Phase change ___________________ c. Formation of a new substance ___________________ d. Change in density ___________________ 5. Circle ALL the chemical changes below: a. Burning paper b. Melting Ice c. C6H12O6 + H2O C6H12O6 + H2O d. Ca + H2O CaO + H2 6. Identify the following as an element, compound, or mixture. a. ______________ b._______________ 8 c.______________ d.________________ XI. SEPARATION TECHNIQUES 1. Identify the separation technique used in the following: a. A process used to separate sand and water ______________________________________________________________________ b. An electrical process that can separate water into hydrogen and oxygen gas ______________________________________________________________________ c. Boiling a chemical and then condensing its vapors ______________________________________________________________________ d. A solution is left sitting on the counter. After several days only a solid remains in the container _______________________________________________________________________ 2. Describe the separation technique that could be used to separate each of the following mixtures: a. Two colorless liquids _______________________________________________________________________ b. Colored dye or ink _______________________________________________________________________ c. A non- dissolving solid mixed with a liquid _______________________________________________________________________ XII. ATOMIC STRUCTURE 1. How do you write a complete chemical symbol for an atom? DRAW A DIAGRAM. 2. If an atom has 14 protons, 15 neutrons and, 14 electrons; its complete chemical symbol would be: 3. If an atom has 8 protons, 8 neutrons, and 10 electrons, its complete chemical symbol would be: 4. If an atom has 13 protons, 14 neutrons, and 10 electrons, its complete chemical symbol would be: 5. If an atom has 11 protons, 12 neutrons, and 10 electrons, its complete chemical symbol would be: 9 6. What is the electron configuration (1s22s2, etc.) for the following atoms: Long Hand Noble Gas Conf. a. Co ________________________________ ________________________ b. N ________________________________ ________________________ c. Al ________________________________ ________________________ d. Ca ________________________________ ________________________ e. S ________________________________ ________________________ f. ________________________________ ________________________ Ar 7. What is the orbital diagram for the following atoms: a. Fe b. O c. N d. S e. Be 10