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Purdue Rare Isotope Measurement Laboratory (PRIME Lab) • • Purdue University is home of the only university-based accelerator-mass-spectrometry (AMS) multi-isotope facility in the United States PRIME Lab has facilities support from the NSF geosciences program and facilities upgrade funds from NASA Measurements performed at PRIME Lab enable Purdue research endeavors and research activities from numerous research groups outside Purdue University 28-Apr-17 Phys217/Phys217H PrimeLabTour 1 What is Accelerator Mass Spectrometry • One of the main uses is Geologic dating • Use elements that decay radioactively as clocks to measure elapsed time and hence the age of an object • Measure concentrations of specific radioactive element to a precision of a few times 10-15. This is like finding a few grains of sand in a Ross Ade stadium full of sand • This means the sample size can be very tiny and not destructive of the original object e.g. shroud of Turin • We need to know when the clock started and that it has measured time without variation 28-Apr-17 Phys217/Phys217H PrimeLabTour 2 Radioactive decay 28-Apr-17 Phys217/Phys217H PrimeLabTour 3 Age of the earth The best age for the Earth comes not from dating individual rocks but by considering the Earth and meteorites as part of the same evolving system in which the isotopic composition of lead, specifically the ratio of lead-207 to lead-206 changes over time owing to the decay of radioactive uranium-235 and uranium-238, respectively. These calculations result in an age for the Earth and meteorites, and hence the Solar System, of 4.54 billion years with an uncertainty of less than 1 percent. To be precise, this age represents the last time that lead isotopes were homogeneous throughout the inner Solar System and the time that lead and uranium was incorporated into the solid bodies of the Solar System. The age of 4.54 billion years found for the Solar System and Earth is consistent with current calculations of 11 to 13 billion years for the age of the Milky Way Galaxy (based on the stage of evolution of globular cluster stars) and the age of 14 billion years for the age of the Universe (based on the recession of distant galaxies and analysis of the Cosmic Microwave background). 28-Apr-17 Phys217/Phys217H PrimeLabTour 4 Age of our galaxy Rhenium-187 (187Re), an element similar in mass to gold, was produced in the first stellar explosions after the birth of our galaxy. 187Re betadecays into osmium-187 (187Os) with a half-life of 41 billion years— slowly enough so that the relative abundance of 187Re to 187Os provides a good measure of the time that has elapsed since our galaxy first formed. However, additional nuclear processes, other than the decay of 187Re, change the abundance of 187Os, which can cause error in the rheniumosmium clock. Accelerators were used to precisely determine the neutron-capture cross sections of 187Os and its adjacent osmium isotopes, 186Os and 188Os, which then allows for an accurate subtraction of this direct contribution. 28-Apr-17 Phys217/Phys217H PrimeLabTour 5 Carbon 14 dating Carbon 14 is a radioactive form of carbon which is continually being produced by the interaction of cosmic rays in the atmosphere. The chemistry of C14 is the same as that of stable C12. We ingest C14 by breathing and eating so at the time we die we have a fixed ratio of C14/C12 . The C14 then decays with a half life of 5730 years. So measuring this ratio at a later time detemines the age at which the living organism died. One C14 atom exists in nature for every 1,000,000,000,000 C12 atoms in living material. Accuracy of ±0.4% or ±35 years using a 0.5-milligramsample 28-Apr-17 Phys217/Phys217H PrimeLabTour 6 Analyzing the surface of rocks When cosmic rays hit rock surfaces they produce very small amounts of trace elements called cosmogenic nuclei. The amount of the elements depend on the length of exposure. This technique can be used to measure the age of meteorite impacts, volcanic eruptions and movement of glaciers since the rocks now on the surface were first exposed when the event happened. Have to worry about the climate, weathering etc. 28-Apr-17 Phys217/Phys217H PrimeLabTour 7 Galactic Cosmic Rays 28-Apr-17 Phys217/Phys217H PrimeLabTour 8 Radionuclides measured routinely 28-Apr-17 Detection Natural limit (10- level (1015) 15) Radionuclide Half-life (years) 10Be 1,600,000 3 14C 5,730 2 26Al 730,000 5 36Cl 300,000 1 500 41Ca 100,000 1000 10 129I 16,000,00 0 20 1000 Phys217/Phys217H PrimeLabTour 1200 9 Sample Age in Years Cloth wrappings from a mummified bull. [Samples taken from a pyramid in Dashur, Egypt. This date agrees with the age of the pyramid as estimated from historical records.] 2,050 Charcoal. [Sample, recovered from bed of ash near Crater Lake, Oregon, is from a tree burned in the violent eruption of Mount Mazama which created Crater Lake. This eruption blanketed several States with ash, providing geologists with an excellent time zone.] 6,640 Charcoal. [Sample collected from the “Marmes Man” site in southeastern Washington. This rock shelter is believed toe among the oldest known inhabited sites in North America.] 10,130 Spruce Wood. [Sample from the Two Creeks forest bed near Milwaukee, Wisconsin, dates one of the last advances of the continental ice sheet into the United States.] 11,640 Bishop Tuff. [Samples collected from volcanic ash and pumice that overlie glacial debris in Owens Valley, California. This volcanic episode provides an important reference datum in the glacial history of North America.] 700,000 Volcanic ash. [Samples collected from strata in Olduvai Gorge, East Africa, which sandwich the fossil remains of Zinjanthropus and Homo habilis<possible precursors of modem man.] 1,750,000 Monzonite. [Samples of copper-bearing rock from vast open-pit mine at Bingham Canyon, Utah.] 37,500,000 Quartz monzonite. [Samples collected from Half Dome, Yosemite National Park, California.] 80,000,000 Conway Granite. [Samples collected from Redstone Quarry in the White Mountains of New Hampshire.] 180,000,000 Rhyolite. [Samples collected from Mount Rogers, the highest point in Virginia.] 820,000,000 Pikes Peak Granite. [Samples collected on top of Pikes Peak, Colorado.] 1,030,000,000 Gneiss. [Samples from outcrops in the Karelian area of eastern Finland are believed to represent the oldest rocks in the Baltic Region.] 2,700,000,000 The Old Granite. [Samples from outcrops in the Transvaal, South Africa. These rocks intrude even older rocks that have not been dated.] 3,200,000,000 Morton Gneiss. [Samples from outcrops in southwestern Minnesota are believed to represent some of the oldest rocks in North America.] 3,600,000,000 28-Apr-17 Phys217/Phys217H PrimeLabTour 10 Requirements for Dating There are several critical elements to determine the date at which a particular event occurred Reliable clock --- Use radioactive decay Knowing when the clock started Death of a living organism First exposure to cosmic rays calibration compare to a known standard sample precise and reproducible measurements measure ratios e.g. 12C/14C control of machine parameters statistically significant number of ions 28-Apr-17 Phys217/Phys217H PrimeLabTour 11 Timeline on earth 28-Apr-17 Phys217/Phys217H PrimeLabTour 12 How is it done We cannot manipulate neutral atoms. The only tools we can use are electric and magnetic fields. Electric fields accelerate charged particles and magnetic fields bend particles and act like prisms and lenses for light qEd = 1/2mv2 qvB = mv2/r E v2 = 2Edq/m v = Brq/m So if we use electric and magnetic fields We can select atoms with the same q/m Use energy loss in a gas which depends on q2 to separate the ionized atoms with the same q/m 28-Apr-17 Phys217/Phys217H PrimeLabTour 13 Accelerator mass spectrometry Add negative charge to the atoms AMS allows the counting of individual atoms of a radionuclide rather than the decay 28-Apr-17 Phys217/Phys217H PrimeLabTour 14 Accelerator Components The ion source Hot cesium ions are used to produce negative ions with q = -1 from a few milligrams of solid material such as a rock or meteorite. which are accelerated down an evacuated beam line. The injector magnet This magnet bends the ions by 90 degrees and is tuned to select the element of interest. The accelerator The accelerator is a large tank containing the beam vacuum tubes and CO2 and N2 insulating gas at 10 atmospheres.The center of the tank is at a positive voltage of up to 10 million volts. 28-Apr-17 Phys217/Phys217H PrimeLabTour 15 Accelerator components The stripper At the center of the tank the ions pass through a foil which strips electrons from the negative ions and the ions become positively charged and are accelerated again by the 10 million volt potential. The ions have a distribution of charges and They choose the most populous charge state Carbon +3 Beryllium +3 Aluminum +7 Chlorine +7 The analyzing magnets These select the radionuclide of interest and further reduce the intensity of the wrong elements. The electrostatic analyser This uses electric fields to select ions with the correct energy and remove background. The gas ionization chamber Counts ions one at a time by measuring the energy deposited in propane gas which determines the nuclear charge. 28-Apr-17 Phys217/Phys217H PrimeLabTour 16 Possible Backgrounds ISOTOPES ISOBARS MOLECULES same q different m different q same m could have same q/m The measurement of a particular element requires a detailed knowledge of both the element and possible backgrounds and the incorporation of many different techniques to reduce or eliminate the background. 28-Apr-17 Phys217/Phys217H PrimeLabTour 17 Research Topics 14C dating death of living organisms. 10Be, 26Al, 36Cl in rocks chronologies of glaciations, volcanic eruptions and impact craters. Also erosion rates and burial histories of sediments. 36Cl, 129I Release of radioactivity into the environment 36Cl Tracing groundwater movements 10Be, 26Al, 36Cl meteorites, exposure history, terrestrial residence times. Use for measuring biological tracers e.g Calcium for osteoporosis 28-Apr-17 Phys217/Phys217H PrimeLabTour 18 28-Apr-17 Phys217/Phys217H PrimeLabTour 19 Surface exposure dating Meteor Crater in Arizona Typical glaciated surface 28-Apr-17 Phys217/Phys217H PrimeLabTour 20 Glacial chronology has been redefined around the world. 28-Apr-17 Phys217/Phys217H PrimeLabTour 21 Dating terraces above the goosenecks of the San Juan River River gravels 28-Apr-17 Phys217/Phys217H PrimeLabTour 22 GENESIS Our Sun belongs to the generation of stars created 4.6 billion years ago, when our galaxy was roughly half its present age. A cloud of interstellar gas, dust, and ices containing several generations of material collapsed to form the nebula from which the Sun and the rest of the solar system grew. This collapse may have been triggered by a nearby supernova. The conservation of angular momentum confined some of the material to a flat, spinning disk around the young Sun. As time went on, the grains and ices in that disk bumped into and stuck to one another. As they grew larger, their gravitational forces increased, attracting more matter from the disk and gradually building up kilometer-sized bodies called planetesimals, some of which in turn formed the nuclei of the planets as we know them today. Other planetesimals either became comets or asteroids. About 4.6 billion years ago, the solar nebula transformed into the present solar system. Fortunately for us the average isotopic and elemental composition of the solar system of 4.6 billion years ago, is largely preserved in the surface layers of the Sun. The Sun contains most of the mass of the original nebula, and while nuclear reaction has modified the composition at the core, the surface layers which do not mix with the core have preserved the original nebula composition. NASA’s Genesis sample-return mission 1 is designed to give us just such a baseline composition 2. It has collected solar wind, material which is ejected fromthe outer portion of the sun, and returned it to Earth. This material can be thought of as a fossil of our nebula because the preponderance of scientific evidence suggests that the outer layer of our sun has not changed measurably for billions of years. Moreover, for most rock-forming elements, there appears to be little fractionation of either elements or isotopes between the sun and the solar system http://genesismission.jpl.nasa.gov/ 28-Apr-17 Phys217/Phys217H PrimeLabTour 23