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Chapter 4: Carbon and Molecular Diversity: KEY Vocabulary and Study Questions 1) List the six major elements that are components of organic molecules. C, H, N, O, P, S 2)What is tetravalence? Carbon has 4 valence electrons b) What effect does it have on carbon? Each C atom can act as an intersection point from which a molecule can branch off in up to 4 directions 3)Even though it is easier to write out or draw molecules as two-dimensional or flat structures, in reality they are three-dimensional. Why is this important? The shape of a molecule often determines its function. 4)Why is CO2 considered inorganic? it lacks hydrogen 5)What are two characteristics of hydrocarbons? 1) hydrophobic 2) can undergo reactions that release a large amount of energy 6)Define the following terms: organic chemistry: branch of chemistry that specializes in the study of Carbon hydrocarbon: organic molecules consisting of only Carbon & Hydrogen isomer: variations in the architecture of organic molecules o structural isomer: differs in the covalent arrangement of atoms (ex: linear or branched skeleton) o geometric isomer: same covalent partnerships, but differ in spatial arrangement o enantiomer: molecules that are mirror images of each other functional group: components of organic molecules that are most commonly involved in chemical reactions 7)List a biological consequence or use for a) geometric isomers: light induces a change in rhodopsin from a cis isomer to a trans isomer and b) enantiomers: pharmaceuticals- two enantiomers may not be equally effective (L-dopa vs D-dopa drug for Parkinsons & thalidomide) 8) Covalent bonds link carbon atoms together in long chains that form the skeletal framework for organic molecules. These carbon skeletons vary from one another in four ways. List these below. length branched or unbranched may have double bonds (vary in location) may be arranged in rings 9) Complete the following table for the six major functional groups of organic molecules. Functional Molecula Polar or soluble Names and Characteristics examples Group r nonpola in of Organic Compounds with Formula r water this Functional Group ? Alcohols (~ol) (water molecules attracted to Hydroxyl ~OH Polar Yes ~OH which helps dissolve ethanol organic compounds (ex: sugars) Carbonyl Carboxyl *** Amino *** ~CO (~C==O) ~COOH ~NH2 Sulfhydryl ~SH Phosphate *** ~PO4- Polar Polar Polar Polar Polar Aldehyde Propanol Ketone (have different properties due to location of C=O bond) acetone Formic acid Yes Carboxylic acids (source of H+; covalent bond very polar due to 2 O atoms that the H+ dissociates [sour taste; sting]) Glycine Yes Amines (acts as a base; picks up an H+ from surrounding solution most common state in a cell ~NH3) Thiols (help stabilize intricate structure of many proteins ethanethiol Phosphate groups (transfer energy between prganic molecules so a cell can perform work Glycerol phosphate Yes Yes Yes Acetic acid Contrac-tion of muscle cell