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Experiments about Discharge in Water with Changing Conductivity and Applied Voltages Masatoshi Fue, Ogata Ryoma, Takuma Oikawa, Masahiro Akiyama Electrical Engineering University of Iwate Japan Abstract—Discharge plasma generated by pulsed high voltage applied to water is used in industry for such purposes as improving water quality. High voltages have been considered necessary for discharge plasma in water. However, discharge plasma in water was here generated using a low applied voltage of 3 kV by capacitor discharge circuit. This report discusses two experimental methods: one using an MPC (Magnetic Pulse Compression) [1] circuit, the other using a capacitor discharge circuit. In these experiments, parameters are conductivity of water and applied voltage. From these experiments, waveforms were measured and pictures of the discharge plasma were taken. 110 and 3000 μS/cm to analyze plasma formation with voltage waveforms. We took pictures of discharge plasma using a single-lens reflex camera and a high speed camera. Keywords—Plasma; Discharge in water; Pulsed power; Capacitor; Conductivity; MPC circuit I. INTRODUCTION Applying a high voltage pulse to an electrode in water generates a discharge plasma with streamers around the electrode tip [1]. Many researchers have studied discharge in water [2,3]. While discharges have multiple industrial applications, such as improving water quality [4,5], some aspects of the water discharge mechanism remain unclear. Typically, water discharges are generated by a pulsed high voltage. For example, discharge plasma in water by a magnetic pulse compression (MPC) circuit is generated at the applied voltages greater than approximately 15 kV, while applied voltages under 15 kV seem unable to generate discharge plasma. In this manuscript, we generate discharge plasma in water at approximately 3 kV using a capacitor discharge circuit. We show experimental results as a function of conductivity and applied voltage using an MPC circuit and a capacitor discharge circuit. II. EXPERIMENTAL SETUPS Fig. 1 shows the experiment setup. Discharge plasma is generated by either an MPC circuit or capacitor discharge circuit. resulting in discharge plasma in water generated around a 0.8 mm diameter copper electrode tip. Discharge voltage waveforms were measured by a high voltage probe (Tektronix Model P6015A). Conductivity was varied between Fig. 1. Experimental setup. III. EXPERIMENTAL RESULTS BY MPC MPC circuits are a common pulsed power generator. In our experiment, voltage waveforms were measured under varopis conductivity and applied voltage. Images of discharge plasma formation were taken by a single-lens reflex camera. A. Varied conductivity under the MPC circuit Discharge plasma was generated by an MPC circuit and measured under reactor water with conductivity between 110 μS/cm and 1500 μS/cm. The applied voltage was 30 kV. Fig. 2 shows voltage waveforms, and Fig. 3 shows discharge plasma formations at three conductivity states (a) 110 μS/cm, (b) 500 μS/cm, and (c) 1500 μS/cm. Discharge plasma formations changed depending on conductivity. Increasing conductivity reduced discharge plasma streamer length while incrasing plasma brightness. (a) 35 30 25 Voltage (kV) (b) 110 μS/cm 20 Fig. 5. The formations of discharge plasma of each applied voltage. (a) 30 kV, (b) 15 kV 500 μS/cm 15 10 1500 μS/cm 5 0 IV. -5 -10 -15 The capacitor discharge circuit used in our experiment was unable to generate as high a voltage as that generated by the MPC circuit, with a maximum applied voltage of about 5 kV. An applied voltage of 5 kV was insufficient to generate discharge plasma under an MPC circuit, while it was possible at that voltage using the capacitor discharge circuit. Fig. 6 shows the capacitor discharge circuit used in our experiment. The capacitance was 0.56 μS/cm. V0 was a DC power supply variable between 0 kV and 5 kV. The switch was a gap switch which determined applied voltage by gap distance. The load in this experiment was the reactor. time (μs) Fig. 2. Voltage waveforms (a) EXPERIMENTAL RESULTS BY CAPACITOR DISCHARGE (b) (c) Switch Fig. 3. Discharge plasma formation at each conductivity: (a) 110 μS/cm, (b) 500 μS/cm (c), 1500 μS/cm V B. Varying the applied voltage using MPC circuit We measured the discharge plasma for voltages from 15 kV to 30 kV. Discharge plasma was not generated at 15 kV. Fig. 4 shows waveforms of applied voltage, and Fig. 5 shows discharge plasma formation at (a) 30 kV and (b) 15 kV. Reducing applied voltage reduced plasma size and brightness. 35 Voltage (kV) 30 Max voltage : 30 kV 25 Max voltage : 22.5 kV 20 15 Max voltage : 15 kV 10 5 0 -5 -10 -15 Time (μs) Fig. 4. Waveforms of applied voltages. C load 0 Fig. 6. Capacitor discharge circuit. A. Comparison of MPC and capacitor discharge circuits Output waveforms displayed large differences between the MPC and capacitor discharge circuits. In the waveform of conductivity that is 110 μS/cm by the MPC circuit, the maximum voltage is 30 kV and FWHM (full width at half maximum) is about 2 μs. Fig. 7 shows voltage waveforms of conductivity that is 110 μS/cm by the capacitor discharge circuit. The maximum voltage is 3.5 kV and the FWHM is about 20 ms. Fig. 8 is the formation of discharge plasma taken by high speed camera. The interval time of these pictures are 1 ms. These pictures indicate that discharge plasma lasted for about 9 ms under the capacitor discharge circuit but only about 2 μs under the MPC circuit; therefore, the discharge plasma generated by capacitor discharge is far longer-lasting. 4 110 μS/cm 1500 μS/cm 3 2.5 2 1.5 500 μS/cm 2500 μS/cm 4.5 20 ms 4 1 3.5 0.5 Voltage (kV) Voltage (kV) 3.5 0 -0.5 time Fig. 7. Waveforms of voltage of conductivity of 110 μS/cm. 3 2.5 2 1.5 0.4 ms 1 0.5 ① ② ③ 0 time Fig. 9. Waveforms of voltages of each conductivity ④ ⑤ ⑥ ⑦ ⑧ ⑨ (a) (b) (c) Fig. 10. Formations of discharge plasma. (a) 500 μS/cm, (b) 1500 μS/cm, (c) 2500 μS/cm ⑩ ⑪ Fig. 8. Discharge plasma formation taken by the high speed camera. B. Varying conductivity using the capacitor discharge circuit We also assessed the discharge plasma generated by the capacitor discharge circuit for conductivities ranging from 110 μS/cm to 3000 μS/cm for an applied voltage of approximately 3.5 kV. Fig. 9 shows waveforms of the voltage at each conductivity. As the conductivity increased, FWHM grew shorter. Fig. 10 shows the formation of discharge plasma at (a) 500 μS/cm, (b) 1500 μS/cm, and (c) 2500 μS/cm. Discharge plasma formation changed depending on conductivity. Increased conductivity influences discharge plasma color, size, and shape with the plasma becoming larger and more ballshaped. In addition, the discharge plasma also becomes louder. C. Low applied voltage using capacitor discharge circuit Discharge plasma was generated using the capacitor discharge circuit under a low applied voltage, and discharges were measured under varying conductivities. Fig. 11 shows waveforms of a low applied voltage. We reduced the applied voltage as we increased the conductivity. For instance, we applied 1.5 kV for a conductivity of 3000 μS/cm. Fig. 12 shows the formation discharge plasma generated at low applied voltage for conductivities of (a) 500 μS/cm, (b) 1500 μS/cm, and (c) 2500 μS/cm. As conductivity increases, the color of the discharge plasma changes. Fig. 11. Waveforms of minimum applied voltage. (a) (b) (c) Fig. 12. Discharge plasma formations generated by minimum applied voltage. (a) 500 μS/cm, (b) 1500 μS/cm, (c) 2500 μS/cm V. CONCULUSION We generated discharge plasma using both MPC and capacitor discharge circuits. We measured waveforms and discharge plasma formation. Changing the conductivity altered the discharge plasma formed by an MPC circuit with increasing conductivity shortening the length of the streamer of the discharge plasma and increasing the plasma brightness. Decreasing the applied voltage caused the discharge plasma to grow smaller. Discharge plasma was unable to be generated by any voltage under 15 kV. In the case of the capacitor discharge circuit, discharge plasma was generated by a comparatively low applied discharge of 3.5 kV. In this case, the lifespan of discharge plasma FWHM was considerably longer than under the MPC: in the MPC circuit, FWHM was about 2μs, while in the capacitor discharge circuit, FWHM was about 20 ms. From the pictures of discharge plasma by high speed camera, it is considered that the discharge plasma lasts for about 9 ms. For the capacitor discharge circuit, increasing the conductivity caused the discharge plasma to change color, grow larger, and became ball shaped. In the output waveform, as the conductivity increased, FWHM shortened. Also, increasing conductivity decreased the applied voltage for discharge plasma formation. Conductivities below 3000 μS/cm required an applied voltage of 1.5 kV for plasma generation. REFERENCES [1] [2] [3] [4] [5] J. Choi, T. Yamaguchi, K. Yamamoto, T. Namihira, T. Sakugawa, S. Katsuki, H. Akiyama : “Feasibility studies of emtp simulation for the design of the pulsed-power generator using MPC and BPFN for water treatments,” IEEE Trans. Plasma Sci., vol. 34, no. 5, pp. 1744 – 1750, Oct. 2006. B. Sun, M. Sato, and J. S. Clements, “Optical study of active species produced by a pulsed streamer corona discharge in water,” J. Electrostat., vol. 39, no. 3, pp. 189–202, July 1997. J. S. Clements, M. Sato, and R. H. Davis, “Preliminary investigation of prebreakdown phenomena and chemical reactions using a pulsed highvoltage discharge in water”, IEEE Trans. Ind. Appl., vol. IA-23, no. 2, pp. 224-235, 1987. B. R. Locke, M. Sato, P. Sunka, M. R. Hoffmann, and J.-S. Chang, “Electrohydraulic discharge and nonthermal plasma for water treatment,” Ind. Eng. Chem. Res., vol. 45, no. 3, pp. 882–905, 2006. H. Akiyama, “Streamer discharges in liquids and their applications,” IEEE Trans. Dielectr. Electr. Insul., vol.7, no. 5 pp. 646-653, 2000.