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Homework 4 Material Surfaces 1 The 2007 Nobel prize in chemistry was awarded to Gerhard Ertl for his investigations of fundamental processes at gas-solid interfaces. Google ”chemical processes on solid surfaces Nobel”, dowload the commentary on Ertl’s work produced by the Nobel committee and create a ≈ 250 word essay highlighting the main points in the commentary. 2 The attached Excel worksheet contains raw measured asperity elevation data as a function of distance along the surface for a certain material surface (values in micrometers). a) Compute the mean asperity height, adopt the computed value as the reference asperity height and create a new column of transformed data showing the difference between the local asperity height and the reference value. b) Use the data to compute the values of Ra , and Rq . c) Use the data to construct a histogram. Check that the data is approximately normally distributed and find a closed form expression for a good fit Gaussian. Compute then the mean µ, variance σ, Skewness Sk and Kurtosis K. Comment on your results. d) Compute values of the autocorrelation function and discuss. e) Compute the bearing ratio tp for various preselected asperity heights h∗ and also the bearing area curve for the surface. Comment on your results. 3 The contact angle of water on platinum has been measured to be θ = 40 degrees, while that on paraffin is θ = 110 degrees. Estimate the work of adhesion of water on platinum and water on paraffin and comment. 1 4 A cylindrical water bridge (radius r = 0.01 m, thickness h = 0.0001 m) forms between two flat platinum surfaces. Estimate the adhesive force due to the bridge. 5 Carry out calculations to simulate the combined effect of a flat punch and a Hertzian pressure distribution. Compare against the results obtained for the Hertzian pressure alone. 6 The surface of a sample of Al-7075 alloy has been investigated using profilometry. The standard deviation of the asperity heights was measured as s ≈ 1.4µm and the average tip radius of curvature was R = 5µm. Compute the value of the plasticity index ψ and show that the asperities are expected to deform plastically. How small would the standard deviation of asperity heights would have to be in order for the asperities to deform elastically? 2