Download Literature review of Conduction in Polymer - Indico

Last Measurement on GEM and
Literature review of Conduction in
Polymers
Gabriele Croci (CERN)
GDD Meeting
March, the 20th 2008
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Leakage Current in 10x10 GEM
ZOOM
2
Leakage Current in Cu covered Kapton
Foil (GEM 10X10 without holes)
3
Comparison Holes/No Holes
The major effect seems to come from surface conduction
4
REFERENCES
[1] P. Keith Watson, “The transport and Trapping of Electrons in Polymers”, IEEE Transaction on
Dielectrics and Electrical Insulation, Vol. 2 No 5. October 1995
[2] John J. Simmons, “Poole-Frankel Effect and Schottky Effect in Metal-Insulator-Metal Systems”,
Physical Review, Volume 155,3, 15 March 1967
[3] E. Motyl, “Electrode Effects and Electrical Conduction in Polyimide Kapton HN Films”, IEEE
Internation Conference on Conduction and Breakdown in Solid Dielectrics, June 22-25 1998
[4] J-P Salveat et al “Onset and growth of conduction in polyimide Kapton induced by swift heavyion irradiation”, Physical Review B, Volume 55, Number 10, 1 March 1997-II
[5] A. Rose, “Space-Charge Limited Currents in Solids”, Physical Review Volume 97, Number 6,
March 15, 1955
[6] Edward J. Yadlowsky, Robert C. Hazelton, “Radiation Induced conduction in Kapton H Film”,
IEEE Transactions on Nuclear Science, Volume 35, No 4, August 1988
[7] R.G. Filho et al, “Induced conductivity Of Mylar and Kapton Irradiated by X-Rays”, IEEE
Transactions on Electrical Insulation Volume EI-21 No. 3, June 1986
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General Polymer Description
• A polymer is a substance composed of
molecules with large molecular mass
composed of repeating structural units, or
monomers, connected by covalent chemical
bonds
• Poliymide (Kapton, dielectric used in GEM)
belongs to the polymer family
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General statements about Conduction
in Polymers
• Polymers conductivity can be due to the small
number of low-mobility charge carriers and to
the high trap density [1]
• The traps can play a very important role in the
carrier recombination process; they can trap
carriers and release them in a successive time [1]
• Mobility changes of several order of magnitude
with respect the free (without traps) mobility
• Dependence on temperature, applied electric
field and particle (e-, p+, X-rays, Ions..) irradiation
7
Energy Band Diagram in a Polymer [1]
• Slight difference from organized structure like
metals or semiconductors
• The conduction band edge is substituted by the
mobility edge and we can keep the concept of
valence band
• The trap levels are usually between this two
states
• Tentative to discover the energy distribution of
these trapping states injecting electrons inside
the polymer
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Some possible origins of trapping
centers
•
•
•
•
•
•
Impurities in the material [2]
Presence of Radicals in the polymer
Chemical structure of polymer chain
Open covalent (0,C) bounds
Regions of free volumes
….
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Charge Trapping and Decay (1)[1]
• The model described in [1] does not take into
account retrapping after a charge is released by a
trap: this holds for thin polymers
• The current flowing in the polymer is a function
of the energy density of the traps
• Definition of a trapping parameter α=1/μτE
(μ:mobility, τ:characteristic time, E: electric field
in the polymer)
• Electron is shallow states are rapidly detrapped
and are driven more deeply in the material by the
field
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Charge Trapping and Decay (2)
• The charge detrapped
can contribute to the
conduction and can
accumulate on the
surface of the polymer
• Measurement of
Surface Potentials (Vs)
with time
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Other Possible Conduction
Mechanisms [2],[3],[4]
•
•
•
•
•
Poole-Frenkel effect
Schottky Effect
Hopping
Tunneling
Space charge limited currents
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Poole-Freknel Effect
• P-F: field-assisted thermal
ionization; lowering of a
Coulombic potential
barrier with an electric
field; it is associated with
the lowering of a trap
barrier in the bulk
• Change of work function:
W W- eβPFE½
• Change of conductivity:
σ=σ0exp(βPFE½/kT)
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Schottky Effect
• Very similar to Poole-Frenkel Effect. It is the
attenuation of a metal-insulator barrier arising
from electrode image force interaction. It is a
surface effect
• Change of conductivity similar to P-F
σ=σ0exp(βsE½/kT)
• βPF=2βs
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Hopping Models[4]
• Presence of π-conjugated bonds; phonon assisted tunneling
between localized states
• Two basic processes: local jumping between adjacent sites
and “percolation”
• A hop between two localized electronic states occurs when
the atomic vibratory motion changes the relaive energy of
the localized states
• Two kinds of hops
– Adiabatic: large electron energy transfer between states; jump
rate not limited by electron energy transfer or distance between
sites
– Non Adiabatic: low electron energy transfer; jump rate limited
by transfer energy and distances
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Tunneling and Space Charge Limited
Current
• Tunneling is the quantum effect of passing
through a barrier also if the energy is not
enough to overcame the barrier itself
• Space charge limited current[5]: maximum
current that can flow in a built-up capacitor
charged with static charges. The current can
be enhanced by PF effect. Current density has
a voltage square dependence
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Radiation Induced Conduction in
Kapton H Film [6]
• 8 μm thick kapton irradiated by 45 KeV
penetrating electrons
• I-V characteristic depends on the voltage
applied to the irradiated sample:
– Low Voltage (<50V): Ohmic regime, Linear I-V
Characteristic
– Intermediate Voltage (50V<V<700V): Space Charge Limited
Current (SCL) regime, I proportional to V2
– High Voltage (>700V): Trap Filled limit regime (TFL), I
exponentially proportional to V
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Conduction Model [6]
• This is the math form of previous statements
2
V
V
V 2 hV kT
J  Aohmic  BSLC 3  CTFL e
L
L
L
It is possible to see three different regimes at different voltage
values for current density
The constant A,B,C take into account all the parameters of the
material and of the irradiation; h take into account also the
energy gap over which the traps are distributed
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Induced Conductivity of Mylar and
Kapton Irradiated by X-Rays [7]
• Kapton Samples of 80 mm diameter with
thickness varying from 6 to 75 μm were
irradiated with W X-Rays for several hours
• Electric field (of different intensity) were
applied to the samples
• They saw a variation of the Kapton
conductivity
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Induced Conductivity of Mylar and
Kapton Irradiated by X-Rays [7] (2)
From my calculation and considering the rate we are using in our lab to test GEM, we
are very close to the black curve
Next week I will perform this kind of measurement irradiating a 10x10 GEM for
several hours to see if there is a variation of the conductivity
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Measurement of Induced Conductivity inside a
copper-clad kapton foil (GEM w/o holes)
This copper-clad kapton foil was powered with 500 V and irradiated at very high
rate in open air with Cu X-Rays to understand if irradiation will vary its conducibility.
Since measurement was performed in open air, air ionisation maybe a problem.
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Measurement of Induced Conductivity inside a
copper-clad kapton foil (GEM w/o holes)
Literature
K thickness 25 um
E = 8 x 104 V/cm
W X-Rays
There is a slope  0.3 pA/hour
We should get rid of air ionisation!!
HV OFF, X-RAYS OFF
HV ON, X-RAYS OFF
HV ON, X-RAYS ON
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Triple GEM Sealed Detector with
2D (strips) readout
• Goal:
– This detector is using the same material as TOTEM
chambers
– Make a series of measurement before putting this
detector in beam of neutrons and hadrons
– We would like to know if the performance of the
detector is changed after strong hadronic
irradiation
– Test of Radiation Hardness of the material
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Series of measurements to be
performed
•
•
•
•
•
•
•
•
Gain
Maximum Gain
Rate Capability
Discharge Probability
Time Scan: Same Time
Time Scan: On Before
Position Scan
2D Test
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Gain Measurement
8.9 keV X-Rays
Reading 16*3 Y Strips
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Rate Capability
8.9 keV X-Rays
Reading 16*3 Y Strips
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2D Acquisition Test
5.9 KeV X-rays (55Fe)
Pedestal around 100 ADC Ch
Reading 16*3 X and Y Strips
Triggering on X Strips
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On Before Time Scan
Triple Standard
GEM
8.9 keV X-Rays
Reading 16*3 Y Strips
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Last Year Measurements
TRIPLE STANDARD GEM
3 cm x 3 cm GEMs
SINGLE STANDARD GEM
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New Ideas for GEM Gating
April, the 24th 2008
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Experimental Setup
8.9 keV Copper X-Rays
A
Ed
2 mm
B
ET1
3 mm
PreAmp GEM
Gate GEM
C
ET2
7 mm
Bot GEM
EI
2 mm
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PH Spectrum
Ar/CO2 70%/30%
C
B
A
Pedestal
PreAmpGEM Gain ~ 10
BotGEM Gain >=1000 32
Measurement without PreGEM
PH Spectra
Standard GEM
Ar/CO2 70%/30%
350
300
Counts
250
200
Inverted ED
VPreGEM = 0 V
ET1 = 150 V/cm
ET2 = 300 V/cm
VBotGEM = 510 V
EI = 3 kV/cm
C
VGateGEM
VGateGEM
VGateGEM
VGateGEM
=
=
=
=
0V
10 V
20 V
30 V
B
150
100
50
0
-50
0
500
1000
ADC Channels
Pedestal
33
Measurement without PreGEM
Electron Transparency
Standard GEM
Ar/CO2 70%/30%
Electron Transparency
35
Electron Transparency (%)
30
25
20
15
Inverted ED
VPreGEM = 0 V
ET1 = 150 V/cm
ET2 = 300 V/cm
VBotGEM = 510 V
EI = 3 kV/cm
10
5
0
-5
0
5
10
15
20
25
30
V Gate GEM (V)
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Pieter’s Measurements
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