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DEE4521
Semiconductor Device Physics
Lecture 3a:
Transport: Drift and Diffusion
Prof. Ming-Jer Chen
Department of Electronics Engineering
National Chiao-Tung University
October 2, 2014
1
Textbook pages involved
This lecture accompanies pp. 111–131 on
drift and diffusion, as well as pp. 159-175 on
non-uniform doping, of textbook.
2
Drift
Hole drift current density Jp,x,drift = qp<vx> = qppx
Maxwellian velocity distribution (equilibrium) for holes (<vx> = 0)
Shifted Maxwellian velocity distribution
f(vx) for holes (electric field  : must be small)
x
Holes
-
<vx>: drift (NOT thermal)
velocity
p: hole mobility
0
x
vx +
Similarly, for electrons
Jn,x,drift = qnnx
Note: Polarity
3
Diffusion
Electron diffusion current density Jn,x,diffusion = qDndn/dx
p
or
n
very hot
Dn: Electron diffusion coefficient
Hot to Cold: Diffusion
Gradient of carrier density
very cold
x
Dp: Hole diffusion coefficient
4
Why D and its unit?
f(x)
N=0
1
This is a random walk problem.
-3d -2d -1d 0 1d 2d 3d
x
N=1
1/2
1/2
N=2
1/4
Variance [x2] =Nd2
1/4
1/4
1/4
5
I-V in a biased semiconductor
 = V/L
I/A = J
Applied V must be small.
For electrons in a band, Jn = Jn, drift + Jn,diffusion
For holes in another band, Jp = Jp,drift + Jp,diffusion
Total J = Jn + Jp
= (n + p) + diffusion components
=  + diffusion components
Electron conductivity n = qnn
Hole conductivity p = qpp
Total conductivity  = n + p
6
Non-uniformly doped semiconductor
is a Good Vehicle,
1. to derive Einstein’s relationship.
2. to prove that in equilibrium case, Fermi level remains
constant, through any direction in all spaces (real
space, energy space).
7
4-2
8
4-8
Built-in Field in Non-uniform Semiconductors
You must be able to distinguish between built-in electric field and
applied electric field. (hint: Superposition principle)
9
4-9
The experimentally measured dependence of the drift velocity on the applied field.
Figure 3.9
Focus on low field region
(<103 V/cm)
drift =  
10
3-10
Mobility as a function of temperature. At low temperatures, impurity scattering dominates, but at high
temperatures, lattice vibrations dominate.
Figure 3.8
11
3-9
(a) An electron approaching an ionized donor is deflected toward it, but a hole is deflected away from the
donor. (b) Electrons deflect away from the negatively charge ionized acceptors but holes deflect toward them.
Figure 3.5
Coulomb (or Impurity) Scattering
12
3-6
Displacement of atomic planes under the influence of a pressure wave. For a longitudinal wave (a), the
displacement is in the direction of motion. For a transverse wave (b), the displacement is transverse to the
direction of motion. For a three-dimensional crystal, for each longitudinal wave there are two transverse
waves. The dashed lines represent the equilibrium positions, and the solid lines indicate the deflected positions
at a given time.
Figure S1B.6
Lattice Vibrations
13
S1B-6
Room temperature majority and minority carrier mobility as functions of doping in p-type and n-type silicon.
Solid lines: minority carriers; dashed lines: majority carriers.
Figure 3.4
14
3-5
Electron Mobility
n = qfe/m*ce
Electron Conductivity Effective Mass
Electron Mean Free Time
or Electron Average Scattering Time
Time constants are relevant in device physics.
So, the ability to experimentally extract those is essential.
15
How to derive n = qfe/m*ce?
This is a collision (scattering) event. This event is a Poisson event.
Given applied  in a conductor with a length L





l
l
l
l
l
: time to scatter, free time
l: free path, scattering length
Two random variables:  and l
n: total number of collision events
v
v = (a + a +…….+ a)/n
a
t
Slope = a = q/m
vdrift = <v> = na<v>/n =a<v>
…
L = a<2>n/2
 follows exponential distribution
16
n = L/vdrift<>