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Journal #2 • What are two things you know about water? • What are two things you want to know about water? Chapter 6 The Nature of Water The Water Planet • Water covers about 71% of the Earth’s surface. • The world’s oceans provide more than 99% of the Earth’s biosphere: the habitable space on earth. • A majority of the water on this planet cant be used directly for drinking, irrigation, etc. because most of it is salt water. • As the population on Earth increases so does the need for water. How do we meet the demand for water? • What is it? • Where does it go? • How does it cycle in nature? Water’s Unique Properties • Water as a simple molecule: – Its structure gives the unique properties – Hydrogen atoms---Oxygen atoms by a covalent bond (sharing of electrons); makes water very stable • A molecule with a positive (hydrogen end) and negative (oxygen end) end has polarity. This is called a polar molecule. - This enables water to bond with other water molecules. - Positive hydrogen end attracts negative oxygen end. - This bond that forms is known as a hydrogen bond (weak alone, strong in large numbers). Why a polar molecule? • Liquid water: Due to the hydrogen bonds, water is able to be a liquid at room temperature. Otherwise, water would be a gas. • Cohesion/adhesion: Due to hydrogen bonds and polarity, water molecules tend to stick to one another; this is COHESION. When water molecules stick to other things this is called ADHESION. • Viscosity: Tendency for a fluid to resist flow. Colder water= more viscous ex: oil in a frying pan • Surface Tension: a skin-like surface formed due to the polar nature of water. Water’s resistance to organisms trying to break through the surface. Why a polar molecule? • Why does ice float? - When water cools, goes from liquid to solid. - Hydrogen bonds spread out into crystal structure, taking up more space than in liquid form - Ice floats - What would happen if ice sank? Solution vs. Mixture • Solution: molecules of one substance are homogeneously dispersed among the molecules of another substance (seawater) - Solute: the substance being dissolved - Solvent: the substance doing the dissolving (water) • Mixture: when two or more substances closely intermingle, yet retain their individual properties. (chexmix) Salts and Salinity • Salinity: total quantity of all dissolved inorganic solids in seawater • Sodium Chloride is the most abundant sea salt • Scientists measure the salinity in many ways • Varies from no salinity near mouths of rivers to more salinity in confined, arid regions of ocean Colligative Properties: • Properties of a liquid that may be altered by the presence of a solute and are associated primarily with sea water (pure water has none) • They include: – – – – – – Ability to conduct an electrical current (electrolyte) Decreased heat capacity (less heat to raise temp) Raised boiling point Decreased freezing temperature Slowed evaporation: due to attraction of molecules Ability to create osmotic pressure: Osmosis: water molecules moving from high concentration to low concentration. Water moving in= raises osmotic pressure The Principle of Constant Proportions • In seawater, no matter how much the salinity varies, the proportion of several key inorganic elements and compounds NEVER change. • Only the amount of water and salinity changes Why are the Seas Salty? • Source of salts seems to come from eroding minerals and chemicals that dissolve in fresh waters that flow into the ocean. (waves contribute to this as well) • Belief that all of these factors counterbalance, keeping salinity of the ocean fairly constant • Ocean is said to be in chemical equilibrium. Salinity and Temperature • Precipitation vs. Evaporation - Rainfall decreases salinity by adding fresh water - Evaporation increases salinity by removing fresh water - Fresh water input from rivers lowers salinity. • Salinity and Temperature also vary with depth Water Density • Low temperature + high salinity = high density • Warm, low-density surface waters are separated by the cool, high-density deep waters by the thermocline: the zone in which temperature changes rapidly with depth • Salinity differences overlap temperature differences and the transition from low-salinity surface waters to high-salinity deep waters is known as the halocline. • Both together make the pycnocline: zone where density increases as depth increases Acidity and Alkalinity • Concentration of positively charged hydrogen ions or negatively charged hydroxide ions determines waters acidity or alkalinity. • Measured as pH: when solution has many hydrogen ions, considered an acid with a pH value of 0 to less than 7; when solution has a pH value of more than 7 considered a base (lots of hydroxyl ions; called an alkaline) • pH of seawater is relatively stable, but changes slightly with depth because the amount of carbon dioxide also varies with depth. Why is this? Biogeochemical Cycles • Organisms require certain elements and compounds in order to stay alive - Primary nutrient elements related to seawater are: carbon, nitrogen, phosphorus, silicon, iron, and other trace elements. - Not all these nutrients cycle at the same rate; this affects the nature of organisms and where they live in the sea Carbon Cycle Nitrogen Cycle Water Cycle What factors of water affect marine life? • Diffusion and Osmosis: - Diffusion: Moving from high concentration to low concentration - Osmosis: diffusion of water moving from areas of high concentration to low concentration • Hypertonic: water moves from inside (high) the cells to outside the cells (low). Ex: putting a freshwater fish into a marine environment • Isotonic: water molecule concentration is equal on both sides (marine fish in seawater) • HypOtonic: water moves from outside the cells to inside the cells causing them to burst. Ex: placing a marine fish into a fresh water environment (cells will burst in the fish) Active Transport, Osmoregulators, Osmoconformers • Osmosis- type of passive transport moving water molecules from high to low. NO ENERGY • Active Transport: Moves molecules from low to high and REQUIRES ENERGY - Goes against the flow of diffusion • Osmoregulators: Marine fish have ability to regulate water concentration in their cells using active transport; Adapt to changes in salinity • Invertebrates cant control their internal water concentration. Internal salinity rises and falls as salinity rises and falls in the surrounding seawater. These organisms are called osmoconformers. Daily Quiz # 1 1) What does it mean to be polar? What does polarity do for water molecules? 2) Where does the salts in the ocean come from? 3) Differentiate between hypertonic and hypOtonic. How does this affect marine life?