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ENV H 452/ENV H 542 Water and wastewater treatment processes John Scott Meschke Gwy-Am Shin Office: Suite 2249, Office: Suite 2339, 4225 Roosevelt 4225 Roosevelt Phone: 206-221-5470 Phone: 206-543-9026 Email: [email protected] Email: [email protected] Key points • • • • Purpose of the individual unit processes The typical operating conditions The outcome of the processes Microbial reduction in the processes Wastewater treatment processes How much wastewater do we produce each day? Source Domestic sewage Shopping centers Average Daily Flow 60-120 gal/capita 60-120 gal/1000 ft2 total floor area 240-480 gal/bed 18-36 gal/student Hospitals Schools Travel trailer parks Without individual 90 gal/site hookups With individual 210 gal/site hookups Campgrounds 60-150 gal/campsite Mobile home parks 265 gal/unit Motels 40-53 gal/bed Hotels 60 gal/bed Industrial areas Light industrial area 3750 gal/acre Heavy industrial 5350 gal/acre Source: Droste, R.L., 1997. Theory and Practice of Water and Wastewater Treatment These values are rough estimates only and vary greatly by locale. Wastewater Characteristics Wastewater treatment systems • Decentralized – Septic tank – Waste stabilization ponds • Facultative lagoon • Maturation lagoon – Land treatment • Centralized Sewer systems Typical composition of untreated domestic wastewater Microorganism concentrations in untreated wastewater (Minimum) Goals of wastewater treatment processes • <30 mg/L BOD5 • <30 mg/L of suspended solids • <200 CFU/100ml fecal coliforms Conventional Community (Centralized) Sewage Treatment Secondary Treatment Using Activated Sludge Process Pathogen Reductions Vary from: low (<90%) to Very High (>99.99+%) Sludge drying bed or mechanical dewatering process Typical Municipal Wastewater Treatment System Preliminary or Pre- Primary Treatment Treatment Sludge Treatment & Disposal Secondary Treatment Disinfection Preliminary Wastewater Treatment System Preliminary or PreTreatment Solids to Landfill Preliminary Treatment - Bar Racks Bar Racks: are used to remove large objects that could potentially damage downstream treatment/pumping facilities. Ref: Metcalf & Eddy, 1991 Preliminary Treatment Facilities Preliminary Treatment - Grit chamber Grit chamber: used to remove small to medium sized, dense objects such as sand, broken glass, bone fragments, pebbles, etc. Primary Wastewater Treatment Primary Treatment Primary sedimentation • To remove settleable solids from wastewater Primary Clarification Scum: Oil, Grease, Floatable Solids Primary Effluent Primary Sludge Influent from Preliminary Treatment Section through a Circular Primary Clarifier Primary Treatment Primary sedimentation • • • • • • • • To remove settleable solids from wastewater Maximum flow: 30 - 40 m3 per day Retention period: 1.5 - 2.0 hours (at maximum flow) 50 - 70 % removal of suspended solids 25 - 35 % removal of BOD5 ~20 % removal of phosphate ~50 % removal of viruses, bacteria, and protozoa 90 % removal of helminth ova Secondary Wastewater Treatment Secondary Treatment Secondary treatment processes • To remove suspended solids, nitrogen, and phosphate • 90 % removal of SS and BOD5 • Various technologies – Activated sludge process – Tricking filter – Aerated lagoons – Rotating biological contractors Secondary Treatment Using Activated Sludge Process Sludge drying bed or mechanical dewatering process Secondary Treatment Secondary Treatment Simplified Activated Sludge Description The Activated Sludge Process Aerobic microbes utilities carbon and other nutrients to form a healthy activated sludge (AS) biomass (floc) The biomass floc is allowed to settle out in the next reactor; some of the AS is recycled Secondary Treatment Activated sludge process • To remove suspended solids, nitrogen, and phosphate • Food to microorganism ratio (F:M ratio): 0.25 kg BOD5 per kg MLSS (mixed liquor suspended solids) per day at 10 oC or 0.4 kg BOD5 per kg MLSS per day at 20 oC • Residence time: 2 days for high F:M ratio, 10 days or more for low F:M ratio • Optimum nutrient ratio: BOD5:N:P =>100:5:1 • 90 % removal of BOD5 and SS • ~20 % removal of phosphate • >90 % removal of viruses and protozoa and 45 - 95 % removal of bacteria Secondary Treatment Using Trickling Filter Process Trickling Filter Secondary Treatment Secondary Treatment Trickling Filter Primary effluent drips onto rock or man-made media Rotating arm to distribute water evenly over filter Rock-bed with slimy (biofilm) bacterial growth Treated waste to secondary clarifier Primary effluent pumped in http://www.rpi.edu/dept/chem-eng/Biotech-Environ/FUNDAMNT/streem/trickfil.jpg Trickling Filter http://www.eng.uc.edu/friendsalumni/research/labsresearch/biofilmreslab/Tricklingfilter_big.jpg Tricking filter process • To remove suspended solids, nitrogen, and phosphate • Organic loading (BOD5 X flow/volume of filter): 0.1 kg BOD5 per m3 per day • Hydraulic loading: 0.4 m3 per day per m3 of plan area • 90 % removal of BOD5 and SS • ~20 % removal of phosphate • Variable removal levels of viruses, 20-80 % removal of bacteria and >90 % removal of protozoa Wastewater Disinfection Disinfection Wastewater disinfection • To inactivate pathogens in wastewater • Several choices – Free chlorine and combined chlorine – UV – Ozone – Chlorine dioxide Overall pathogen reduction in wastewater treatment Water treatment processes Water contaminants • Chemicals – Inorganics – Organics • Synthetic organic compounds • Volatile organic compounds • Microbes – – – – – Viruses Bacteria Protozoa parasites Algae Helminths Water contaminants (I) Water contaminants (II) Water contaminants (III) Water contaminants (IV) Water contaminants (V) Multiple barrier concept for public health protection Barrier Approach to Protect Public Health in Drinking Water • • • • Source Water Protection Treatment Technology Disinfection Disinfectant residual in distribution system Water treatment processes Oxidation • To remove inorganics (Fe++, Mn++) and some synthetic organics – Cause unaesthetic conditions (brown color) – Promote the growth of autotrophic bacteria (iron bacteria): taste and order problem • Free chlorine, chlorine dioxide, ozone, potassium permanganate – Fe++ + Mn ++ + oxygen + free chlorine → FeOx ↓ (ferric oxides) + MnO2 ↓ (manganese dioxide) – Fe (HCO3)2 (Ferrous bicarbonate) + KMnO4 (Potassium permanganase) → Fe (OH)3 ↓ (Ferric hydroxide) + MnO2 ↓ (manganese dioxide) – Mn (HCO3)2 (Manganese bicarbonate) + KMnO4 (Potassuim permanganase) → MnO2 ↓ (manganese dioxide) Physico-chemical processes • To remove particles in water • Coagulation/flocculation/sedimentation • Filtration Rapid Mix • Intense mixing of coagulant and other chemicals with the water • Generally performed with mechanical mixers Chemical Coagulant Major Coagulants • Hydrolyzing metal salts – Alum (Al2(SO4)3) – Ferric chloride (FeCl3) • Organic polymers (polyelectrolytes) Coagulation with Metal Salts Soluble Hydrolysis Species + + Al(OH)3 (Low Alum Dose) (High Alum Dose) Colloid Colloid Alx(OH)y Colloid Al(OH) Al(OH)3 Al(OH)3 Floc Colloid Al(OH)3 Colloid Al(OH)3 Al(OH)3 Al(OH)3 Colloid Al(OH)3 Charge Neutralization Al(OH)3 Sweep Coagulation Horizontal Paddle Flocculator Flocculation Example Water coming from rapid mix. Water goes to sedimentation basin. Sedimentation Basin Sedimentation Basin Example Water coming from flocculation basin. Sludge to solids treatment Water goes to filter. Floc (sludge) collected in hopper Coagulation/flocculation/and sedimentation • • To remove particulates and natural organic materials in water Coagulation – 20 -50 mg/L of Alum at pH 5.5-6.5 (sweep coagulation) – rapid mixing: G values = 300-800/second • Flocculation: – Slow mixing: G values = 30-70/second – Residence time:10 -30 minutes • Sedimentation – Surface loading: 0.3 -1.0 gpm/ft2 – Residence time: 1 – 2 hours • • Removal of suspended solids and turbidity: 60-80 % Reduction of microbes – – – – – 74-97 % Total coliform 76-83 % of fecal coliform 88-95 % of Enteric viruses 58-99 % of Giardia 90 % of Cryptosporidium Filtration • To remove particles and floc that do not settle by gravity in sedimentation process • Types of granular media – Sand – Sand + anthracite – Granular activated carbon • Media depth ranges from 24 to 72 inches Filter Example Water coming from sedimentation basin. Anthracite Sand Gravel (support media) Water going to disinfection Mechanisms Involved in Filtration Floc particles Interception: hits & sticks Flocculation: Floc gets larger within filter Entrapment: large floc gets trapped in space between particles Sedimentation: quiescent, settles, & attaches Granular media, e.g., grain of sand Removal of bacteria, viruses and protozoa by a granular media filter requires water to be coagulated Rapid filtration • • • • To remove particulates in water Flow rate: 2-4 gpm/ft2 Turbidity: < 0.5 NTU (often times < 0.1 NTU) Reduction of microbes – – – – – 50-98 % Total coliform 50-98 % of fecal coliform 10-99 % of enteric viruses 97-99.9 % of Giardia 99 % of Cryptosporidium Disinfection in water • To inactivate pathogens in water • Various types – Free chlorine – Chloramines – Chlorine dioxide – Ozone – UV Trend in disinfectant use (USA, % values) Disinfectant 1978 1989 1999 Chlorine gas 91 87 83.8 NaClO2 (bulk) 6 7.1 18.3 NaClO2 (onsite) 0 0 2 Chlorine dioxide 0 4.5 8.1 Ozone 0 0.4 6.6 Chloramines 0 20 28.4 Comparison of major disinfectants Consideration Disinfect ants Cl2 Oxidation potential Residuals Mode of action Disinfecting efficacy By-products Strong ClO2 O3 Stronger? Strongest Yes No No Proteins/ Proteins/ Proteins/ NA NA NA Good Very good Excellent Yes Yes Yes? NH2Cl Weak Yes Proteins Moderate No