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Chem G Review Chemistry is the study of matter and the changes it undergoes. Matter is anything that has mass & volume Changes can be Physical: melting, freezing, evaporating Chemical: neutralization, combustion Chemical Reactions Chemical reactions are in the form of: Reactant + Reactant Product + Product What other symbols are included in a chemical reaction? (page 206) Write the following chemical reactions: Sulfur burns in oxygen to form sulfur dioxide. Sodium metal and water form sodium hydroxide and hydrogen gas Why H2? Diatomic elements: HONCl BrIF These elements are never found alone. Always in combination with other atom even if just another of its own kind. Example: oxygen = O2 Types of Chemical Reactions Combination (synthesis) Reactions Two or more substances combine to form a single substance Example: SO3 + H2O H2SO4 Calcium oxide and water form calcium hydroxide Types of Chemical Reactions Decomposition reactions A single compound is broken into two or more compounds Example: Calcium carbonate is heated and decomposes into calcium oxide and carbon dioxide Types of Chemical Reactions Single-Replacement (displacement) One element replaces another in a compound Example: Mg + ZnCl2 Zn + MgCl2 Calcium oxide reacts with aluminum metal Types of Chemical Reactions Double Replacement (displacement) Reactions An exchange of the positive and negative ions in each compound Example: MgCl2 + Li2O MgO + LiCl Barium chloride and potassium fluoride form the compounds barium fluoride and potassium chloride Types of Chemical Reactions Combustion Reactions What do you remember about this type of reaction? _________ + __________ _________ + _________ Chemical Reaction of Solutions Solution - two or more substances physically combined that appear uniform throughout. Solutions are composed of: solvent - substance into which the solutes are dissolved solutes - substances being dissolved. Solvent/ Solute combinations Solids solid/solid alloys (Ni and Pt into Au) liquid/solid amalgam fillings (Hg into Ag) gas/solid CO into Pt or Pd Solvent/ Solute combinations Liquids solid/liquid Kool Aid (sugar into water) liquid/liquid paint in paint thinner gas/liquid carbon dioxide into pop Solvent/ Solute Combinations Gases solid/gas Food odors into the air liquid/gas perfume into the air gas/gas oxygen into the air The Solubility Rules for Water 1. All common salts of lithium, sodium, potassium, and ammonium are soluble. 2. All common salts of nitrates, acetates, chlorates, and perchlorates are soluble. 3. All common salts of chlorides, bromides, and iodides are soluble, EXCEPT for those of Ag, Pb(II), and Hg(I). 4. All common salts of sulfates are soluble, EXCEPT for those of Pb(II), Ca, Sr, and Ba. 5. All common salts of carbonates, phosphates, hydroxides and sulfide are insoluble, EXCEPT for those listed in rule 1. Sample Compounds lithium chloride _____ iron (III) phosphate _____ magnesium chloride _____ ammonium sulfate _____ sodium carbonate _____ Sample Compounds lithium chlorate _S(1)or(2)_ iron (III) phosphate _I(5)_ _S(3)_ magnesium chloride _S(1)or(4)_ ammonium sulfate _S(1)or(5)_ sodium carbonate Sample Compounds Ba(NO3)2 _________ Na3(PO4) _________ BaCl2 Ca(SO4) Fe(CO3) _________ _________ _________ Sample Compounds Ba(NO3)2 _soluble (2) Li3(PO4) _soluble (1) BaCl2 _soluble (3) Ca(SO4) _insoluble (4) Fe(CO3) _insoluble (5) Polar and Non-Polar Polar molecules have a definite positive and negative end. (water, ionics, alcohols) Non-polar molecules have uniform external charge General Rule to Solutions Like solvents dissolve like solutes, and unlike solvents will not. (Like dissolves like) Freezing Point Depression What is the science behind putting salt on the roads in the winter? Polar and Non-Polar Some molecules are large enough to have both polar and non-polar characteristics. Soap molecules are an excellent example of a bipolar particle Solubility and Saturation Is there a limit to the amount of salt that will dissolve in to a certain amount of water? Yes?? No?? Explain Solubility and Saturation The solute will continue to dissolve until the solution is full of solute: Saturated-as much as possible Unsaturated -less than possible Supersaturated-more than possible Solubility and Saturation Dissolving can be aided in three ways: 1. ______________ 2. ______________ 3. ______________ General Rule to solubility If only a little solute will dissolve in a lot solvent, the solute is said to be insoluble. If only a lot solute will dissolve in a little solvent, the solute is said to be soluble.