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Chemistry Revision Session 8 Naming Alkenes Name this alkene And what about (CH3)2CHCHCH2? Isomerism What type of isomerism is this? Why does it occur? Mechanisms! Explain how bromine reacts with ethene (4 marks) Identify the mechanism type! Polymers Draw a section of polymer chain to show the structure of poly(propene) Draw a section of the polymer chain obtained from the monomer 1-chloroprop-1-ene! Identify the intermolecular forces present in each polymer Which would be more flexible? Why? More on IMF Why does H2O have a higher boiling point than H2S? Include a diagram in your answer for water!! What is the shape of H2S? Test! How can I differentiate between ethane and hex-3-ene in the laboratory? Sorry Couldn’t resist ONE trick question- in the lab ethene will be a gas, where as, of course, hex-3-ene is a liquid. The more sensible question to ask is how to differentiate between hex-3-ene and hexane! Add bromine water- which will be decolourised by hex-3-ene (orange colourless) Definitions Explain the difference between thermosetting and thermoplastic ploymers What is a co-polymer What is the difference between a crystalline and a amorphous region of a polymer How will this affect its properties? Manipulating polymers Explain how each of the following will affect a polymers strengthAdding a side group to the monomer- eg CH3 Increasing the chain length of the polymer Substituting a Cl atom for an H atom in the monomer Substituting that Cl for an amine group Manipulating Polymers Give 2 other ways I can increase the strength of a polymer Again- boring though it may be- justify your answer! Manipulating polynmers Cross-linking Increasing stereo-regularity Alcohols Which is/are secondary alcohols and which is/are tertiary alcohols? Name the product if I oxidise- Name the functional group State the reagents and conditions How would it be different if I oxidised ethanol using mild conditions? And if I spent too long drinking coffee (surely not) and came back too late I would have made which compound? Dissolving Polymers The polymer with the repeating unit shown below dissolves well in water. Why? H OH ----C—C-----n H H Final definitions Define the terms: Elimination Electrophile