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Sunbeds and stars... Ionization, excitation and line spectra Incident radiation p Hydrogen Atom e Electron absorbs energy and… Ionisation! p e Is able to completely escape from the atom Ionisation! p e Energy = 0 Energy = -13.6eV • Photons with a minimum energy of 13.6eV are needed to ionise a hydrogen atom from it’s ground state. Lower frequency radiation p Hydrogen Atom e Electron absorbs radiation and… Excitation! p e Is only able to move to a higher energy state within the atom The electron in its excited state is unstable and so it drops back, releasing the energy as a photon. -13.6eV p -3.6eV e One photon with a specific amount of energy is released in an electron transition 10eV Ionisation and excitation in a fluorescent tube • High voltage - electrons bombard mercury atoms • Excitation occurs - unstable electrons fall back • Ionisation allows the current to flow - + High Voltage e e e Mercury e Argon High voltage - e e e e Phosphorous coating Fluorescence e e Argon + Spectral transitions in hydrogen Ionisation 0eV Electron transitions Ground state -13.6eV Spectroscopy Looking at the signatures of elements Intensity Wavelength of radiation emitted or absorbed