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Herbicides
Stephen J. Toth, Jr.
Department of Entomology
North Carolina State University
Wayne G. Buhler
Department of Horticultural Science
North Carolina State University
Photograph from University of Illinois
Weeds
• Compete with desirable plants
for water, nutrients, light and
space
• Contaminate crop at harvest
• Harbor pest insects, mites,
vertebrates or plant disease
agents
• Release toxins in the soil which
may inhibit crop growth
Photographs by David
and Dale Monks.
Stages of Plant Development
• Seedling - small, vulnerable plants
• Vegetative - rapid growth and production of
stems, roots and foliage
• Seed production - energy is directed toward
the production of seed
• Maturity - little or no energy production
Weeds Annual Plants
Lambsquarters
• Complete all four stages of
growth in one year
• There are many annual
weeds, including pigweed,
crabgrass, lambsquarters,
morningglory, cocklebur and
henbit
Tall morningglory
Photographs by Kathy Kalmowitz and David Monks.
Weeds - Biennial
Plants
• Complete the seedling and
vegetative stages of growth in
first year; seed production and
maturity stages are completed
in second year
• Common biennial weed is
wild carrot (also known as
Queen Anne’s lace)
Photograph courtesy of the University of Illinois.
Queen Anne’s Lace
Weeds - Perennial Plants
• May or may not complete all
four stages of growth in first
year, then repeat vegetative,
seed and maturity stages for
several more years
• Seed production and maturity
stages may be delayed for
several years
• Examples: Johnsongrass,
Bermudagrass, pokeweed
Bermudagrass
Photograph by David Monks.
Weed Classification - Grasses
• Have only one leaf as
they emerge from seed
• Leaves are narrow and
upright with parallel
veins
• Examples are Johnsongrass and crabgrass
Johnsongrass
Photograph by Dale Monks.
Weed Classification - Broadleaves
• Have two leaves as
they emerge from seed
• Leaves broad with
netted veins
• Usually have taproot
and coarse root system
• Examples: pigweed,
cocklebur, dandelion
and poison ivy
Cocklebur
Photograph by David Monks.
Weed Classification - Sedges
• Similar to grasses, but have
triangular (3-sided) stems
• Often listed on pesticide
labels as grasses, but
certain herbicides will
control grasses and not
sedges (i.e., Poast)
• Examples are nutsedges
Yellow nutsedge
Photograph by David Monks.
Factors Affecting Weed Control
• Growing points - contact herbicides do not
reach those sheathed or below soil surface
• Leaf shape - herbicides run off of narrow
upright leaves; held by broad, flat leaves
• Wax and cuticle - thick wax/cuticle layer
prevents herbicide entry; waxy surface forms
droplets which run off leaves
• Leaf hairs - dense layer hold droplets away
from leaf; thin layer holds herbicide longer
Factors Affecting Weed Control
• Plant size and age - young, rapidly-growing
plants more susceptible to herbicides
• Deactivation - certain plants can deactivate
herbicides and are less susceptible; basis for
herbicide selectivity, can cause resistance
• Plant life cycle - seedlings very susceptible to
most weed control methods; vegetative and
early bud stages susceptible to translocated
herbicides; timing important
Weed Control Methods
• Cultivation - traditional weed
Farmer cultivating beans
control method; may increase
erosion, spread weeds/diseases
• Planting timing - planting date
delayed to avoid or remove weeds
• Mulching - keeps light from weed
seedlings
• Mowing - often used in orchards;
prevents erosion
• Others - nurse crops, fire and
flooding (in rice)
Photograph by Bill Tarpenning, USDA/ARS.
Herbicide Characteristics
• Foliage-absorbed: herbicide kills all foliage contacted
• Root-absorbed: herbicide is applied to the soil
• Contact: herbicide must be applied directly to weeds, little
or no movement to underground or shaded part of weed
• Translocated: herbicide is absorbed and moves throughout
the living portion of the plant (weed)
• Selective: differences between plant and weed (foliar
characteristics, deactivation) makes herbicide selective
• Nonselective: herbicide kills most plants, must be applied
in absence of desirable plants
Herbicide Characteristics
• Persistent: herbicide remains for weeks or months
• Nonpersistent: herbicide remains for hours or days
• Pre-plant incorporated (PPI): herbicide application made
prior to planting and mixed into the soil
• Preemergence: herbicide is applied after planting, but
prior to crop and, generally, weed emergence
• Postemergence: herbicide application occurs after crop
emergence (also can refer to after weed emergence)
Inorganic Herbicides
• Romans used brine and a mixture of salt and ashes to
sterilize land in biblical times (nonselective herbicides)
• Copper sulfate used in grain fields to kill weeds in 1896
• Sodium arsenite solutions used as herbicides from 1906
to 1960
• Sodium chlorate used for nonselective weed control for
the last 50 years
• A few inorganic herbicides are still in use, but are being
replaced by organic herbicides because of persistence of
inorganic herbicides
Organic Herbicides
Arsenicals:
• Inhibit the growth of weeds
• Not as toxic to mammals (humans) as inorganic forms
of arsenic
• Not used in agriculture as widely as in the past
• Example is monosodium methanearsonate (MSMA)
Additional Organic Herbicides:
• Numerous classes of herbicides with several modes
of actions
Organic Herbicides Arranged by Mode of Action:
Growth Inhibitors (Soil Applied)
• Acetanilides: inhibit root growth;
alachlor (Lasso), metolachlor (Dual)
• Dinitroanilines: inhibit root
and shoot growth; benefin
(Balan), oryzalin (Surflan),
pendimethalin (Prowl) and
trifluralin (Treflan)
• Thiocarbamates: inhibit root
and shoot growth; pebulate
(Tillam), thiobencarb (Bolero)
Organic Herbicides Arranged by Mode of Action:
Growth Inhibitors (Soil & Foliar Applied)
• Imidazolinones: inhibit
root and shoot growth;
imazapyr (Arsenal) and
imazaquin (Scepter)
• Sulfonylureas: inhibit
root and shoot growth;
nicosulfuron (Accent)
and primisulfuron
(Beacon)
Organic Herbicides Arranged by Mode of Action:
Growth Inhibitors (Foliar Applied)
• Phosphono amino acids:
inhibit shoot growth;
glyphosate (Roundup)
• Phenoxy proprionic acids:
inhibit shoot growth;
fluazifop-butyl (Fusilade)
• Cyclohexones: inhibit
root and shoot growth;
sethoxydim (Poast)
Organic Herbicides Arranged by Mode of Action:
Photosynthesis Inhibitors (Soil & Foliar Applied)
• Triazines: atrazine (Aatrex), metribuzin (Sencor) and
simazine (Princep)
• Phenylureas: linuron (Lorox)
• Uracils: terbacil (Sinbar)
Organic Herbicides Arranged by Mode of Action:
Photosynthesis Inhibitors (Foliar Applied)
• Benzothiadiazoles:
bentazon (Basagran)
• Phthalic acids:
endothall (Aquathol)
Organic Herbicides Arranged by Mode of Action:
Cell Membrane Disrupters
• Bipyridyliums: paraquat
• Diphenyl ethers: acifluorfen (Blazer)
Organic Herbicides Arranged by Mode of Action:
Plant Growth Hormones
• Phenoxy acids: affect cellular division and metabolism;
2,4-D and 2,4,5-T
• Benzoics: resemble growth hormones; dicamba (Banvel)
• Pyridinoxy acids: hormone herbicides; picloram (Tordon)
References
• Ware, G. W. An Introduction to Herbicides.
Radcliffe’s IPM World Textbook.
(http://ipmworld.umn.edu/chapters/wareherb.htm)
• Ware, G. W. 1994. The Pesticide Book. 4th
edition. Thomson Publications, Fresno, California.
pp. 103-125.
• U. S. EPA. 1993. Agricultural Pest Control Plant Training Manual. pp. 18-26.