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Stars: Element Factories •Review of last class • Dimitri Mendeleev and the Periodic Table •What is an isotope? •Internal structure of the Sun •Stars and nuclear fusion What’s a Mole??? Mole (abbr. mol): An amount of an element (or compound) whose mass, expressed in grams, is numerically equal to its atomic (or molecular) weight. Atomic Number (Z ) Atomic Symbol Atomic Weight Avogadro’s Number • Avogadro’s number: the number of atoms in 1 mole • 6.022 10 23 mol-1 Dimitri Mendeleev • At 33, Russian chemist Dimitri Mendeleev was appointed as chair of chemistry at the University of St. Petersburg. • In 1871 he published a periodic table of the elements and predicted the properties of 3 new elements (Gallium, Scandium and Germanium, discovered in 1875, 1879 and 1886) Mendeleev’s Periodic Law • The properties of elements are periodic functions of their atomic weight K Na Rb Cs Julius Meyer, 1870 Mendeleev’s Periodic Law • The periodicity led him to organize the elements into the PERIODIC TABLE OF ELEMENTS Sample calculation •Atomic weight of copper (Cu): 63.55 g • A 63.55 g sample of Cu (= 1 mole) contains 6.022 1023 atoms. • A penny weighing 1 g contains 6.022 10 63.55 = digits) 23 9.48 1021 atoms (to 3 significant Atomic isotopes • Mass number (A): number of protons + number of neutrons in an atom •A is often indicated in the top left corner of the element symbol 16O, 18O What’s an Isotope??? • Definition: An Isotope is one of two or more atoms having the same atomic number but different mass numbers. Hydrogen (1H) Deuterium (2H) Tritium (3H) Uranium-235 (235U) Uranium-238 (238U) Mass number (A) Number of protons (Z) Number of neutrons 1 2 3 1 1 1 0 1 2 235 92 143 238 92 146 Molecules • Definition: Molecules are two or more atoms joined together by chemical bonds. • E.g., H O 2 • The molecular weight is ~ the sum of the atomic weights. • one mole of water weighs ~ 18.02 g. Composition of the universe Helium (7.8%) Hydrogen (92%) Carbon (.03%) and Oxygen (.06%) All other elements (.11%) How are the elements created? The Sun The sun’s size in perspective To scale Interior of the Sun • The sun has multiple layers (like an onion) • The sun’s energy source is generated by H fusion at the core • Heat escapes the core by radiation • In the outer part of the sun, heat is transferred by convection Solar Data Value Surface temp. 6000oC Diameter 1.392x106 km Density 1.41 g/cm3 Mass 1.989x1030 kg Surface gravity 274.4 m/s2 Luminosity 3.9x1026 Watt Rotation period 25.4 days Equator 28.0 days 40o latitude 36.4 days 80o latitude Compared to Earth Hot! 109 0.26 330,000 28 1.2x1014 * * Compared to energy consumption of U.S.A. Nuclear fusion reactions Definition: Nuclear fusion is the process of combining two (or more) atomic nuclei to create a new element. • Requires extremely high temperature and pressure • Energy release: E = mc2 Hydrogen fusion: the sun’s energy source (at the present) • All naturally occurring elements are created by fusion in the interiors of stars •4 H nuclei are required to make 1 He nucleus • Net mass reduction: 0.7% • H -> He is a 3-step process Evolution of a 15 solar-mass star Element fused Hydrogen Helium Carbon Neon Fusion product Helium Carbon O, Ne, Mg O, Mg Oxygen Silicon Si, S Iron Time Temp. (K) 1010 years > 106 years 1000 years A few years 1 year A few days 4x106 1x108 6x108 1x109 2x109 3x109 Source: In Quest of the Universe, Kuhn, 1998