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Transcript
Honors Chemistry Periodic Table Notes
Antoine Lavoisier (1700’s)
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
Listed all known elements (33) at the time
4 groups: _____________,____________, ___________ and _____________.
Dobereiner (early 1800’s)

Arranged the elements into _______ (groups of three elements) based on __________ in properties.
John Newlands (1864)
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Arranged elements by increasing atomic ________. (70)
Noticed a ___________ pattern of ____________.
Created the ________________________ (repeating patterns at every eighth element)
Lothar Meyer (1869)
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
Identified and proved that there was a connection between ________ ________ and the ________
of the element
Arranged the elements by increasing atomic mass (added the ________ ________)
Dmitri Mendeleev (1869)
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Proved a __________ between atomic mass and element properties
Arranged elements by increasing atomic mass
Predicted the ___________ and __________ of elements yet to be ___________
Henry Moseley (1913)
•
•
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Discovered atomic _______________
Arranged elements by increasing atomic number
By doing this a pattern of properties was discovered and fixed previous problems
Periodic Law
•
•
When elements are arranged by increasing atomic __________, there is a periodic repetition of
___________and ____________ properties.
Modern Periodic Table:
o __________ (rows)- contain a variety of elements ranging from metals to nonmetals to
Noble gases. There are __________.
o __________ or __________ (columns)- contain elements that share similar properties.
There are ________.
Representative (Main) Elements:
• Marked by “___” on most groups.
• Elements in the ____ and _____ block
• _________ range of characteristics
• This is ____________ ______________
Transition Elements (B) Consists of only metals.
• Found in the ___________ of the period table.
Metals, Nonmetals, and Metalloids
Metals:
•
•
•
•
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Make up ___________ of the periodic table
________ at room temperature (except __________)
Good conductors of _________and _____________
____________ and _____________
Have Luster (____________)
Nonmetals:
• __________ or _________ at room temperature (except ________, it is a liquid)
• ___________ conductors of heat or electricity
• _____________
• Dull
Metalloids:
• ____________ of characteristics of both ___________ and nonmetals
• ______, ________, ________, _________, ________, _________, _________, _______
• Silicon and Germanium both used in computer chips
S- Block:
•
•
Alkali Metals
– 1 valence e-. This makes them highly ____________
– Exist only as ____________
– Silvery white in color
– Often bond with ______________
– Used in salts and batteries
– Forms _________ with a ________ charge.
Alkaline Earth Metals
– 2 valence e-. Makes them highly reactive
– Ca and Mg are important components of living cells
– Silvery in color
– Used to make laptop casings
– Forms ions with a ________ charge.
P- Block (Families 13-18):
•
•
•
•
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Boron Family (13)
– 3 valence e– Tends to _________ its valence e- away
– Most are ____________
– Not as ____________ as group one and two
– Forms ions with a 3+ charge
Carbon Family (14)
– 4 valence e– Can either _________ __________ its valence electrons or take additional electrons
– Sn and Pb will form ions with 4+charges
Nitrogen Family (15)
– 5 valence e-, but will form _______ (it prefers to _______ 3 e- rather than ____ away 5)
– N and P are reactive and found in many molecular compounds
Oxygen Family (16)
– 6 valence e– Forms 2- ions. It prefers to gain_________ 2 e- rather than give away 6)
– O and S are reactive and found in many compounds
Halogens (17)
– 7 valence e– Form 1- ions (gains 1 e-)
– Highly reactive ____________
– Will often bond with metals to make ________
Noble Gases (18)
– 8 valence e-, full p ___________
– Does not form ions
– Inert gases (__________)
– They do not __________ with other elements because they do not need any more e-.
D- Block (3-12)
• All ____________ metals
• Most are hard metals
• All can exist as _________ elements in nature
• Will form a variety of _________ ions due to the fact that the s and d sublevels are close in
energy amounts
F- Block (Period 6 and 7)
• Lanthanide Series
– elements 57-70
– Fits in period _______
– Shiny metals
– Highly ___________
• Actinide Series
– elements 89-102
– Fits in period _________
– Radioactive
– The first 4 are naturally occurring the rest are lab created
** For the Lanthanides and Actinides:
Electrons fill the f-orbitals in an ____________ manner
and there are many ___________ to electron configuration rules.
•
Octet Rule: Every Element wants 8 valence e-
Formation of Ions:
• A positive ion (called a __________) results when an atom _________electrons.
• A negative ion (called an ___________) results when an atom ______ electrons.
Periodic Trends:
• Patterns in the periodic table that can be determined by __________ a period or a group
• ____________, _______________, ______________, __________________
Atomic Radius:
•
•
•
The “__________ of atom”
the outer edge of an atom is not clearly defined; there is no definite edge
atomic radius is therefore ________ the distance between two identical nuclei
R = AB/2
Atomic Radius Trend:
•
__________as you go __________ the period - as you go across a period, more ___________ in nucleus,
greater positive charge. Added __________ in ______principal energy level, so they get pulled closer to
nucleus.
•
Increases as you go down the ________ – as you go down a group, more ________ are added increasing
nuclear charge. However added electrons are in successively _______ energy levels which are _______
from the nucleus. This offsets the increased positive charge in nucleus. Also, increased number of inner
electrons shield the outer electrons from increased nuclear charge. Electrons are NOT pulled as tightly
toward the nucleus.
Ionic Radius:
•
•
Cations have ______ electrons to become __________ charged– they become smaller than their
___________ atom. Electrons lost are __________ electrons. This can leave an empty outer
orbital resulting in a smaller ________. Electrostatic repulsion between remaining electrons
decreases, so remaining electrons are pulled in ______ to positively charged nucleus
Anions have __________ electrons to become negatively charged – they become ________
than their parent atom. Additional _________ increase electrostatic repulsion among outer
electrons forcing them to move _________ apart (and further from nucleus)
Ionic Radius Trend:
•
•
Cation and anion size __________ as you go across a period
Both cation and anion size ___________ going down a group
** What do you notice about both the ionic and atomic radii trends?
Ionization Energy:
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Removing an ___________ from a neutral atom requires ________!
Ionization energy is the amount of energy required to remove an electron (the outermost) from
a gaseous atom
_________ ionization energy indicates an atom’s nucleus holds on strongly to its electrons
•
These atoms will _______ lose electrons
•
______ atoms have high IE
________ ionization energy indicates an atom’s nucleus has a weaker hold on its electrons
•
These atoms will lose electrons _______
**Metals = have ________ IE, therefore lose electrons (become cations)
**Nonmetals = have _______ IE, therefore gain electrons (become anions)
Ionization Energy Trend:
 Increases across the period – atoms get __________ as you move across a period. Increased
positive nuclear charge holds ________ to electrons.
 Decreases down the group – atoms get larger_________ as you move down a group. Valence
electrons are further_________ from positive nuclear charge, so not held as tightly. ____ to
remove.
Electronegativity:
•
•
•
the ability of an atom to _________ an electron while in a __________ bond
electronegativity expressed in “Paulings” – numbers from 0 - 3.98
the larger the electronegativity value, the _________ an atom is at _______ electrons while in
the chemical bond
Electronegativity Trend:
•
•
_______across the period – atoms are smaller going across a period, _______shell is closer to
being full, and it is closer to the ______ nuclear charge
Decreases down the _______ – atoms are larger going down a group, outer orbitals ________
from positive nuclear charge, not good at attracting electrons
What do you notice about both the ionization energy and electronegativity trends?