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Chemical Family: Phenols Phenols Phenols are known to be reactive as they release their hydrogen hydroxyl (-OH) and bind with other positively-charged molecules, including protein which can be harsh and cause skin damage. Essential oils containing phenols are aggressive in nature and have a strong aroma. It is the benzene ring (6-carbon ring) that distinguishes it from alcohols. The benzene ring is typically drawn with a circle in the middle to signify that all the bonds in the ring are equal. Like alcohols, many phenol names end in “-ol.” Phenols tend to be base to middle notes, lasting longer on the skin. They are also responsible for the fragrance of an oil. Pictured left to right is the molecular structure of carvacrol, eugenol, thymol, members of the Phenols chemical family. Phenols Chemical Component Family and Oils that Have Them Eugenol can be protective to the liver, but only in low concentrations. In high concentrations, it is hepatotoxic and can cause damage to tissues. When used in acute illnesses and with infections, phenols can stimulate the immune system. Phenols are strengthening and analgesic and anti-inflammatory. Thymol found in thyme is beneficial for acute respiratory infections. Clove Bud essential oil is 67% phenols and is excellent for combating infections, but should be avoided by people on blood thinners due to its high eugenol content. They contain high levels of oxygenating molecules and have anioxidant properties. Carvacrol Eugenol Thymol Chavicol Methyl eugenol Methyl chavicol anethole Anti-inflammatory, anti-infectious, antioxidants, radical savenger Analgesic, anti-inflammatory Anti-inflammatory, anti-infectious Anti-inflammatory, anti-infectious, anticancerous Safrole Myristicin Apiol Oils that contain Phenols Cinnamon Bark - cinnamomum-zeylanicum Clove Bud – Eugenia caryophyllata Oregano – Origanum vulgare Savory - Satureja montana Thyme – Thymus vulgaris CT thymol Phenols’ Therapeutic Properties have an anti-inflammatory effect on bronchial asthma (see safety considerations). Analgesic Antiseptic Antibacterial Antifungal Antispasmodic Antioxidants Antiviral Rubifacient Stimulant to immune system Warming Safety Considerations Essential oils high in phenols tend to be very irritating to the skin and mucous membranes and should be used with care. Can be used with success when diluted properly. It is recommended to use only at a 1% dilution and used with other skin-nourishing oils to balance your blend. Phenol-rich oils can be irritating to the skin in a bath. Should not be used on individuals with skin issues or dermatitis. Essential oils high in eugenol, thymol or carvacrol inhibits platelet aggregation and should not be used by people with blood clotting disorders or individual anticoagulant drugs such as aspirin or warfarin or before surgery. The shelf life of essential oils containing phenols tends to be three to five years.