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s8pe-30902-ca 12/6/05 4:31 PM MAZER Page 284 Using Coefficients to Balance Equations The balanced equation for the combustion of methane shows that one molecule of methane reacts with two molecules of oxygen to produce one molecule of carbon dioxide and two molecules of water. The equation can be simplified by writing 2O2 instead of O2 + O2, and 2H2O instead of H2O + H2O. The numbers in front of the chemical formulas are called coefficients. Coefficients indicate how many molecules take part in the reaction. If there is no coefficient, then only one molecule of that type takes part in the reaction. The balanced equation, with coefficients, for the combustion of methane is shown below. Balanced Equation with Coefficients reminder A subscript shows the number of atoms in a molecule. If a subscript is changed, the molecule represented by the formula is changed. CH 4 + 2O 2 coefficient CO 2 + 2H 2 O subscript Chemical formulas can have both coefficients and subscripts. In these cases, multiply the two numbers together to find the number of atoms involved in the reaction. For example, two water molecules (2H2O) contain 2 • 2 = 4 hydrogen atoms and 2 • 1 = 2 oxygen atoms. Remember, coefficients in a chemical equation indicate how many molecules of each type take part in the reaction. Only coefficients can be changed in order to balance a chemical equation. Subscripts are part of the chemical formula for reactants or products and cannot be changed to balance an equation. Changing a subscript changes the substance represented by the formula. For example, the equation for the combustion of methane cannot be balanced by changing the formula CO2 to CO. The formula CO2 represents carbon dioxide gas, which animals exhale when they breathe. The formula CO represents carbon monoxide gas, which is a very different compound from CO2. Carbon monoxide gas is poisonous, and breathing too much of it can be fatal. Check Your Reading 284 Unit 3: Chemical Interactions Why are coefficients used to balance equations? The combustion of methane (CH4) is used to melt glass. PDF