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Answer Key to Chem Semester 1 Exam Review Questions (Parts 3 & 4) Pgs. 89-90 1. A. Because all chemical reactions are only the rearrangements of atoms, mass is neither created nor destroyed in such changes. B. Atoms of each element have their own characteristic mass, so compounds consisting of these atoms always have the same composition by mass. C. Only whole atoms combine in chemical compounds, so different compounds between the same two elements must result from the combo of different whole numbers of atoms. 2. 5 mass units; 13 mass units 3. A. the smallest particle of an element that retains the chemical properties of that element B. the nucleus and the surrounding electrons 4. An electron is negatively charged, has a mass approx. 1/2000 that of a H atom, has a fixed charge-to-mass ratio, and is present in atoms of all elements. 5. His model had most of the mass in the nucleus. He bombarded gold atoms with positively charged particles; most went straight through the atom, but some were deflected and a few bounced back. 6. Atomic number 7. A. atoms of an element that have the same number of protons but different number of neutrons B. They have the same number of protons and electrons. C. They have different numbers of neutrons. 8. Isotope Protons Electrons Neutrons Si-28 14 14 14 Si-29 14 14 15 Si-30 14 14 16 9.A. Its number of protons B. the total number of protons and neutrons in an isotope C. atomic = 1; mass = 2 10. any isotope of any element 11. A. helium-4 B. oxygen-16 12. A. carbon-12 B. 12 amu 13. A. 4 amu B. 54 amu C. potassium-39 14. A. the number of particles equal to the number of atoms in 12g of carbon-12 C. 6.022 x 1023 B. mol D. Avogadro’s number 15. A. the mass of one mole of atoms of that element B. 12.01 g/mol, 20.18 g/mol, 55.85 g/mol, 238.03 g/mol 16. A. divide by molar mass B. divide by molar mass, then multiply by Avogadro’s # 17. A. 6.94g B. 27.0g 18. A. 1.000 mol C. 40.1g B. 0.5000 mol D. 55.8g C. 1.57x103mol E. 12.01g F. 107.9g D. 2.81x10-13mol 19. 39.95 amu 20. 10.00 amu 21. A. 9.03x1023 atoms 22. A. 9.500g E. 7.6x10-21g B. 4.068x1024 atoms C. 1.50x1023 atoms C. 2.65x10-10g B. 6.05g D. 1.12x10-3g F. 3x10-22g 23. A. 3.01x1023 atoms D. 7.872x1019 atoms B. 1.51x1023 atoms C. 2.31x1022atoms E. 3.06x1011 atoms Pg. 124 1. Gamma rays, x rays, UV light, visible light, infrared, microwaves, radio waves; 3.00x108 m/s 2. Light’s wavelike properties include frequency and wavelength as well as the ability to interfere and diffract. It’s particle-like properties when it is absorbed and emitted by matter in phenomena such as the photoelectric effect, emission of light by hot objects, and the lineemission spectra of elements. 3. Frequency ranges from approx. 4.29x1014 to 7.50x1014 Hz. Wavelength ranges from 400 – 700 nm. 4. Red, orange, yellow, green, blue, violet 5. The wave theory could not explain the photoelectric effect of hydrogen’s line-emission spectrum. 6. A. c = λv; λ is wavelength and v is frequency and c is velocity B. E = hv; E is energy, h is Planck’s constant, and v is frequency C. E = hc/λ 7. A. wave theory B. particle theory C. particle theory 8. The ground state of an atom is the lowest energy state. An excited state of an atom is any energy state that is higher in energy than the atom’s ground state is. 9. a line-emission spectrum is produced when an electron drops from a higher-energy orbit to a lowerenergy orbit, emitting a photon. The photon’s energy is equal to the difference in energy between the two levels. 10. 7.05 x 1016 Hz 11. 2.35 x 10-16 J 12. E = hc/λ 13. 267s 14. 1.99 x 10-13 J