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Name_______________________________________Date__________________________Period__________ Pre-AP Chemistry Exam 4 Matching Match each item with the correct statement below. a. atomic orbital d. ground state b. aufbau principle e. Pauli exclusion principle c. electron configuration f. Heisenberg uncertainty principle ____ ____ ____ ____ ____ ____ 1. 2. 3. 4. 5. 6. region of high probability of finding an electron states the impossibility of knowing both velocity and position of a moving particle at the same time lowest energy level tendency of electrons to enter orbitals of lowest energy first arrangement of electrons around atomic nucleus each orbital has at most two electrons Match each item with the correct statement below. a. atomic emission spectrum d. photon b. frequency e. quantum c. wavelength f. spectrum ____ 7. discrete bundle of electromagnetic energy ____ 8. energy needed to move an electron from one energy level to another ____ 9. number of wave cycles passing a point per unit of time ____ 10. distance between wave crests ____ 11. separation of light into different wavelengths ____ 12. frequencies of light emitted by an element Match each item with the correct statement below. a. electronegativity f. b. ionization energy g. c. atomic radius h. d. metal i. e. transition metal j. ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. periodic law cation period group electrons horizontal row in the periodic table vertical column in the periodic table A repetition of properties occurs when elements are arranged in order of increasing atomic number. type of element that is a good conductor of heat and electric current type of element characterized by the presence of electrons in the d orbital one-half the distance between the nuclei of two atoms when the atoms are joined type of ion formed by Group 2A elements subatomic particles that are transferred to form positive and negative ions ability of an atom to attract electrons when the atom is in a compound energy required to remove an electron from an atom Multiple Choice 1 Name_______________________________________Date__________________________Period__________ Identify the letter of the choice that best completes the statement or answers the question. ____ 23. What is the name given to the electrons in the highest occupied energy level of an atom? a. orbital electrons c. anions b. valence electrons d. cations ____ 24. The octet rule states that, in chemical compounds, atoms tend to have ____. a. the electron configuration of a noble gas b. more protons than electrons c. eight electrons in their principal energy level d. more electrons than protons ____ 25. What is the electron configuration of the oxide ion (O )? a. 1s 2s 2p c. 1s 2s b. 1s 2s 2p d. 1s 2s 2p ____ 26. Under what conditions can potassium bromide conduct electricity? a. only when melted b. only when dissolved c. only when it is in crystal form d. only when melted or dissolved in water ____ 27. Which of the following is NOT a characteristic of most ionic compounds? a. They are solids. b. They have low melting points. c. When melted, they conduct an electric current. d. They are composed of metallic and nonmetallic elements. ____ 28. An ionic bond is a bond between ____. a. a cation and an anion c. the ions of two different metals b. valence electrons and cations d. the ions of two different nonmetals ____ 29. Why do atoms share electrons in covalent bonds? a. to become ions and attract each other b. to attain a noble-gas electron configuration c. to become more polar d. to increase their atomic numbers ____ 30. Which of the following is the name given to the pairs of valence electrons that do not participate in bonding in diatomic oxygen molecules? a. unvalenced pair c. inner pair b. outer pair d. unshared pair ____ 31. Each period in the periodic table corresponds to ____. a. a principal energy level c. an orbital b. an energy sublevel d. a suborbital ____ 32. To what category of elements does an element belong if it is a poor conductor of electricity? a. transition elements c. nonmetals b. metalloids d. metals ____ 33. Atomic size generally ____. a. increases as you move from left to right across a period b. decreases as you move from top to bottom within a group c. remains constant within a period d. decreases as you move from left to right across a period ____ 34. Which of the following elements has the smallest first ionization energy? 2 Name_______________________________________Date__________________________Period__________ a. sodium c. potassium b. calcium d. magnesium ____ 35. Which of the following elements has the lowest electronegativity? a. lithium c. bromine b. carbon d. fluorine ____ 36. Which of the following statements correctly compares the relative size of an ion to its neutral atom? a. The radius of an anion is greater than the radius of its neutral atom. b. The radius of an anion is identical to the radius of its neutral atom. c. The radius of a cation is greater than the radius of its neutral atom. d. The radius of a cation is identical to the radius of its neutral atom. Short Answer 37. Give the electron configuration for a neutral atom of selenium, (34Se). 38. Draw an orbital diagram showing all the electrons as arrows in a neutral atom of phosphorous. Don’t forget to label your boxes with the appropiate sublevels. 39. Draw a Lewis structure (electron dot structure) for the oxygen atom. 40. Draw a Lewis structure for methane (CH4). 41. Which group in the periodic table is known as the noble gases? 3 Name_______________________________________Date__________________________Period__________ 42. Is nitrogen a metal or nonmetal? What group is it in? What charge will nitrogen have when it becomes an ion? Numeric Response 43. How many electrons are in the highest occupied energy level of a neutral chlorine atom? 44. How many unpaired electrons are in there in a neutral nitrogen atom? 45. What is the charge of a particle having 9 protons and 10 electrons? 46. How many electrons are shared in a single covalent bond? 47. How many unshared pairs of electrons does the oxygen atom in water (H2O) possess? 48. How many electrons are shared in a double covalent bond? 49. How many electrons are there in the highest occupied energy level of atoms in Group 5A elements? Essay 50. Describe the trends in the atomic size of elements within groups and across periods in the periodic table. Provide examples. 4 Name_______________________________________Date__________________________Period__________ Pre-AP Chemistry Exam 4 Answer Section MATCHING 1. ANS: A 2. ANS: F 3. ANS: D 4. ANS: B 5. ANS: C 6. ANS: E 7. ANS: D 8. ANS: E 9. ANS: B 10. ANS: C 11. ANS: F 12. ANS: A 13. ANS: H 14. ANS: I 15. ANS: F 16. ANS: D 17. ANS: E 18. ANS: C 19. ANS: G 20. ANS: J 21. ANS: A 22. ANS: B MULTIPLE CHOICE 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: B A B D B A B D A C D C A A 5 Name_______________________________________Date__________________________Period__________ SHORT ANSWER 37. ANS: 1s 2s 2p 3s 3p 3d 4s 4p 38. ANS: 1s2 2s2 2p6 3s2 3p6 39. ANS: The chemical symbol for oxygen with two single dots in two quadrants and two pairs of dots in two quadrants. Six dots total. 40. ANS: Carbon with one hydrogen in each of carbons quadrants. One line is used to connect each hydrogen to carbon. 41. ANS: 8A 42. ANS: nonmetal, 5A, 3NUMERIC RESPONSE 43. ANS: 7 44. ANS: 3 45. ANS: 1 46. ANS: 2 6 Name_______________________________________Date__________________________Period__________ 47. ANS: 2 48. ANS: 4 49. ANS: 5 ESSAY 50. ANS: Atomic size increases with increasing atomic number within a group. For example, sodium atoms are larger than lithium atoms, and potassium atoms are larger than sodium atoms. Atomic size decreases with increasing atomic number across a period. For example, lithium atoms are larger than beryllium atoms, and beryllium atoms are larger than boron atoms. 7