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For NERC use: SME No. 145 PS Lucy Carpenter Natural Environment Research Council Ship-time & Marine Equipment Application form (SME) NOTES: 1. NERC’s marine facilities programme is planned on the basis of the calendar year. This form MUST be submitted by 1st April of the preceding year to be considered for inclusion in this programme. Submissions after this date will be carried forward to the subsequent year, unless they can be satisfied on an opportunistic basis. 2. This form should be submitted electronically to Dr Helen Beadman ([email protected]), NERC, Polaris House, Swindon SN2 1EU. [NB. Core-strategic applications should be backed up by a hard copy (with the necessary approval signed at Part 3)] 3. This form is NOT an application for research and ‘superstructure’ funding, which must be applied for separately. Unless this is being provided from an external source, such as a commissioned research customer or the EU, an application for NERC funding should be submitted to the relevant Peer Review Committee. The NERC policy on the allocation of ‘superstructure’ costs to grant proposals in the non-thematic and thematic modes can be found at: http://www.nerc.ac.uk/funding/marineplan/. 4. All SME applications will be acknowledged by email on receipt by NERC. Contacts: Dr Mike Webb, NERC, Swindon Head Office Tel : 01793 411520 Fax : 01793 411545 E-mail : [email protected] Chris Hindley, Ops Manager, British Antarctic Survey (BAS) Tel : 01223 221497 Fax : 01223 362616 E-mail : [email protected] Dr Helen Beadman, NERC, Swindon Head Office Tel : 01793 411513 Fax : 01793 411545 E-mail : [email protected] Geraint West, Hd UK Ocean Research Services (UKORS) Tel :023 80596147 Fax :023 80596267 E-mail : [email protected] Colin Day, Ops Manager, UK Ocean Research Services (UKORS) Tel : 023 80596109 Fax : 023 80596267 E-mail : [email protected] Andrew Louch, Ops Manager, Research Ship Unit (RSU) Tel : 023 80596472 Fax : 023 8059 8063/5130 E-mail : [email protected] SME Version 03/05 1 SME No. PART 1 General Particulars SECTION A Applicants Details A.1 Principal Scientist’s Details [ONE ONLY PER CRUISE] Name Dr Lucy Carpenter (on behalf of PI of RHaMBLe, Dr Gordon McFiggans) Address Dept of Chemistry, University of York Telephone No 01904 434588 Fax No 01904 432516 E-mail [email protected] A.2 Title of Project Reactive Halogens in the Marine Boundary Layer – (RHaMBLe) A.3 Duration Is this application for a cruise or cruises in 2007 only or for cruises spanning more than one year (2007 onwards)? 2007 only A.4 Description of research project Please paste below a detailed two-page description of the research project to be carried out during the cruise, including a programme of activities and a cruise track within the science area. This description will be used for programming purposes and, for programmed cruises; the description will be displayed on the NERC marine planning web site. Where a research grant is also being applied for, the supporting science case for the research grant application is acceptable and should be pasted below. Programme description: Introduction: RHaMBLe is an integrated programme aiming to quantify impacts of marine halogen emissions on atmospheric composition by the direct observation of a range of reactive halogen species (RHS) in the marine atmosphere. Emphasis is placed on the roles of halogens in oxidative processes and on secondary SME Version 03/05 2 SME No. aerosol formation and transformations resulting from the cycling of RHS. RHaMBLe will extensively link to UK and Internationally funded programmes to provide a package within UK SOLAS to link oceanic fluxes to atmospheric impacts. The recent focus of marine boundary layer halogen research has been on two atmospheric implications: i) participation of reactive halogen species in catalytic ozone destruction cycles including heterogeneous reaction in or on seasalt aerosol and ii) the formation of new aerosol particles in the coastal boundary layer and their potential to act as cloud condensation nuclei (CCN). RHaMBLe will develop both closely related areas of SOLAS science. RHaMBLe will use a targeted combination of open ocean and coastal field deployments. Two open ocean deployments will link with long-term studies in the tropical Atlantic Ocean on Sao Vicente in the Cape Verde Islands: i) an intensive campaign and supplementation of the continuous measurements already funded at Cape Verde and ii) a simultaneous ship transect through the biologically-active upwelling region west of Mauritania. These will provide possibly the most comprehensive characterisation of halogen compounds in the marine atmosphere to date, including both organic and inorganic reactive species and providing substantial spatial and temporal coverage. A coastal field project is planned to provide direct observational linkage between new particle formation and RHS, to enable development of a usable parameterisation for use in large-scale models. This investigation will use largely the same observational techniques and personnel as the open ocean deployments. RHaMBLe will interact bi-directionally with a range of funded activities to contribute to both integrated biological production and atmospheric chemical process understanding (as explained in the Project Management section). The interactions within this cluster of activities will ensure that measurements made within RHaMBLe are used optimally to contribute to the quantification of the effects of marine halogens. Specific Objectives: i) to quantify the spatial and temporal variability of RHS in the tropical and sub-tropical Atlantic, to assess the cycling mechanisms of reactive halogens in the marine atmosphere and hence quantify the regional and global effect on oxidative chemistry through perturbation of the HOx and NOx cycles, coupling to the sulphur cycle and the effect on ozone and on aqueous oxidation. ii) to describe the formation and growth mechanisms and assess the regional importance of iodinecontaining particles recently formed in the coastal and remote marine boundary layers and compare this with predicted contributions due to DMS oxidation. Detailed description of research cruise: Aims: The cruise will address a number of key scientific questions required to determine the global importance of iodine chemistry and to further our understanding of the controls of halogen chemistry in the remote ocean. It will quantify marine halocarbon emission variability and latitudinal variation, characterise in situ open ocean atmospheric reactive iodine latitudinal variability and characterise oxidative chemistry perturbation due to oceanic emission of halogens from the Mauritanian upwelling region. Specifically, the following science questions will be addressed: i) How heterogeneous are the direct halogen sources and on what scale is the heterogeneity – does the upwelling region produce more or less halogens than the “background” region? ii) What are the relative contributions of I atoms to the remote MBL from I2 and organic iodine? SME Version 03/05 3 SME No. iii) Is sufficient iodine released to the remote MBL to sustain aerosol nucleation or to significantly affect the ozone budget and free radical populations? Study Area: The target area for survey is the NW African upwelling off Cap Blanc in Mauritania, between approximately 16-22oN and 16-21oW, NNE of Cape Verde. We will take advice from the SOLAS project of Robinson (PML) as to the peak position and structure of the upwelling, which they will map out in May-June 2006. The upwelling maxima in this region occur between April and June and minima between July and September. We also require broad surface flow connection between Cape Verde and the peak upwelling region (21-22oN), and air trajectories that are not contaminated by the NW African coast. Such trajectories also occur from April to June, thus we request shiptime ideally in May 2007, embarking from Mindelo, Sao Vicente, Cape Verde (with a 3 day mobilization period) . Instrumentation to be deployed: This will be largely an atmospheric chemistry cruise. Measured species include a variety of halocarbons in both surface seawater and atmosphere by GC-MS, and tropospheric measurements of I2, OIO and IO by Broadband Cavity Enhanced Absorption Spectroscopy (BBCEAS). A compact version of the FAGE system, developed for the FAAM BAe-146, will be deployed to provide measurements of IO or OH / HO2, permitting direct assessment of RHS-induced changes in the oxidising environment through the upwelling region. A range of trace gas monitors will be simultaneously deployed on the ship to measure O3, NOx and CO. Aerosol number and size distribution measurements from 3 nm to 20 µm will be made by a range of mobility (SMPS) and optical instrumentation, (OPC and FSSP). Cruise track: After a transect to the upwelling region from Cape Verde, the first goal of the cruise will be to survey the broad area of the upwelling region. Daily processed MODIS ocean colour and sea surface temperature imagery (it is envisaged that this analysis will be carried out daily by RSDAS/PML and forwarded to the ship) will provide a guide to the upwelled (cold) water, informing the identification of major upwelling regions. We request a 10-day period to survey the broad area of the upwelling region (envisaged to be between approximately 18-22oN and 16-21oW – but to be informed by the SOLAS upwelling cruise of Robinson). The survey could either be in uniformly-spaced diagonal transects, or could concentrate on sampling in and out of the upwelling regions. We again will be informed by previous studies and will discuss these issues in detail during a cruise planning workshop in late 2006. Ideally, we would then transect back to the UK via the Bay of Biscay (in ~ 6-8 days), providing information on the variability of source regions. (a) (b) Fig 1. (a) Air-mass back trajectory foot-print analyses produced for the Cape Verde region. Proposed survey area (red outlined square) and transects (red line). SME Version 03/05 4 SME No. (b) SECTION B Logistics B.1 Cruise working area Lat(s) 16-22oN Long(s) 16-24oW Please paste below a map/chart showing scientific area and proposed cruise track. See section above B.2 Cruise timing Month(s) of the year preferred: May Month(s) of the year acceptable: April-June Please state exactly what your time constraints are: B.3 • Upwelling • Trajectories/connected flow/avoidance of dust events • Link up with measurements Cape Verde intensive Cruise period Preferred number of science days (excluding passage to and from the working area) 11 Minimum number of science days acceptable (excluding passage) 8 Please indicate how many of these science days are for contingencies: 1 N.B. We require a 3 day mobilization period at the embarkation point (Mindelo) for set-up of instrumentation and we will continue to make underway measurements on the passage leg to the UK. SME Version 03/05 5 SME No. B.4 Number of berths required See section PART 2 SECTION D below regarding UKORS manning and training berths See guidance notes for additional information on UKORS support personnel Preferred number of berths (exclusive of UKORS technical support) 9 (excl. international collaboration ) Minimum number of berths acceptable (exclusive of UKORS technical support) 8 (excl. international collaboration ) B.5 Request for specific research ship See guidance notes (and the NERC marine planning web site) for details of barter arrangements on IFREMER (France), BMBF (Germany) or NSF (USA) research ships RRS Discovery acceptable RRS Charles Darwin RRS James Clark Ross first preference RV Prince Madog Charter ship Barter ship RV Poseidon also acceptable Please state exactly what your JCR appears to fit in very well with planned schedule reasons are for specifying the ship(s): PART 2 SME Version 03/05 6 SME No. Technical Requirements SECTION C Equipment Please indicate ‘Y’ in the relevant boxes below for equipment required for your cruise. Please contact the UKORS Operations Manager for further details if required. C.1 Yes UKORS National Marine Equipment Pool Main categories of equipment within the UKORS National Marine Equipment Pool available for cruise operations. 1.1Radionuclide laboratory container 1.1 Clean chemistry laboratory container 1.1 General purpose chemistry laboratory container 1.2 Bolt 1500LL seismic airguns 1.2 Multi-channel seismic systems 1.2 Seismic air compressor systems (containerised) 1.3 Sub-bottom profiler (3.5 kHz echo sounder) [see ship fitted section below] 1.4 Towed Ocean Bottom Instrument (TOBI) 1.5 CTD / rosette sampler systems 1.6 Moorings & mooring instrumentation [complete section D2] 1.7 Seasoar system 1.8 Mini box corer (200mm square box) 1.8 Standard piston core system 1.8 Long piston core system 1.8 NIOZ box corer (500mm square box) 1.8 SMBA box corer: stainless steel (500mm square box) 1.8 SMBA box corer: mild steel (500mm square box) 1.8 Kasten corer 1.8 Day grab 1.8 Shipek grab 1.9 XBT operations 1.10 Agassiz trawl systems 1.10 OTSB trawl systems SME Version 03/05 7 SME No. C.1 Yes UKORS National Marine Equipment Pool Main categories of equipment within the UKORS National Marine Equipment Pool available for cruise operations. 1.11 Seabed dredging 1.12 Stand Alone Pumps (SAP) 1.13 Laboratory fume hood 1.13 Laboratory laminar flow hoods 1.14 Laboratory hydrogen gas generators 1.14 Laboratory pure air gas generators 1.14 Laboratory nitrogen gas generators 1.15 Laboratory liquid nitrogen generator Y 1.16 Laboratory pure water system (Millipore) Y 1.17 -70 degree centigrade freezer Y 1.17 -20 degree centigrade freezer Y 1.17 Refrigerators Y 1.17 Ice making machine Y 1.18 Gas bottle storage racks Y 1.19 Echo sounder 10kHz (10/12 kHz fish and hull mounted system) 1.20 ‘Waterfall’ monitoring equipment 1.6 McLane moored profiling CTD systems Moving Vessel Profiler (MVP300) SC ADCP RDI WH long ranger (75kHz) SC ADCP RDI WH sentinel 6000m (300/600kHz) SC ADCP RDI WH monitor 500m (1200kHz) L ADCP RDI WH monitor 6000m (300kHz) L ADCP RDI narrow band (150kHz) CI FASTRACKA FRRF Long Base Line navigation system (LBL) DARTCOM satellite imaging system Salinometer SME Version 03/05 8 SME No. C.2 Electronic Communications RRS Discovery and RRS Charles Darwin operate a communications schedule for electronic transfer capable of supporting a high-speed (64 kbaud) link to the Internet. The links are available to the scientific party via subscription to cover costs external to RSU for the use of INMARSAT. Applicants should budget for a supplementary charge of £25 per cruise day for the Principal Scientist’s Scientific Main Account, to be billed prior to commencement of the cruise. Scientific/Business Accounts each, at a supplementary charge of £4 per cruise day is available to individuals of the scientific party to conduct business not associated with the research cruise. This supplementary charge will be billed and collected on board the ship. Regarding the transfer of data and satellite images, should your project require significant connection time or additional connections to the standard schedule, it will be necessary for you to allocate specific funds to this aspect of the project. The additional charges will be accounted and settled on board. For further advice please contact UKORS. Do you intend transferring data, satellite images or software? C.3 Yes Additional supplied equipment (Non-UKORS Pool Equipment) Please itemise below the main items of equipment outside the UKORS equipment pool to be used during the cruise (i.e. over-side equipment, laboratory equipment, specialist containers etc). Please state the source of the equipment. Please include owner-supplied equipment. (If possible, please comment on size, weight, power requirements, installed location on the ship and brief deployment details) Equipment details SME Version 03/05 Institute/organisation owning the equipment 9 SME No. C.4 Ship-fitted Scientific Equipment Item availability on ship Equipment RRS Discovery RV Prince Madog RRS Charles Darwin RRS James Clark Ross Available Available Is this item requested? Seismic air compressor / delivery systems Available Computing systems [scientific data acquisition] Available Available Available Available Y Pumped sea water sampling system [from 6m depth] Available Available Available Available Y Sea surface monitoring system [sal., temp., fluor., trans.] Available Available Available Available Y Meteorology monitoring package Available Available Available Available Y 150 kHz hull mounted ADCP system Available Available Available 75 kHz hull mounted ADCP system Available 300 kHz hull mounted ADCP system Available Ultra Short Base Line acoustic navigation Available Hull mounted wave height recorders Available Available Available Y? SIMRAD EM12 Swath Bathymetry system Available SIMRAD EM120 Swath Bathymetry system Available SIMRAD EK500 Echo sounder Available SIMRAD EK60 Echo sounder Available DPS Available SME Version 03/05 10 SME No. C.5 Mooring and drifting buoys: design and deployment details. In order to establish an outline mooring design for the planning and costing exercises please provide the following information. Please give as much detail as is available at the time. Scientific objective; description of mooring measuring criteria. Sensors proposed + sensor ranges / resolutions. Sensor depths (depths from surface or heights off bottom). Duration of mooring deployment. Geographical location of mooring deployment. Details of topography at mooring site. Details of current profile extremes. Is Argos mooring monitoring required? Budgetary constraints to be applied to mooring design. Please state proposed recovery ship. Please paste below a sketch layout with bathymetry. Please add any further comments as required: No moorings required SME Version 03/05 11 SME No. C.6 Additional Facilities In addition to research ships, UKORS technicians and NMEP equipment, NERC provides a range of facilities to support environmental research (see ‘NERC Services & Facilities’ website for further information) and NERC has access to a number of marine facilities via the barter arrangements with IFREMER (France), BMBF (Germany) & NSF (USA) (see the NERC marine planning website for more information). Please indicate below which, if any, of the additional facilities you may require to support the research, should the cruise be programmed. Comments: SME Version 03/05 12 SME No. SECTION D Technical Support Staff D.1 UK Ocean Research Services (UKORS) Responsibilities Mobilisation – Preparation of the ship for a science cruise - this involves locating, installing, setting up and testing the equipment for a forthcoming cruise, and may take 2-7 days, depending on the equipment required. Operation - Operation and supervision of deployment of all scientific equipment detailed in C.1 (NMEP Equipment) and also responsible (including calibration) for all item listed as ship-fitted equipment available onboard RRS Discovery and RRS Charles Darwin in table C.4. In addition UKORS are also currently responsible for the following fitted items of handling equipment onboard these ships: Deck hydraulics / powerpacks Gantry systems Scientific cranes Ship fitted winch systems Responsibility for operation of these items is currently being handed over to the Research Ship Unit, and you should consult with the UKORS Operations Manager for the current status of this. Repair and Maintenance - General fault finding, repair of defective equipment and on-going daily maintenance of equipment as defined in the paragraph above: again RSU are in the process of assuming responsibility for fitted handling equipment. Allocation of Engineering Staff During the cruise planning process, the number and skills balance of UKORS staff allocated to cruise support from the three engineering disciplines, together with the level of RSU Marine support staff will be determined by assessing the cruise activities and workload. Because of this it is critical that applicants discuss manning requirements with UKORS when completing this form. In particular, certain operations may require significantly increased manning levels: Multi-channel seismics Giant (Long) Piston Corer EM12 Swath Bathymetry Training Where possible, NERC’s Research Vessels Advisory Panel would like to develop the principal of providing training berths on board NERC ships for UKORS technicians. If there are spare berths available during your cruise please give serious consideration to this request. There will be no additional charges for this extra technical support. If the offer can be taken up by UKORS, the training berth may be to your advantage as you could gain an extra pair of technical hands. However the technician may be a novice, and should therefore not be regarded as capable of working without supervision. If a trainee is catered for during your cruise, the work activities and hours of UKORS technical staff must be assessed disregarding any additional trainee berths. Are berths available during your cruise for use by a UKORS trainee technician? SME Version 03/05 13 Yes SME No. D.2 British Antarctic Survey (BAS) This guidance only applies to NERC-funded sea days and not BAS core science or AFI, which are addressed separately. Unless otherwise agreed, BAS technicians must be employed if BAS equipment is to be used. A maximum of 2 x BAS technicians (ITS/ETS) are included in the daily rate for the RRS James Clark Ross. Additional staff can be provided at agreed rates, subject to availability. SME Version 03/05 14 SME No. PART 3 Funding and Approval SECTION E Funding Only complete questions in this section as appropriate to your project. E.1 Existing Research Grant Is this application directly related to an existing thematic/non-thematic research grant? If ‘yes’, please indicate grant number and the approximate level of funding that you have to cover ‘superstructure’ costs (if known): If ‘no’, is a new research grant covering the full funding of research and ship ‘superstructure’ costs being applied for together with this application? E.2 Core Funding Is NERC core funding providing all of the funds to cover the science and the ‘superstructure’ support costs associated with this application form? If ‘yes’, please state programme title and the approximate level of funding that you have to cover ‘superstructure’ costs: YES – SOLAS (RHaMBLe). But no superstructure costs expected. If ‘no’, please state the way in which the costs are to be attributed. Please also confirm that agreement for this joint arrangement has been obtained from all sources: E.3 Commissioned Research Please state the name of the commissioned research customer(s)? If you are bidding for ‘free at the point of use’ access to NERC’s marine facilities, please confirm that all data collected using these facilities can be freely used for scientific research: Please state the level of funding that you have to cover ‘superstructure’ costs: SME Version 03/05 15 SME No. E.4 Funding from a non-NERC Peer Reviewed Source Is this application directly related to an existing award from a non-NERC peer reviewed source (e.g., EU, NSF)? If ‘yes’, please state the grant number and the level of funding that you have to cover ‘superstructure’ costs: If ‘no’, please indicate if the grant proposal that’s being applied for together with this application covers the full funding of research and ship ‘superstructure’ costs, and the date when you expect to know if funding has been secured: E.5 Additional funding sources If none of the above (sections E1 - E4) applies, please indicate the source of the full funding for research and ship ‘superstructure’ costs: SECTION F SME Version 03/05 16 SME No. Approval F.1 Approval for a NERC core-strategic science cruise Director’s name: I confirm that this SME application form is for scientific research that is part of a NERC core-strategic programme Date: Signature: Additional comments (if any): SME Version 03/05 17 SME No.