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Masonry Stone, Brick, Concrete, Terracotta, Adobe, Tabby [Plaster & Stucco] STONE Oldest building material Simplest building technique — stacked stone Most expensive – Traditionally, large public buildings built of stone – Less often used for residential buildings, except for facing or decoration. The high cost of transporting stone meant that it was advisable to use local stone Egypt’s first pyramids ca. 3000 BCE. Built mostly from limestone; other stones used on interior. Sphinx, ca. 2500 BCE. Carved out of limestone outcrop. Granite facing applied later. Great Wall of China, 7th6th Centuries, BCE Sandstone, rammed earth, brick Longest human-made structure, approx. 3,948 miles Parthenon, Athens, Greece, 447-432 BCE. Marble and limestone Colosseum, Rome Vespasian, 70-82 CE Concrete and tufa faced with travertine Taj Mahal Agra, India 1630-1653 Marble How to Distinguish Rocks Lightness / Darkness Coarseness / Fineness – Are the grains visible? Rhyolite Gabbro Basalt Granite “Granite” Countertops? Marketing claims aside, these countertops are andesite How not to Distinguish Rocks Not by color: color often comes from impurities in the rock – Greens — chlorites, magnesium – Reds — iron oxides, esp. hematite (iron ore) – Yellows/tans — hydrated iron oxides Chlorite Iron Ore Limonite Igneous — rock deposited in a molten state Plutonic — formed deep beneath earth’s surface, when magma cools & hardens – Granite (light); diorite (dark); gabbro (very dark, mistakenly called black granite) – Granite: “grain”-y, non-porous, light colored (gray to pink), hard, durable, scratch- and chemical-resistant, takes a variety of finishes, low thermal expansion, can be used in contact with the ground or exposed to severe weathering Volcanic — formed close to the earth’s surface when lava cools & hardens – Rhyolite, andesite, basalt, pumice, tuff – Not often used for building in U.S. — few volcanoes Boston Public Library Pink granite; 1888-1895; McKim, Mead & White Rhodes Hall — 1516 Peachtree Street NW; Stone Mtn. granite and Lithonia gneiss; 1904; W. F. Denny, II Stone Mountain, GA, ca. 1916 Sedimentary — rock deposited on the earth’s surface by the action of wind and water Anisotropic – directionally dependent – Specific bedding planes – Sandstone and limestone are examples Sandstone Crossbeds 1st Sedimentary Rock Type Carbonates: CaCO3 and Mg(CO3)2 – Composed of carbonate minerals which precipitate out of supersaturated waters, or are formed when the water evaporates – Limestone, travertine, tufa are precipitates – Oolitic limestone, gypsum are evaporates – Porous; will not accept a high polish; soluble in acid; very absorbent and susceptible to staining not usually in contact with soil Tufa — Ostia, 1st century BCE Travertine — LA, 1984-1997 Tufa Towers, Mono Lake, CA “Tufa” – a sedimentary rock... Not to be confused with “Tuff” – an igneous rock Tuff buildings, Kirkland, AZ, ca. early 1900s Tuff columns, Pompeii forum, pre-79 CE Georgia Capitol — Atlanta; Indiana oolitic limestone; 1889; Edbrooke & Burnham Manufacturer and Builder, XIX, 11 (Nov. 1887), 253. Georgia Capitol, West Exterior Stairs 2nd Sedimentary Rock Type Silicates: SiO2 (quartz) + Fe2O3 or CaCO3 – Composed primarily of silicate minerals transported by moving fluids, and were deposited when the fluids came to rest – Sandstone (brownstone & bluestone are colored sandstones) – Highly stratified, durable good for paving, sills, hearths, mantels, copings Mount Airy, Warsaw, Virginia, 1758; dark brown sandstone, trimmed in light-colored sandstone, projecting limestone pavilion; John Ariss (?) Connecticut brownstone used to build the New York Brownstones Bluestone — used for coping and flagging Metamorphic Rock — formerly igneous or sedimentary rock, transformed by heat and/or pressure Three Main Types: Gneiss, Slate, Marble Types of Metamorphic Rocks –Gneiss: formed from igneous or sedimentary rocks Very hard Good for foundations, walls, & other loadbearing applications –Slate –Marble Peachtree Center MARTA Station — carved out of solid gneiss Granite vs. Gneiss Granite is a plutonic igneous rock. Its crystals form differentially upon cooling deep in the earth's crust. Granite’s visible crystals are randomly arranged. Gneiss is a metamorphic rock that shows obvious banding of light and dark minerals resulting from recrystallization of the original material due to high heat and pressure. If you can discern a pattern, it's not granite! Arabia Mtn. gneiss among the granite Arabia Mountain Migmatitic Gneiss “Tidal Gray” Atlanta Area Rock Outcrops georgiarocks.us Distribution of Granites & Gneisses in Georgia from quarriesandbeyond.org Types of Metamorphic Rocks –Gneiss –Slate: formed from shale (sedimentary rock) Very dense and hard Good for paving stones, roof shingles, water courses, and countertops –Marble Slate Pentagon, Arlington, VA, ca. 1943, George Bergstrom September 11, 2001 attack destroyed more than an acre of the slate roof. Slatebearing formations in Georgia Types of Metamorphic Rocks – Gneiss – Slate – Marble: recrystallized limestones (sedimentary), easily carved and polished Carrera and Vermont marble — grains are smaller, more porous, metamorphic process did not go as far, chisel can go through it cleanly finely detailed carving, more susceptible to deterioration, especially granular disintegration Georgia marble — larger grained, stronger, used as foundation stone Candler Building 127 Peachtree Street NE; 1906; George E. Murphy, architect; F. B. Miles, sculptor; Georgia marble from the Amicalola quarries in Pickens County Distribution of Marble in Northwest Georgia Igneous or Sedimentary Rock Type Metamorphic Rock Type Almost any rock subjected to high-grade (high heat and pressure) regional metamorphism Gneiss Sandstone (Sedimentary) Quartzite Limestone (Sedimentary) Marble Shale (Sedimentary) Slate Basalt (Igneous) Greenstone Forms of Stone Naturally occurring or human-made Fieldstone — from riverbeds or fields Flagstone — thin slabs used for flooring, paving (stones split on a bedding plane) Rubble — irregular quarried fragments, unsquared Dimension stone — quarried and cut into rectangles – Cut stone: large slabs – Ashlar: smaller, rectangular blocks Fieldstone Flagstone Bluestone — a colored sandstone popular for flagging Rubble (unsquared) Coursed = continuous horizontal lines Uncoursed = discontinuous; no horizontal lines Ashlar (squared) Courses and Wythes Load-bearing Weight of upper floors supported by walls of lower floors Interior spaces smaller on lower floors Arches, vaults, domes opened up space, reduced weight Limited height due to volume and mass necessary to support the building Veneer Skeletal framing system supports building – Wood – Metal (steel) – Reinforced concrete Masonry veneer Taller buildings possible By early 1900s, most stone and brick buildings in the U.S. were veneer Monadnock Building; Chicago; unreinforced brick; 16 stories; 1891, Burnham & Root 18” 6 ft. Expensive ashlar face (veneer) over inexpensive brick or rubble wall (wall section diagrams) More veneer examples Dressed stone over poured concrete Concrete block over steel I-beam Modern ties Stone over concrete masonry units (CMUs) Thin stone veneer over wood framing What is the error in the labelling? Thin stone veneer over wood framing Stone Finishes Tooth chiseled Point chiseled Rock faced Broached Drove Crandalled More Stone Finishes Vermiculated Rusticated Bush hammer Bush hammered Wire sawn Washington Hall, U.S. Military Academy, West Point, NY; gneiss Modes of Deterioration Solution Weathering Acid Rain Salt Weathering Dry Deposition Freeze-Thaw Cycle Hygric Swelling Thermal Effects Biological Effects Solution Weathering Occurs when soluble chemicals in stones dissolve in rainwater and get washed off and re-deposited elsewhere Occurs naturally when rain falls – Rainwater is a weak carbonic acid formed by the reaction of CO2 with atmospheric moisture – Carbonic acid can dissolve calcium carbonate (primary component of limestones and marbles) In polluted environment, rainfall acidity is increased & solutional activity intensifies Solution Weathering, cont. Marble headstone with lead lettering, 130 years old. Rainwater (carbonic acid) washes unevenly over the surface, causing pitting and wave-like deterioration patterns in the marble. The lead letters, originally even with the stone surface, now are “raised”, indicating how much stone surface has been lost. Acid Rain Mostly sulfur dioxides and nitrous oxides Creates gypsum (hydrated calcium sulfate) on building surfaces Loss of material—gets washed off and redeposited somewhere else Acid Rain & Solution Weathering Processes 1. Rainwater - naturally composed of carbonic acid formed by Rx of CO2 with atmospheric moisture 2. Calcium carbonate is soluble in carbonic acid 3. Sulfur oxides in atmospheric pollution + water in the air form sulfuric acid. When it “rains” on stone containing CaCO3, it forms gypsum Salt Weathering Every salt has its own relative humidity equilibrium point. Depending on the surrounding RH, the solution of salt can give up its water, forming salt crystals, which can split rock. Marine environments De-icing salts Salt contained in Portland cement—alkalis can migrate into the surrounding stone Dry Deposition Occurs on carbonate rocks (e.g., limestone, marble) constantly Fly ash and sulfur dioxide in the air captured by the moisture that is always present in the stone formation of a crust Occurs more often in winter – More particulates in the air – Greater temperature differential more condensation, so the wet stone captures more particulates Freeze-Thaw Cycle More porous stones are more affected (e.g., limestone more susceptible than granite) Water experiences 10% volume increase when it goes from liquid to solid (freezes) Stonework should be laid on the quarry bed (grain running horizontally) because stone is stronger and more weatherresistant in that orientation. Photo courtesy of Ben Sutton, 2014 Hygric Swelling Clay swells when it gets wet; differential strain between wet and dry areas causes deformation, stress, cracking Sedimentary rocks more susceptible: weaker mechanically, more porous, have layers, contain clay Bio-deterioration Physical and chemical processes Bacteria, algae, and fungi — cause mostly chemical effects; have a specialist identify these Lichens — chemical and physical effects; can tear away surface of rock; hard to clean Mosses — mostly physical effects; easier to remove than lichens Higher Plants — can damage surface and retain moisture Algae growth on sandstone Lichen growth on stone wall Plant-covered brick building Thermal Effects Coefficient of linear thermal expansion = rate at which mineral expands with increasing temperature Stone temperature can vary between 30%-50% higher than air temperature Darker stones absorb more heat and give it up more readily Daily and seasonal heating cause stress and micro-fractures in and along mineral grains, eventually producing flaking Mable is particularly susceptive to thermal effects Creep or drift — building expands during day but does not fully contract at night Before cleaning or repairing stone: Know what the stone is, and its source Understand the nature of the stone: grain, chemical composition, crystal structure, water solubility Understand the structure: number of wythes, type of fasteners or dowels Analyze the mortar (composition, color, texture, type of joint) Know the chemical composition of pollution/salts Cleaning Masonry Water wash – fine spray directly onto element (removes gypsum crust) Chemical cleaners – acidic, alkaline – use extreme care; watch dwell time; rinse thoroughly. Environmental hazard, containment is essential. Hot water, steam – degreasing Particulate cleaning – more easily localized; can perform partial cleaning; can be used on different stones in juxtaposition; containment problems; requires trained operators Lasers – can clean extremely fragile surfaces; can only clean light surface with dark soiling; primary risk is yellowing Cleaning Dry Deposition — Reconversion of gypsum films into calcite on the surfaces of monuments & statues Gypsum on marble forms crust that preserves underlying design details Gypsum crust itself is fragile Washing gypsum off stone surface causes loss of historic material, esp. carving relief details Inversion of marble sulfation — chemically return gypsum to calcite (CaCO3) by spraying K2CO3 (potassium carbonate) on stone – Consolidates layers of stone, preserving design details – Calcite is five times harder than gypsum – Calcite is 29,000 times less soluble in water than gypsum Traditional Sandblasting Larger particulates, diameter = one mm Delivered at hundreds to thousands psi (pounds per square inch) Particulate used – True sand (quartz) Modern Particulate Cleaning Smaller particulates, diameter = tens of microns Delivered at tens of psi Particulates used: – – – – – Walnut shells Sodium bicarbonate (Armex) Dry ice Calcite or dolomite particles Façade grommage Glass beads Aluminum oxide Power Washing / Sandblasting Sandblasting Historic Brick Repairs to Stonework Re-tool mortar joint Re-dress surface of the stone Re-attach using adhesives and pins, dowels, or staples Patching (Dutchman or composite) Use consolidants (alkaoxysilane monomers) Remove and replace stone Dismantle and rebuild wall Remove and replace corroded metal elements Do all work in accordance with the Secretary’s standards Inappropriate & Appropriate Repairs Washington Park, Charleston, SC Preservation Briefs #1: Assessing Cleaning and WaterRepellent Treatments for Historic Masonry Buildings #2: Repointing Mortar Joints in Historic Masonry Buildings #6: Dangers of Abrasive Cleaning to Historic Buildings #38: Removing Graffiti from Historic Masonry