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Electronics background. Electronics is based on semi-conductors i.e. materials that are half way between being good conductors and good insulators. Silicon and germanium are on the dividing line between metals and non-metals on the periodic table and are good examples of semiconductors. The current that flows through a semiconductor depends on temperature. At low temperatures electrons are held firmly in the covalent bonds between atoms in a piece of the semiconductor. As temperature rises electrons gain kinetic energy. Some electrons will gain enough energy to break free and then it is possible to move them to cause a current to flow. Semi-conductors are used in electronics because it is possible to alter their ability to conduct by adding trace amounts of an impurity to the crystal structure. This is referred to as “doping”. Silicon is doped in 2 ways, using boron or using phosphorous. (Aluminium can be used, rather than boron, but students may think that adding a conductor to the silicon, of itself, will convert it to a conductor.) Boron and phosphorous atoms are about the same size as silicon atoms and so fit into the crystal. Boron atoms have one electron less than silicon whereas phosphorous atoms have an extra electron. Silicon doped with phosphorous has one electron, per phosphorous atom, on an outer shell that is not involved in a covalent bond. If a potential difference (voltage) is set up across a piece of doped silicon it is relatively easy to move this electron. This doped silicon is referred to as n-type as the charge carriers are negatively charged electrons. Silicon doped with boron is short of one electron, per aluminium atom, to complete the set of eight electrons in the outer shell. This creates a “hole” in which there should be an electron. If a potential difference (voltage) is set up across a piece of doped silicon it is possible to get electrons to move into this hole. This means that current can flow. Silicon doped in this way is referred to as p-type. The diode Diode Diode circuit symbol In a diode the 2 types of doped silicon are used in combination. Diodes consist of a piece of silicon one side of which is doped with boron and the other side doped with phosphorous. (A transistor has 3 layers, either p-n-p or n-p-n with a connection to each layer.) At the junction of the p-type and n-type some of the electrons will migrate from the ntype into the holes in the p-type. This creates a region at the junction without any charge carriers i.e. an insulating layer. As electrons have left the n-type it becomes positively charged near the junction while the p-type becomes negatively charged at its side of the junction. This creates a “junction voltage” (of about 0.6 V) where the 2 layers meet. This means that current will not flow when there is a voltage of less than 0.6 V across the diode. In a diode that is connected so that the p-type material is connected to the positive terminal of a battery a current can flow as electrons are repelled from the n-type material to occupy the holes and continue around the circuit. A diode connected in this way is said to be “forward-biased”. In a diode that is connected so that the n-type material is connected to the positive terminal of a battery a current cannot flow as electrons are attracted from the n-type material away from the holes. This creates an area at the junction of the p-type and n-type sections that do not have charge carriers i.e. an insulating layer. A diode connected in this way is said to be “reverse-biased”. A diode acts like a valve in the blood stream. It allows a current to flow in one direction only. It can be used to rectify alternating current by blocking current that is flowing in the “wrong” direction. Light Emitting Diode (LED) Different coloured LEDs LED symbol A light emitting diode is a diode that converts electrical energy to light, rather than to heat. They are used as indicator switches as they require very little energy. Most electrical appliances, TVs, electric kettles, music systems etc. have, at least, one LED to show when it is switched on. A Light-Dependent Resistor (LDR) is a device whose resistance to the flow of current is decreased when light falls on it. cadmium sulfide track A photon (packet of light energy) may provide enough energy to release an electron from an atomic or molecular orbital in the cadmium sulfide. It is then easier to get this electron to move in a particular direction i.e. the resistance is reduced. An LDR can be used to turn on circuits when light shines on it. This can be used in a burglar alarm. An LDR may also be used to automatically turn on and off streetlights.